5G网络中DR-OC型D2D通信收益模型及定价研究

Device-to-Device(D2D)通信是下一代(5G)移动网络的重要组成部分。D2D设备间在不依赖基站的情况下直接进行数据传输,并通过重复使用蜂窝小区的频率资源从而提高移动通信系统的容量。为了激励蜂窝网络用户参与到D2D通信,运营商对D2D通信的定价是一个很关键的问题。文中首先介绍了D2D的基本概念及其四种主要类型,并就其中DR-OC型D2D通信定价提出了运营商和D2D设备的收益模型,然后仿真分析了网络中谱单价和奖励带宽对双方收益的影响。仿真结果显示运营商可以通过调整奖励带宽来协调双方收益以激励更多的用户参与到D2D通信。     

基于载波相移系统的二倍频光电振荡器

为了扩展光电振荡器(OEO)的频率范围,设计了 一种基于载波相移系统的二倍频OEO(FD-OEO)。 系统采用相位调制器(PM)和Mach-Zehnder调制器(MZM)并联,构成载波相移系统,利用载 波相移双边带(CPS-DSB) 调制的方法产生二次谐波分量;同时利用啁啾光纤布拉格光栅(CFBG)色散特性实现边带分 量与CPS补偿,维持 OEO环路中基频信号的振荡。实验结果显示,在OEO环路系统基频信号为2.23GHz情况下,产生了4.30 GHz的FD信号,且通过边模抑制性能、稳定性及相位噪声对系统性能进行了验证。     

Integrated Devices to Realize Energy Conversion and Storage Simultaneously

Other forms of energy are generally converted to electric energy and then transported to electrochemical devices, where the energy is stored, by external electric wires. To further improve total energy conversion and storage efficiency, interest in simultaneously realize the energy conversion and storage in a single device has increased. This Concept describes recent progress in developing such novel integrated energy devices. Both planar and wire architectures are carefully illustrated with an emphasis on the “energy wire” which has been the focus of past developments due to its unique and promising applications, such as being woven into clothes or other complex structures by conventional textile technology. The current challenges and future directions of the integrated devices, particularly in the wire architecture, are summarized.     

A Bipodal Dicyano Anchor Unit for Single‐Molecule Spintronic Devices

The conductance through single 7,7,8,8‐tetracyanoquinodimethane (TCNQ) connected to gold electrodes is studied with the nonequilibrium Green’s function method combined with density functional theory. The aim of the study is to derive the effect of a dicyano anchor group, ?C(CN)₂, on energy level alignment between the electrode Fermi level and a molecular energy level. The strong electron‐withdrawing nature of the dicyano anchor group lowers the LUMO level of TCNQ, resulting in an extremely small energy barrier for electron injection. At zero bias, electron transfer from electrodes easily occurs and, as a consequence, the anion radical state of TCNQ with a magnetic moment is formed. The unpaired electron in the TCNQ anion radical causes an exchange splitting between the spin‐α and spin‐β transmission spectra, allowing the single TCNQ junction to act as a spin‐filtering device.     

Theoretical Study on the Structural and Optoelectronic Properties of the Linear Perfluorooctane Sulfonate （PFOS）

The perfluoroalkyl substances(PFS) have attracted considerable attention in recent years as a persistent global pollutant to be able to bioaccumulate in higher organisms.In this paper,theoretical analysis on electronic structures,optoelectronic properties and absorption spectra properties of the perflurooctane sulfonate(PFOS) in gas phase have been investigated by using the DFT/TD-DFT method.The geometric structures,electrostatic potentials,energy gaps,ionization potentials,electron affinities,frontier molecular orbital,excitation energies and absorption spectra for the ground state of PFOS were calculated.The result indicates that the ability of accepting electron of neutral PFOS is larger than that of anionic PFOS,while the electron excited by UV irradiation from HOMO to LUMO in the anionic PFOS is easier than that in the neutral PFOS.     

An Automatic Molecular Dispenser of Chloride

The combined activity of the 1.1.1‐cryptand and of a dicopper(II) bistren cryptate complex including chloride makes the Cl^? ion be continuously and slowly delivered to the solution, without any external intervention. The 1.1.1‐cryptand slowly releases OH^? ions, according to a defined kinetics, and each OH^? ion displaces a Cl^? ion from the cryptate. Chloride displacement induces a sharp colour change from bright yellow to aquamarine and can be conveniently monitored spectrophotometrically, even in diluted solutions. The 1.1.1‐cryptand is the motor of a molecular dispenser (the dicopper(II) cryptate) delivering chloride ion automatically, from the inside of the solution.     

Biomimetic Synthesis of Materials for Technology

In a world with ever decreasing natural reserves, researchers are striving to find sustainable methods of producing components for technology. Bioinspired, biokleptic and biomimetic materials can be used to form a wide range of technologically relevant materials under environmentally friendly conditions. Here we investigate a range of biotemplated and bioinspired materials that can be used to develop components for devices, such as optics, photonics, photovoltaics, circuits and data storage.     

Efficient Green‐Light‐Emitting Electrochemical Cells Based on Ionic Iridium Complexes with Sulfone‐Containing Cyclometalating Ligands

A new approach to obtain green‐emitting iridium(III) complexes is described. The synthetic approach consists of introducing a methylsulfone electron‐withdrawing substituent into a 4‐phenylpyrazole cyclometalating ligand in order to stabilize the highest‐occupied molecular orbital (HOMO). Six new complexes have been synthesized incorporating the conjugate base of 1‐(4‐(methylsulfonyl)phenyl)‐1 H‐pyrazole as the cyclometalating ligand. The complexes show green emission and very high photoluminescence quantum yields in both diluted and concentrated films. When used as the main active component in light‐emitting electrochemical cells (LECs), green electroluminance is observed. High efficiencies and luminances are obtained at low driving voltages. This approach for green emitters is an alternative to the widely used fluorine‐based substituents in the cyclometalating ligands and opens new design possibilities for the synthesis of green emitters for LECs.