全文获取类型
收费全文 | 4273篇 |
免费 | 483篇 |
国内免费 | 257篇 |
专业分类
化学 | 421篇 |
晶体学 | 11篇 |
力学 | 263篇 |
综合类 | 68篇 |
数学 | 2119篇 |
物理学 | 445篇 |
无线电 | 1686篇 |
出版年
2024年 | 18篇 |
2023年 | 50篇 |
2022年 | 80篇 |
2021年 | 85篇 |
2020年 | 106篇 |
2019年 | 101篇 |
2018年 | 99篇 |
2017年 | 127篇 |
2016年 | 177篇 |
2015年 | 156篇 |
2014年 | 250篇 |
2013年 | 349篇 |
2012年 | 227篇 |
2011年 | 250篇 |
2010年 | 202篇 |
2009年 | 238篇 |
2008年 | 261篇 |
2007年 | 327篇 |
2006年 | 287篇 |
2005年 | 234篇 |
2004年 | 193篇 |
2003年 | 170篇 |
2002年 | 158篇 |
2001年 | 141篇 |
2000年 | 139篇 |
1999年 | 107篇 |
1998年 | 89篇 |
1997年 | 83篇 |
1996年 | 61篇 |
1995年 | 38篇 |
1994年 | 33篇 |
1993年 | 30篇 |
1992年 | 19篇 |
1991年 | 11篇 |
1990年 | 18篇 |
1989年 | 14篇 |
1988年 | 5篇 |
1987年 | 9篇 |
1986年 | 5篇 |
1985年 | 9篇 |
1984年 | 12篇 |
1983年 | 9篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 6篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1970年 | 2篇 |
1936年 | 1篇 |
排序方式: 共有5013条查询结果,搜索用时 0 毫秒
41.
Jinhua Wang Dr. Barbara Wicher Dr. Victor Maurizot Prof. Ivan Huc 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(3):1031-1038
Quinoline based aromatic amide foldamers are known to adopt stable folded conformations. We have developed a synthetic approach to produce similar oligomers where all amide bonds, or part of them, have been replaced by an isosteric vinylene group. The results of solution and solid state structural studies show that oligomers exclusively containing vinylene linkages are not well folded, and adopt predominantly flat conformations. In contrast, a vinylene segment flanked by helical oligoamides also folds in a helix, albeit with a slightly lower curvature. The presence of vinylene functions also result in an extension of π-conjugation across the oligomer that may change charge transport properties. Altogether, these results pave the way to foldamers in which both structural control and specific electronic properties may be engineered. 相似文献
42.
《Biomedical chromatography : BMC》2018,32(2)
A gas chromatography–tandem mass spectrometry method was developed and validated to simultaneously determine boscalid and fludioxonil in grape and soil samples. These samples were extracted with 10 mL of acetonitrile and purified using a mixed primary secondary amine/octadecylsilane sorbent. The method showed good linearity (R2 > 0.99) in the calibration range 0.005–2 μg/mL for both pesticides. The limits of detection and quantification for the two analytes in grape and soil were 0.006 and 0.02 mg/kg, respectively. Fungicide recoveries in grape and soil were 81.18–92.11% for boscalid and 82.73–97.67% for fludioxonil with relative standard deviations of 1.31–10.31%. The established method was successfully applied to the residual analysis of boscalid and fludioxonil in real grape and soil samples. The terminal residue concentrations of boscalid and fludioxonil in grape samples collected from Anhui and Guizhou were <5 mg/kg (the maximum residue limit set by China) 7 days after the last application and 1 mg/kg (the maximum residue limit set by USA) 14 days after the last application. These results could provide guidance for the proper and safe use of boscalid and fludioxonil in grape and help the Chinese government to establish an MRL for fludioxonil in grape. 相似文献
43.
NMR spectroscopy plays an important part in the determination of the structures of organic compounds. The parameters of importance here are the chemical shifts of the 1H and 13C nuclei and the spin-spin interactions both between 1H nuclei and between 1H and 13C nuclei. Couplings between 13C nuclei were almost completely neglected until a few years ago, since they were extremely difficult to observe because of the low natural abundance of 13C. However, it is these couplings which afford information directly on the carbon-carbon connectivities in the molecule. It is now possible to use a special NMR pulse sequence to make these couplings more readily visible: the result of using this sequence is a 13C-NMR spectrum from which the carbon skeleton concerned can be directly read off. Two-dimensional spectra in particular are very easy to evaluate. The pulse sequence involved, which bears the somewhat puzzling name INADEQUATE, produces double-quantum coherences from which the NMR signals of the coupled carbon nuclei can be obtained. In this article the principle of double-quantum coherence is described and a number of examples for the application of the INADEQUATE pulse sequences to problems in synthetic organic chemistry, biosynthesis and natural products chemistry are presented; in addition, the possibility of applying the INADEQUATE method to other nuclei is considered. 相似文献
44.
Summary A pattern recognition methodology has been developed for analysis of chromatographic data. The method uses a new class of
multidimensional orthogonal polynomials developed by Cohen in conjunction with a supervised learning technique. The method
is applicable to any chromatographic data for which classification into two or more categories is desired. The algorithm analyzes
both elution times and peak areas. An application is shown for the analysis of organic acids in ascitic fluid obtained from
patients with liver disorders. Classification of these patients for presence or absence of bacterial infection shows over
ninety percent correct classification. 相似文献
45.
46.
以N,N-二甲基-1,3-丙二胺、尿素及1,4-二氯丁烷为原料,通过共缩聚反应两步法制备了一种新的主链型的水溶性聚季铵盐.采用正交试验获得了制备聚季铵盐的最佳条件:N,N-二甲基-1,3-丙二胺与尿素的物质的量比为2∶1,反应温度为135℃,反应时间为11h,得到中间体双[3-(N,N-二甲基丙胺基)]丙脲,产率高达99%;中间体与1,4-二氯丁烷的物质的量比为1∶1,于90℃下反应6h.采用红外光谱和核磁氢谱对产物结构进行表征,测定了其热稳定性和特性粘数. 相似文献
47.
48.
49.
Bi Xian Tonghua Li Chen Kai Tongcheng Cao Jianrong Huang Yunpeng Qi 《Journal of mathematical chemistry》2004,36(2):129-138
Orthogonal signal correction (OSC) was a data preprocessing algorithm. It ensured that the filtered information was irrelevant to concentration data while using it to filter the noise from the original data. This paper extended the OSC application range from two-way data to three-way data. Two drug data sets, Enoxacin, Norfloxacin, Ciprofloxacin and Betamethasone, cortisone acetate, prednisone acetate, showed that the application of the OSC algorithm to three-way HPLC data was feasible and needed further research. 相似文献
50.