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111.
112.
The van der Waals equation of state for binary mixtures has been used to determine the location and shape of the Griffiths shield region (where three tricritical lines intersect). If one takes the geometric mean fora
12, the arithmetic mean forb
12, and the configurational free energy as ideal, the center of the Griffiths shield region is found only when the ratio of molecular sizes is infinite. When the Flory equation for the configurational free energy for mixtures of chain molecules is substituted for the ideal form, the results appear to be somewhat different. However, for all the cases studied, with systems which approach geometric mean behavior one finds the shield region only when the ratio of molecular size is very large and when the internal pressure of the small molecule is very much greater than that of the long-chain molecule.This paper is dedicated to our colleague Howard Reiss on the occasion of his 66th birthday. 相似文献
113.
Damped Ly-α systems are the major repository of the observed neutral HI at high redshift. These systems are most efficiently
detected via absorption spectra taken against distant QSOs. In this paper, we review some of the observational constraints
on the nature of these objects, and also discuss the implications of recent observations of two low redshift damped absorbers,
made with the Giant Metrewave Radio Telescope. We find that, for the lowest redshift (z = 0.0912) damped Ly-α system, if the system is a rotating gas disk, then the total associated HI mass has to be less than
2 × 109 M⊙, if the disk is at low inclination angles, and less than 1010 M⊙ if the system is edge on. All limits are 3σ. 相似文献
114.
G.Ya. Korenman 《Hyperfine Interactions》1999,119(1-4):227-233
Effect of medium density on shift and broadening of (
) spectral lines is considered in the framework of binary-collision approximation with an effective (
)–He potential including the long-range attraction and short-range repulsion. Quantum calculations of the scattering phase
shifts at reasonable values of the potential parameters allow to explain the main features of the observed density effect
on the shape of (
) spectral lines in low-temperature helium.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
115.
The results of the analysis of the stability of stationary solutions of wave equations discribing a behavior of the nonlinear Fabry-Perot interferometer with a saturated paramagnetic filling are presented in this paper. The cases when paramagnetic medium is characterized by a homogeneously and nonhomogeneously broadened line of the magnetic resonance have been considered. Areas of unstable behavior of these characteristics of the resonance structure have been found. 相似文献
116.
D. Dangoisse J. Wascat J. M. Colmont 《International Journal of Infrared and Millimeter Waves》1981,2(6):1177-1191
A large number of emissions is obtained in the submillimeter and near millimeter range with the (H2CO)3 laser optically pumped by a CO2 laser. A study of the microwave absorption spectrum of the molecule carried out simultaneously with the submm analysis allows us to assign six of the laser lines in thev
5 excited state of the molecule and to determine the rotational constants and vibrational energy ofv
5. 相似文献
117.
E. C. C. Vasconcellos F. R. Petersen K. M. Evenson 《International Journal of Infrared and Millimeter Waves》1981,2(4):705-711
We report for the first time wavelength, relative polarization, and frequency measurements for 47 new cw FIR laser lines in the wavelength region from 120 to 1714 m, all obtained by optically pumping CD2F2 with a CO2 laser. Relative output powers were also measured. For comparison, the 189.8 m line pumped by RI(34) is nearly five times as efficient as the 118.8 m methyl alcohol line.Contribution of the U.S. Government, not subject to copyright. 相似文献
118.
《Current Applied Physics》2015,15(11):1296-1302
One-dimensional ZnO materials have been promising for field-emission (FE) application, but how to facially control the alignment of ZnO emitters is still a great challenge especially for patterned display application. Here, we report the fabrication of novel ZnO nanowire (NW) line and bundle arrays for patterned field-electron emitters. The effects of PS template size and heating time on the resulted ZnO nanoarrays were systematically studied. The deformation degree of PS templates was controlled and hence utilized to adjust the alignment of electrochemically deposited ZnO arrays. It was found that the length of NW lines and the density of NW bundles can effectively tuned by the PS template heating time. The optimal FE performance with turn-on electric field as low as of 4.4 V μm−1 and the field-enhancement factor as high as of 1450 were achieved through decreasing the screening effect among the patterned field-electron emitters. 相似文献
119.
G. Carelli N. Ioli A. Moretti G. Moruzzi D. Pereira F. Strumia 《International Journal of Infrared and Millimeter Waves》1991,12(5):449-471
We have increased the frequency tunability of our CW waveguide CO2 lasers by means of an acoustooptic amplitude modulator, operating at the fixed frequency of 90 MHz. The up-shifted, or down-shifted, laser optical sideband can be generated independently by adjusting the orientation of the modulator. The efficiency is larger than 50%. The frequency tunability of the CO2 laser around each laser line is thus increased by 180 MHz. To demonstrate the possibilities of this method, a source composed of the above modulator and of a CW, 300 MHz tunable waveguide CO2 laser has been used for the search of new large offset FIR laser lines from optically pumped CH3OH and13CH3OH molecules. As a result 15 and 10 new large offset laser lines were discovered respectively. New assignments of some laser lines are also proposed. We have also measured the Stark effect, the offset, and the polarization of other already known lines. In particular a Stark effect frequency tuning of about 1 GHz is demonstrated for a laser line at 208.399 m. 相似文献
120.
E. C. C. Vasconcellos K. M. Evenson 《International Journal of Infrared and Millimeter Waves》1985,6(11):1157-1167
We have obtained laser action on 34 far infrared lines for the first time in fully deuterated methyl alcohol with the13C isotope (13CD3OD), and we have measured the frequency of 13 lines. The molecule was pumped by a cw CO2 laser. We have measured the wavelength, the relative polarization, the relative intensity of most lines, the frequency, and the CO2 pump frequency offset of the strongest lines. The new lines are distributed in the wavelength region from 75.27 m to 464.7 m.Supported in part by a joint grant with the U.S. National Science Foundation grant # INT 80-19014 and the Brazilian Conselho Nacional de Pesquisas (CNPq). 相似文献