使用溅射AlN成核层实现大规模生产深紫外LED

高质量AlN薄膜对制造高性能深紫外器件非常重要,但是目前还很难使用大型工业MOCVD生长出高质量的AlN薄膜.采用磁控溅射制备了不同厚度的用作成核层的AlN薄膜,使用大型工业MOCVD直接在成核层上高温生长AlN外延层,研究了不同成核层对AlN外延层质量的影响.通过扫描电子显微镜和原子力显微镜对成核层AlN薄膜的表面形貌进行表征;使用高分辨X射线衍射仪对AlN外延层晶体质量进行表征,结果表明:在溅射成核层上生长的AlN外延层的晶体质量有显著提高.使用大型工业MOCVD在蓝宝石衬底上成功制备出中心波长为282 nm的可商用深紫外LED,在注入电流为20 mA时,单颗深紫外LED芯片的光输出功率达到了1.65 mW,对应的外量子效率为1.87%,饱和光输出功率达到4.31 mW.     

Si-玻璃阳极键合失效机理研究

在采用Si-玻璃阳极键合技术制备微惯性传感器的过程中,实验发现键合圆片中心区域键合失效。通过对键合机理和工艺过程进行分析,认为湿法腐蚀工艺引入钾离子(K+)污染是造成键合失效的主要原因,也可以对键合失效现象给出合理的解释。改变工艺参数进行了键合对比实验,结果表明,未受K+污染的键合圆片没有发生键合失效现象。提出了解决键合失效问题的两种方案,并首次提出在Si片表面生长氧化层提高失效区键合强度的方法;从理论上分析了增加SiO2介质层的可行性。强度测试结果表明,在SiO2厚度为150nm时,键合剪切强度达到14MPa,验证了方案的可靠性。利用上述方法制备出微加速度传感器敏感结构。     

体硅热膜传感器单片集成工艺的研究

针对MEMS热膜式传感器的发展趋势和在实用化过程中存在的问题,提出了一种新型的单片电路和体硅MEMS热膜式传感器实现集成制造的嵌入式CMOS工艺技术,解决了MEMS制造工艺和CMOS集成电路工艺之间存在的兼容性问题。通过这种嵌入式CMOS工艺技术,可以实现具备最小体积、最低成本的MEMS器件。通过这种嵌入式热膜式传感器和CMOS处理电路的单片集成制造工艺,实现了一款热膜式传感器和IC放大电路的集成部件,并完成了相关基本电性能测试和传感器功能的演示验证,证明了设计的工艺路线的可行性。     

聚噻吩类有机聚合物材料光电性能研究进展

介绍了典型的具有光电性能的噻吩类聚合物材料,包括烷基取代聚噻吩、联苯基取代聚噻吩、芴与噻吩共聚物及一些新型的噻吩类聚合物。对它们的结构、光学性能、电致发光性能进行了归纳和总结,讨论了不同类聚噻吩的特点,对比了随取代基种类、位置及个数的不同其聚合物性能的优缺点,并对其研究和应用前景进行了展望。     

OLED背光源技术研究进展

有机电致发光二极管(OLED)因其白光材料的多样性、制程的简单性和成本低廉性,特别是其面光源的属性,相较于电致发光二极管(LED)的点光源,更有望成为未来液晶显示器件背光源的主角。介绍了OLED背光源关键技术的最新进展,分别阐述了白光OLED发光效率的提升,OLED器件稳定性和寿命的提高,OLED制备的最新工艺,偏极化的OLED技术,OLED背光源与液晶显示面板匹配技术,还介绍OLED背光源产业发展及发展现状,并对OLED背光源技术的发展趋势进行了展望。     

Contact Doping for Vertical Organic Field‐Effect Transistors

Doping is a powerful tool to overcome contact limitations in short‐channel organic field‐effect transistors (OFETs) and has been successfully used in the past to improve the charge carrier injection in OFETs. The present study applies this familiar concept to the architecture of vertical organic field‐effect transistors (VOFETs), which are often severely limited by injection due to their very short channel lengths. The present study shows that the performance of p‐type VOFETs with pentacene as an active material can be significantly enhanced by the addition of the common p‐dopant C₆₀F₃₆ as a thin injection layer underneath the VOFET source electrode, resulting in an increase of On‐state current and On/Off ratio by one order of magnitude. The present study further investigates mixed injection layers of pentacene and the p‐dopant and finds that the improvement is less pronounced than for the pure dopant layers and depends on the concentration of dopant molecules in the injection layer. Through application of the transfer length method to equivalent OFET geometries, the present study is finally able to link the observed improvement to a decrease in transfer length and can thus conclude that this length is a crucial parameter onto which further improvement efforts have to be concentrated to realize true short‐channel VOFETs.     

