Koexistenzbeziehungen,Darstellung und Eigenschaften ternärer Phasen im System Cu/Mo/O

Coexistence Relations, Preparation and Properties of Ternary Compounds in the System Cu/Mo/O The phase diagram of the ternary system Cu/Mo/O is presented at 773 K. The compounds CuMoO₄, Cu₃Mo₂O₉, Cu₄Mo₅O₁₇, Cu₆Mo₅O₁₈, Cu_4–xMo₃O₁₂, and Cu_xMoO₃ are found to be thermodynamical stable. The homogeneity range of Cu_4–xMo₃O₁₂ runs to x = 0.1–0.2. Single crystals of CuMoO₄ and Cu₃Mo₂O₉ were grown by chemical transport reactions with TeCl₄, Cl₂, HCl, and Br₂ as transport agent. The results were compared with thermochemical calculations. The decomposition of CuMoO₄ and Cu₃Mo₂O₉ was investigated with thermal analysis and decompositon pressure measurements.     

Pure Organic Phase Phenol Biosensor Based on Tyrosinase Entrapped in a Vapor Deposited Titania Sol‐Gel Membrane

A novel amperometric biosensor was constructed for the determination of phenols in pure organic phase. This biosensor was fabricated by immobilizing tyrosinase in a titania sol‐gel membrane which was obtained with a vapor deposition method. This method was facile and avoided the calcination step needed in conventional titania sol‐gel process. The titania sol‐gel membrane could effectively retain the essential water layer around the enzyme molecule needed for maintaining its activity in organic phase. The experimental parameters such as solvent and operating potential were optimized. At ?100 mV this biosensor showed a good amperometric response to phenols in pure chloroform without any mediator and rehydration of the enzyme. For catechol determination the sensor exhibited a fast response of less than 5 seconds. The sensitivity of different phenols was as follows: catechol > phenol > p‐cresol. Additionally, the apparent Michaelis‐Menten constants of the encapsulated tyrosinase to catechol, phenol and p‐cresol were found to be 0.15±0.003, 0.17±0.008 and 0.21±0.004 mM, respectively. The biosensor had also good reproducibility and stability. This work provided a promising platform for the construction of pure organic phase biosensors and the determination of substrates with poor water solubility.     

Damage spreading in a single-component irreversible reaction process: Dependence of the system's immunity on the Euclidean dimension

The spreading of a globally distributed damage, created in the stationary regime, is studied in a single-component irreversible reaction process, i.e., the BK model [Browne and Kleban,Phys. Rev. A 40, 1615 (1989)]. The BK model describes one variant of the A+AA₂ reaction process on a lattice in contact with a reservoir of A species. The BK model has a single parameter, namely the rate of arrival of A species to the lattice (Y). The model, exhibits an irreversible phase transition between a stationary reactive state with production of A₂ species and a poisoned state with the lattice fully covered by A species. The transition takes place at critical points (Y _C ) which solely depend on the Euclidean dimensiond. It is found that the system is immune ford=1 andd=2, in the sense that even 100% of initial damage is healed within a finite healing period (T _H ). Within the reactive regime,T _H diverges when approachingY _C according toT _H (Y _C –Y)^–, with 1.62 and 1.08 ford=1 andd=2, respectively. Ford=3 a frozen-chaotic transition is found close toY _s 0.4125, i.e., well inside the reactive regime 0YY _C 0.4985. Just atY _S the damageD(t) heals according toD(t) t ^–, with 0.71. For the frozen-chaotic transition atd=3 the order parameter critical exponent 0.997 is determined.     

Criticality and phase transitions in ionic fluids

Recent experimental investigations of criticality and phase separation in ionic fluids have revealed behavior of great theoretical interest. In seeking to understand the experiments, some of which appear to exhibit argonlike criticality and some of which exhibit classical (mean-field) criticality, a convenient starting point is the restricted primitive model (RPM) of symmetrically charged hard spheres, all of equal diameter , each sphere bearing a positive or negative charge of magnitudeq. There is overall charge neutrality, so that the expected number densities of the anions and cations are equal, ₊= _-. Studies of RPM charge-charge and density-density correlation functions indicate that the fluctuation-suppressing mechanism that yields mean-field critical behavior in nonionic systems with long-range interparticle potentials is not operative in the RPM. On the basis of plausible assumptions, Ising-like behavior is instead expected. The above work is summarized. New work of Zhang and the author is outlined, showing that when one loses the RPM symmetry (through, e.g., different valence, diameter, or dipole moment of anions and cations) a strong coupling between charge-charge and density-density correlation ensues. The way in which this can be expected to give rise to mean-field or mean-field-like behavior is noted. Other new observations concern the mean-field analogy found by Høye and the author between the parameter 2/(d–2) (d is the dimensionality) in that model and the monomer number in high polymers, with respect to the coexistence-curve shape dependence on those parameters.     

