茂铁基二氢吡唑类衍生物的液相色谱分离研究

本文利用梯度洗脱进行溶剂强度的优化,确定分离一组化合物的最佳二元流动相体系,即甲醇-水、四氢呋喃-水和乙腈-水,将这三种二元流动相的最佳组成作为溶剂选择性三角形的三个顶点,利用ORM法对流动相进行优化选择,得到流动相的最佳组成和配比为V乙腈:V四氢呋喃:V水=33.75:33:33.25,有效地分离了六种二茂铁取代二氢...     

同频重叠信号的单通道盲分离方法综述

同频重叠信号单通道分离在信号分离领域具有广阔的应用前景,成为近年来信号处理领域研究的热点之一.在回顾了自然信号单通道分离方法的基础上,对同频重叠信号的单通道盲分离方法作了详尽的分析,总结了国内外的研究成果,讨论了现有理论和方法的优缺点及应用条件,最后指出了今后可能的进一步研究方向.     

一种改进的雷达脉冲信号分选算法

重频分选方法中,由于序列差值直方图法(SDIF)对PRI抖动的雷达脉冲信号的分选能力差,而PRI变换法可以分选PRI抖动的雷达脉冲信号,但是运算量太大,难以实现实时分选。对SDIF算法进行了改进,采用交叠PRI箱的方法进行直方图的统计,使得改进后的SDIF在运算量增加不多的情况下,可以实时较好地分选PRI抖动量在10%以内的雷达脉冲信号。     

基于非均匀采样的光纤光栅解调系统

鉴于重叠多光纤Bragg光栅(FBG)传感器均匀采样时遇到的数据频谱混叠问题, 提出利用扫描周期随 机变化的正弦波实现传感FBG的非均匀采样方法,并在一种基于可调谐F-P滤波器的 FBG解调系统中得到成功应用。实验结果显示,本文方法能够很好避免混叠现 象,并且还能以低于Nyquist采样频率对信号进行采样分析。     

TD-LTE网络结构评估方法研究及预规划分析

TD-LTE作为同频组网系统,网络结构对其无线网络质量有着重要的影响。而在基于TD-SCDMA或GSM现网基础上进行TD-LTE建设时,会由于传统网络结构无法达到TD-LTE同频组网结构要求而造成网络质量下降。对此,本文提出了一种TD-LTE网络结构评估方法,通过对TD-SCDMA及GSM现网数据进行分析预测得到TD-LTE网络性能及其弱覆盖、重叠覆盖、干扰小区等网络结构指标。该方法可以对TD-LTE网络性能进行准确的评估,从而提升网络结构评估的准确性和实用性。     

低指纹密度下分段式高精确度室内定位方法

针对室内环境中传统定位方法在大定位区域、低指纹密度下定位精确度低、计算复杂度高的问题,提出了一种基于线性插值法和分布重叠的分段式定位方法。该方法采用传统的最近邻法进行粗定位,得到可信区域;利用线性插值法更新可信区域内指纹数据库,增加指纹密度;在可信区域内,采用基于分布重叠的指纹相似度匹配法实现精定位。实验结果表明,在低指纹密度下,该定位方法定位精确度较高,算法复杂度适中,具有一定的适用性。     

基于线性预测分析的语音信号合成

语音合成是实现人机语音通信的关键技术。文中介绍了一种基于语音信号线性预测分析的语音合成方法,以及什么是线性预测系数和如何提取线性预测系数,然后采用了重叠存储法,用预测系数合成语音。这种合成方法可以应用到语音信号的传输过程中,能减小信号的传输带宽,提高传输速率。     

D38R突变对细菌视紫红质光循环后半程M态和N态的影响

用重叠PCR的方法，定点突变细菌视紫红质（bacteriorhodopsin，BR），克隆到单突变体BRD96N和双突变体BRD38R/D96N的基因，同源转化盐沼盐杆菌（Halobacterium salinarium）L33（BR），表达突变蛋白BRD96N和BRD38R／D96N通过显微视频方法对突变BR的M态光致变色特性进行记录，BRD38R／D96N的M态寿命为5s，约为BRD96N（M态寿命为3s）的1．7倍．对突变体的激光共聚焦拉曼光谱测定发现，在BRD96N中，1170cm^-1下移到1171cm^-1，1258cm^-1上移到1255cm^-1，而BRD38R/D96N中1170cm^-1下移到1173cm^-1；1258cm^-1。上移到1252cm^-1，而且BRD38R/D96N与BRD96N相比，1186cm^-1处的峰明显增强．近紫外区圆二色谱显示，两种突变体近紫外区的正负带虽然没有太大差别，但288nm和290nm处的极峰却差别显著．所有这些研究结果表明，细菌视紫红质Asp38（D38）突变为Arg（R）可以延长其光循环后半程M态和N态的寿命．     

Domain decomposition preconditioners for multiscale problems in linear elasticity

We analyze two‐level overlapping Schwarz domain decomposition methods for vector‐valued piecewise linear finite element discretizations of the PDE system of linear elasticity. The focus of our study lies in the application to compressible, particle‐reinforced composites in 3D with large jumps in their material coefficients. We present coefficient‐explicit bounds for the condition number of the two‐level additive Schwarz preconditioned linear system. Thereby, we do not require that the coefficients are resolved by the coarse mesh. The bounds show a dependence of the condition number on the energy of the coarse basis functions, the coarse mesh, and the overlap parameters, as well as the coefficient variation. Similar estimates have been developed for scalar elliptic PDEs by Graham et al. 1 The coarse spaces to which they apply here are assumed to contain the rigid body modes and can be considered as generalizations of the space of piecewise linear vector‐valued functions on a coarse triangulation. The developed estimates provide a concept for the construction of coarse spaces, which can lead to preconditioners that are robust with respect to high contrasts in Young's modulus and the Poisson ratio of the underlying composite. To confirm the sharpness of the theoretical findings, we present numerical results in 3D using vector‐valued linear, multiscale finite element and energy‐minimizing coarse spaces. The theory is not restricted to the isotropic (Lamé) case, extends to the full‐tensor case, and allows applications to multiphase materials with anisotropic constituents in two and three spatial dimensions. However, the bounds will depend on the ratio of largest to smallest eigenvalue of the elasticity tensor.     

Rotational statistics and thermodynamic functions of hydrogen peroxide

Partition functions for both the rotational modes (hindered internal rotation and overall rotation) of the hydrogen peroxide (H₂O₂) molecule in the ground electronic state are studied using quantum and classical Gibbsian statistical mechanics. The partition functions are used to calculate rotational thermodynamic functions (internal energy, enthalpy, Helmholtz free energy, Gibbs free energy and entropy) of a hydrogen peroxide gas of weakly interacting molecules at temperatures above 300 K.