Locally Welded Silver Nano‐Network Transparent Electrodes with High Operational Stability by a Simple Alcohol‐Based Chemical Approach

As an indispensable aspect of emerging flexible optoelectronics, flexible transparent electrodes, especially those comprised of metal nanowires, have attracted great attentions recently. Welding the nanowire junctions is an effective strategy for reducing the sheet resistance and improving the operational stability of flexible nanowire electrode in practical applications. Herein, a simple alcohol‐based solution approach is proposed to weld crossed silver nanowires by chemically growing silver “solder” at the junctions of the nanowires, forming transparent silver nano‐network electrodes with improved electrical conductivity and operational stability. Remarkably, silver nano‐networks can be rapidly formed by this simple approach under ambient condition and room temperature, requiring no assistance from heat, light, electrical current, or mechanical pressure. Furthermore, our results show that the nano‐network electrode formed from large diameter nanowires offers a better operational stability, whose trend is opposite to that of the untreated electrodes. To demonstrate the potential application of the highly stable silver nano‐network from large diameter nanowires, organic solar cells fabricated on the nano‐network electrode incorporated with silicon dioxide nanoparticles achieve comparable performance to the ITO control device. Consequently, strategy demonstrated in this work can contribute to low‐cost and highly stable transparent electrodes in emerging flexible optoelectronics.     

FPD气相色谱法测定液晶材料中微量有机膦杂质

建立了一种液晶材料中微量有机膦杂质的FPD气相色谱分析测试方法,可以同时测试液晶材料中微量三苯基氧膦和三苯基膦杂质。方法重现性好,结果相对标准偏差(RSD,n=5)分别为4.4%和5.6%,有机膦杂质的添加回收率为80%~110%。实验对于液晶材料工业化过程中膦成分的分析方法建立具有较好的指导意义。     

2,2-双(4-氯-2-氟苄基)丙二酸二乙酯的晶体结构和密度泛函理论研究

标题化合物是一个重要的精细化工中间体,可用于制备嘧啶类、吡唑类等产品.本文利用红外光谱(IR)、质谱(MS)、核磁共振氢谱(1 H NMR)、核磁共振碳谱(13 C NMR)和X-射线单晶衍射对此化合物进行了表征,并在B3LYP/6-311G(d,p)模式下使用密度泛函理论(DFT)计算了此化合物的最稳定晶体结构以及最...     

Azides in the Synthesis of Various Heterocycles

In this review, we focus on some interesting and recent examples of various applications of organic azides such as their intermolecular or intramolecular, under thermal, catalyzed, or noncatalyzed reaction conditions. The aforementioned reactions in the aim to prepare basic five-, six-, organometallic heterocyclic-membered systems and/or their fused analogs. This review article also provides a report on the developed methods describing the synthesis of various heterocycles from organic azides, especially those reported in recent papers (till 2020). At the outset, this review groups the synthetic methods of organic azides into different categories. Secondly, the review deals with the functionality of the azido group in chemical reactions. This is followed by a major section on the following: (1) the synthetic tools of various heterocycles from the corresponding organic azides by one-pot domino reaction; (2) the utility of the chosen catalysts in the chemoselectivity favoring C−H and C-N bonds; (3) one-pot procedures (i.e., Ugi four-component reaction); (4) nucleophilic addition, such as Aza-Michael addition; (5) cycloaddition reactions, such as [3+2] cycloaddition; (6) mixed addition/cyclization/oxygen; and (7) insertion reaction of C-H amination. The review also includes the synthetic procedures of fused heterocycles, such as quinazoline derivatives and organometal heterocycles (i.e., phosphorus-, boron- and aluminum-containing heterocycles). Due to many references that have dealt with the reactions of azides in heterocyclic synthesis (currently more than 32,000), we selected according to generality and timeliness. This is considered a recent review that focuses on selected interesting examples of various heterocycles from the mechanistic aspects of organic azides.