Flexible active matrix addressed displays manufactured by printing and coating techniques

A flexible electrochromic active matrix addressed display, including 8 × 8 pixels, is demonstrated by using solution processing based on standard printing and coating manufacturing techniques. Each organic electrochromic display (OECD) pixel and its corresponding organic electrochemical transistor (OECT) are located on different sides of the flexible PET substrate. Electronic vias generated through the plastic substrate connects each OECD pixel with one addressing OECT. When comparing this display with actively addressed OECDs with all its components located on the same side, the present approach based on this electronic via substrate provides an enhanced pixel resolution and a relatively more simplified manufacturing process. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012     

A discrete-time amplifier based on Thin-Film Trans-Capacitors for sensor systems on foil

Organic materials can be used to fabricate sensors for physical and chemical quantities, and also to make electronics. The integration of these two elements holds the promise to enable novel smart-sensors on foil. In this paper, we deal with the design of the first stage of a signal conditioning chain on foil: the amplifier. The poor electrical performance of organic TFTs hampers the design of complex circuits, and negatively affects the characteristics of continuous-time amplifiers. In order to improve small-signal gain and speed, a mixed discrete-time and continuous-time approach is presented in this paper for the sensor frontend. A new device, the Thin-Film Trans-Capacitor, is presented and used to build the discrete-time amplifier, while the continuous time amplifier exploits a simple traditional architecture to improve yield. Simulations of the circuit proposed show that the total gain of the sensor frontend increases of about one decade without any detrimental effect on the speed. CAD (Computer-Aided Design) simulations confirm the results of the simple mathematical model we present.     

Accounting for variability in the design of circuits with organic thin-film transistors

We experimentally verify that the methodology to account for local parameter variations and transistor mismatch known in Si CMOS technologies can be transposed to organic thin-film transistor technologies, and we present a design case that makes use of design for variability. Transistor parameter variation decreases with the square root of the transistor footprint. As a consequence, Monte Carlo simulations which take this effect into account can be executed to better predict the final circuit yield. The design case in this work is an 8-bit, organic RFID transponder chip. The yield prediction by simulations corresponds to the finally observed circuit yield.     

Addition reaction and characterization of chlorotris(triphenylphosphine)iridium(I) on silicon(1 1 1) surfaces

Studies were performed to determine the chemical addition of a metal complex molecule, chlorotris(triphenylphosphine)iridium(I), on hydrogen passivated Si(1 1 1) surfaces to form a self-assembled monolayer (SAM). The iridium complex was synthesized prior to chemical addition, for which modified reaction conditions were chosen. Following addition, the silicon surfaces were characterized with X-ray photoelectron spectroscopy (XPS) and cyclic voltammetry (CV). The XPS results revealed that the surfaces consisted of the expected elemental percentages and that the iridium has a slightly higher success rate at attaching to oxide-free surfaces. XPS data also strongly indicate that the iridium complex remained intact upon chemisorption and did not decompose during the addition reaction. CV data show a difference between iridium treated surfaces and control samples. Hydrogen passivated wafers with iridium complex were much more conductive than those which were terminated with just an oxide or with an oxide and iridium complex. Furthermore, no free iridium reagent was detected as an additional feature in the current profile, indicating there was no physisorbed layer.     

加拿大针叶木纸浆的打浆特性及其电声性能

本文对各种加拿大进口针叶木纸浆的纤维特性做了分析。研究了各种加拿大进口纸浆的打浆特性及其电声性能。结果表明：在加拿大进口纸浆中,电子级乔治王子未漂白硫酸盐木浆FUKP和北木漂白硫酸盐木浆NBKP比较适合做为生产扬声器纸盆的主要材料。在扬声器纸盆的研发过程中,可以根据扬声器的具体用途及对音质的不同要求采用适当比例的FUKP和NBKP混合抄纸来达到相应的目标。     

铜粉添加量对铜酚醛树脂导电油墨性能的影响

以微米级铜粉为导电填料、酚醛树脂为粘接剂制备了导电油墨,并将该油墨以聚酰亚胺薄膜为基底,采用丝网印刷技术制备导电涂层。研究了铜粉添加量对铜酚醛树脂导电油墨的黏度、固含量以及导电涂层的微观形貌、电阻率和附着力的影响。研究表明,当铜粉添加量质量分数为70%时,制备的铜酚醛树脂导电油墨具有良好的性能,该导电油墨经丝网印刷得到的导电铜膜经低温固化后具有良好的电性能,其电阻率最低可以达到53.865×10–3Ω·cm。     

Molecular Heterojunctions of Oligo(phenylene ethynylene)s with Linear to Cruciform Framework

Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO–LUMO energy gaps. OPE3, OPE3–DTF, and OPE3–tetrathiafulvalene (TTF) can form good self‐assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe–atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3–TTF > OPE3–DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero‐bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.     

Materials and Wireless Microfluidic Systems for Electronics Capable of Chemical Dissolution on Demand

Electronics that are capable of destroying themselves, on demand and in a harmless way, might provide the ultimate form of data security. This paper presents materials and device architectures for triggered destruction of conventional microelectronic systems by means of microfluidic chemical etching of the constituent materials, including silicon, silicon dioxide, and metals (e.g., aluminum). Demonstrations in an array of home‐built metal‐oxide‐semiconductor field‐effect transistors that exploit ultrathin sheets of monocrystalline silicon and in radio‐frequency identification devices illustrate the utility of the approaches.     

Flexible and Highly Sensitive Strain Sensors Fabricated by Pencil Drawn for Wearable Monitor

Functional electrical devices have promising potentials in structural health monitoring system, human‐friendly wearable interactive system, smart robotics, and even future multifunctional intelligent room. Here, a low‐cost fabrication strategy to efficiently construct highly sensitive graphite‐based strain sensors by pencil‐trace drawn on flexible printing papers is reported. The strain sensors can be operated at only two batteries voltage of 3 V, and can be applied to variously monitoring microstructural changes and human motions with fast response/relaxation times of 110 ms, a high gauge factor (GF) of 536.6, and high stability >10 000 bending–unbending cycles. Through investigation of service behaviors of the sensors, it is found that the microcracks occur on the surface of the pencil‐trace and have a major influence on the functions of the strain sensors. These performances of the strain sensor attain and even surpass the properties of recent strain sensing devices with subtle design of materials and device architectures. The pen‐on‐paper (PoP) approach may further develop portable, environmentally friendly, and economical lab‐on‐paper applications and offer a valuable method to fabricate other multifunctional devices.