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981.
Determination of contact stresses in problems on bending of a package of transversely isotropic bars
V. I. Zubko 《Mechanics of Composite Materials》2004,40(6):495-508
A mechanomathematical model for bending of packages of transversely isotropic bars of rectangular cross section is proposed. Adhesion, slippage, and separation zones between the bars are considered. The resolving equations for deflections and tangential displacements are supplemented with a system of linear differential equations for determining the normal and tangential contact stresses, and boundary conditions are formulated. A scheme for analytical solution of two contact problems—a package under the action of a distributed load and a round stamp—is considered. For these packages, a transition is performed from the initial system of differential equations for determining the contact stresses, where the unknown functions are interrelated by recurrent relationships, to one linear differential equation of fourth order and then to a system of linear algebraic equations. This transition allows us to integrate the initial system and get expressions for the contact stresses.Translated from Mekhanika Kompozitnykh Materialov, Vol. 40, No. 6, pp. 761–778, November–December, 2004. 相似文献
982.
研究了阳离子表面活性剂十六烷基三甲基溴化铵 (CTAB)对四 ( 4 N 甲基吡啶 )卟啉 (H2 TMPyP)及其银配合物 (AgTMPyP)在Ag胶中的表面增强拉曼散射 (SERS)谱的影响 .SERS光谱表明 ,吸附于Ag胶粒的H2 TMPyP与衬底银原子结合形成AgTMPyP ,加入CTAB后 ,部分AgTMPyP表面络合物还原为H2 TMPyP .相似的去金属化反应也出现在AgTMPyP/Ag胶 /CTAB体系中 .CTAB的加入使SERS谱带强度明显增加 .AgTMPyP的去金属化被认为是由于CTAB的存在使Ag胶颗粒表面附近微环境发生改变 相似文献
983.
N. A. A. Rossi R. G. Jones S. J. Holder 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):30-40
ABA block copolymers of methyl methacrylate and methylphenylsilane were synthesized with a methodology based on atom transfer radical polymerization (ATRP). The reaction of samples of α,ω‐dihalopoly(methylphenylsilane) with 2‐hydroxyethyl‐2‐methyl‐2‐bromoproprionate gave suitable macroinitiators for the ATRP of methyl methacrylate. The latter procedure was carried out at 95 °C in a xylene solution with CuBr and 2,2‐bipyridine as the initiating system. The rate of the polymerization was first‐order with respect to monomer conversion. The block copolymers were characterized with 1H NMR and 13C NMR spectroscopy and size exclusion chromatography, and differential scanning calorimetry was used to obtain preliminary evidence of phase separation in the copolymer products. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 30–40, 2003 相似文献
984.
985.
Two new polyacid derivative ligands of thienyl-substituted terpyridine analogues, N,N,N1,N1-[4′-(2?-thienyl)-2,2′:6′,2″-terpyridine-6,6″-diyl]bis(methylenenitrilo) tetrakis(acetic acid) (TTTA) and N,N,N1,N1-[2,6-bis(3′-aminomethyl-1′-pyrazolyl)-4-(2″-thienyl)pyridine] tetrakis(acetic acid) (BTTA), were synthesized, and the luminescence properties of their Eu3+ and Tb3+ chelates were investigated. The Eu3+chelates of the two ligands are strongly luminescent having luminescence quantum yields of 0.150 (TTTA-Eu3+) and 0.114 (BTTA-Eu3+), and lifetimes of 1.284 ms (TTTA-Eu3+) and 1.352 ms (BTTA-Eu3+), whereas their Tb3+ chelates are weakly luminescent. The TTTA-Eu3+ chelate was used for streptavidin (SA) labeling, and the labeled SA was used for time-resolved fluoroimmunoassay of insulin in human sera. The method gives the detection limits of 33 pg ml−1. 相似文献
986.