小像元量子阱FPA抗光学串音的FDTD仿真

采用光栅耦合结构的焦平面阵列(Focal Plane Array,FPA)在工艺上难以制备,反射耦合结构较为容易。为探究反射耦合结构是否可以在小尺寸范围内替代光栅耦合结构,文章使用FDTD电磁场仿真软件MEEP构建了光栅耦合结构和反射结构GaAs/AlGaAs量子阱红外焦平面阵列三像元模。通过对器件内部光学串音进行仿真,验证了在逼近衍射极限时,采用全内反射结构的FPA在5~7μm和8.5~10μm之间的抗串音效果强于光栅耦合结构,而在6.5~8.5μm和10~12μm之间,光栅耦合结构的抗串音效果更好,在12~15μm范围内,两种结构的抗串音能力相当。针对15μm中心距全内反射结构量子阱FPA,探究了反射角度、刻蚀深度和量子阱周期对其串音的影响。     

140 GHz回旋管高转换效率准光模式变换器设计研究（英文）

成功实现高转换效率的140 GHz TE22,6准光模式变换器原型设计。基于周期微扰原理设计Denisov辐射器,实现低边缘绕射的初级出射波束。针对三镜面光路系统,采用全矢物理光学积分作为主要计算手段,围绕主极化场分量进行三级相位修正面迭代优化,实现高出射高斯纯度的模式场转换,其中一级镜的修正有效改善了辐射器出射的不理想性。基于全矢数值仿真确认,相比原二次曲面原型设计,相位修正后的变换器系统的出射高斯纯度从92.7%提高到99.6%,结合98.8%以上的功率传递效率,实现了性能优越的高阶回旋管准光模式变换器原型设计。     

一种应用于5G毫米波通信的双极化有源相控阵模组

针对5G毫米波通信,研制了一种双极化有源相控阵天线模组。厚度为2 mm的多层PCB正面印制阵列天线,在其背面集成多通道波束成形芯片,通过中间层实现天线与芯片的互连以及供电、控制等。测试结果表明,研制的板状4×4双极化相控阵模组在E面和H面均实现了不小于±40度的波束扫描范围（不大于3 dB的电平下降）和低于-18 dB的归一化交叉极化电平,在24～27.5 GHz的频率范围内实现了V极化和H极化分别为42.6～45.7 dBm和43.5～46.1 dBm的等效全向辐射功率（EIRP）。     

多高斯关联扭曲光束在GRIN光纤中的轨道角动量演化

轨道角动量(orbital angular momentum, OAM)的引入丰富了光通信领域内的调制维度,为寻找更高效快捷的通信方式提供了新思路,相较于传统携带涡旋相位的涡旋光束,部分相干扭曲光束携带的OAM性质更为复杂。本文针对椭圆多高斯关联扭曲光束在梯度折射率(gradient-index, GRIN)光纤中的OAM传输,基于GRIN光纤的ABCD光学传输矩阵,着重分析了多高斯关联扭曲光束在GRIN光纤传输的OAM的传输演化特性。研究结果表明,光束的光强、OAM通量密度以及归一化OAM通量密度在光纤传输过程中均呈现周期性变化,通过对关联结构以及扭曲因子的调控不仅可以改变光束OAM通量密度的分布,还可以调控单光子携带OAM的大小。本文的研究有助于丰富扭曲部分相干光束在GRIN光纤中传输的理论结果,在光纤通信中具有潜在的应用前景。     

Boosting Piezo-Catalytic Activity of KNN-Based Materials with Phase Boundary and Defect Engineering

Although the piezo-catalysis is promising for the environmental remediation and biomedicine, the piezo-catalytic properties of various piezoelectric materials are limited by low carrier concentrations and mobility, and rapid electron-hole pair recombination, and reported regulating strategies are quite complex and difficult. Herein, a new and simple strategy, integrating phase boundary engineering and defect engineering, to boost the piezo-catalytic activity of potassium sodium niobate ((K, Na)NbO₃, KNN) based materials is innovatively proposed. Tur strategy is validated by exampling 0.96(K_0.48Na_0.52)Nb_0.955Sb_0.045O₃-0.04(Bi_xNa_4-3x)_0.5ZrO₃-0.3%Fe₂O₃ material having phase boundary engineering and conducted the defect engineering via the high-energy sand-grinding. A high reaction rate constant k of 92.49 × 10⁻³ min⁻¹ in the sand-grinding sample is obtained, which is 2.40 times than that of non-sand-grinding one and superior to those of other representative lead-free perovskite piezoelectric materials. Meanwhile, the sand-grinding sample has remarkable bactericidal properties against Escherichia coli and Staphylococcus aureus. Superior piezo-catalytic activities originate from the enhanced electron-hole pair separation and the increased carrier concentration. This study provides a novel method for improving the piezo-catalytic activities of lead-free piezoelectric materials and holds great promise for harnessing natural energy and disease treatment.     

Tailoring of Photoluminescence Properties in All-Vacuum Deposited Perovskite via Ruddlesden–Popper Faults

Ruddlesden–Popper (RP) faults are well known in oxide perovskites, and are also observed in promising metal halide perovskites. However, the effect of RP faults on optical properties of perovskite has not been systematically investigated. In this study, it is found that RP faults are common planar faults in all-vacuum deposited CsPbBr₃-based perovskite polycrystal thin films, and the density of RP planar faults can be greatly increased by non-stoichiometric composition (Cs-rich) as well as reduced dimensionality (quasi-2D) strategies. The photoluminescence (PL) measurement reveals monotonically increasing peak intensities with higher densities of RP planar faults from Cs-rich, quasi-2D to Cs-rich & quasi-2D samples. The corresponding atomic-scale differential phase contrast maps indicate strongly confined charges within the RP planar fault network, which explains well the relationship between PL enhancement and the density of RP planar faults, and offers an alternative pathway for tailoring the optoelectronic properties of perovskite.