I. Capek J. Chudej S. Janí
kov 《Journal of polymer science. Part A, Polymer chemistry》2003,41(6):804-820
The sterically stabilized emulsion polymerization of styrene initiated by a water‐soluble initiator at different temperatures has been investigated. The rate of polymerization (Rp) versus conversion curve shows the two non‐stationary‐rate intervals typical for the polymerization proceeding under non‐stationary‐state conditions. The shape of the Rp versus conversion curve results from two opposite effects—the increased number of particles and the decreased monomer concentration at reaction loci as the polymerization advances. At elevated temperatures the monomer emulsion equilibrates to a two‐phase or three‐phase system. The upper phase is transparent (monomer), and the lower one is blue colored, typical for microemulsion. After stirring such a multiphase system and initiation of polymerization, the initial coarse polymer emulsion was formed. The average size of monomer/polymer particles strongly decreased up to about 40% conversion and then leveled off. The initial large particles are assumed to be highly monomer‐swollen particles formed by the heteroagglomeration of unstable polymer particles and monomer droplets. The size of the “highly monomer” swollen particles continuously decreases with conversion, and they merge with the growing particles at about 40–50% conversion. The monomer droplets and/or large highly monomer‐swollen polymer particles also serve as a reservoir of monomer and emulsifier. The continuous release of nonionic (hydrophobic) emulsifier from the monomer phase increases the colloidal stability of primary particles and the number of polymer particles, that is, the particle nucleation is shifted to the higher conversion region. Variations of the square and cube of the mean droplet radius with aging time indicate that neither the coalescence nor the Ostwald ripening is the main driving force for the droplet instability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 804–820, 2003 相似文献
987.
The mobile ad hoc network (MANET) has recently been recognized as an attractive network architecture for wireless communication. Reliable broadcast is an important operation in MANET (e.g., giving orders, searching routes, and notifying important signals). However, using a naive flooding to achieve reliable broadcasting may be very costly, causing a lot of contention, collision, and congestion, to which we refer as the broadcast storm problem. This paper proposes an efficient reliable broadcasting protocol by taking care of the potential broadcast storm problem that could occur in the medium-access level. Existing protocols are either unreliable, or reliable but based on a too costly approach. Our protocol differs from existing protocols by adopting a low-cost broadcast, which does not guarantee reliability, as a basic operation. The reliability is ensured by additional acknowledgement and handshaking. Simulation results do justify the efficiency of the proposed protocol. 相似文献
988.
N[a,b]类中边界Nevanlinna-Pick插值(I) 总被引:1,自引:1,他引:0
用所谓的Hankel向量方法求解N[a,b]函数类中带边界插值数据的Nevanlina-Pick插值(BNP(N[a,b]))问题,并建立BNP(N[a,b])问题与[a,b]上的某种带约束条件的Hausdorff矩量问题之间等价的可解条件以及解之间明确的一一对应关系.这使得当BNP(N[a,b])问题有多解时,能通过带约束条件的矩量问题的可解性准则和解获得BNP(N[a,b])问题的可解性准则和解的参数化描述,而在唯一解的情况下,通过BNP(N[a,b])问题解的存在唯一性准则和唯一解来获得带约束条件的 相似文献
989.
机载红外搜索跟踪系统被动定位滤波算法研究 总被引:1,自引:1,他引:0
首先用扩展卡尔曼滤波算法构建了机载红外搜索跟踪系统被动定位滤波模型.然后针对该滤波算法要求先验的噪声统计及存在系统观测模型线性化误差影响滤波精度的特点.利用虚拟噪声技术,提出了适合于红外搜索跟踪系统被动定位的自适应扩展卡尔曼滤波算法。该算法实时地估计了虚拟噪声的统计特性,减小了线性化误差,提高了非线性滤波的精度。仿真结果表明,在完全相同的初始条件下,自适应扩展卡尔曼滤波对目标距离和速度的估计结果明显优于扩展卡尔曼滤波,此算法具有很高的工程应用价值。 相似文献
990.
Finite element analysis of fluid flow with moving free surface has been performed in 2‐D and 3‐D. The new VOF‐based numerical algorithm that has been proposed by the present authors (Int. J. Numer. Meth. Fluids, submitted) was applied to several 2‐D and 3‐D free surface flow problems. The proposed free surface tracking scheme is based on two numerical tools; the orientation vector to represent the free surface orientation in each cell and the baby‐cell to determine the fluid volume flux at each cell boundary. The proposed numerical algorithm has been applied to 2‐D and 3‐D cavity filling and sloshing problems in order to demonstrate the versatility and effectiveness of the scheme. The proposed numerical algorithm resolved successfully the free surfaces interacting with each other. The simulated results demonstrated applicability of the proposed numerical algorithm to the practical problems of large free surface motion. It has been also demonstrated that the proposed free surface tracking scheme can be easily implemented in any irregular non‐uniform grid systems and can be extended to 3‐D free surface flow problems without additional efforts. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献