全文获取类型
收费全文 | 19385篇 |
免费 | 3399篇 |
国内免费 | 2403篇 |
专业分类
化学 | 4967篇 |
晶体学 | 445篇 |
力学 | 672篇 |
综合类 | 90篇 |
数学 | 174篇 |
物理学 | 10506篇 |
无线电 | 8333篇 |
出版年
2024年 | 41篇 |
2023年 | 91篇 |
2022年 | 272篇 |
2021年 | 383篇 |
2020年 | 392篇 |
2019年 | 282篇 |
2018年 | 319篇 |
2017年 | 627篇 |
2016年 | 747篇 |
2015年 | 753篇 |
2014年 | 1189篇 |
2013年 | 1136篇 |
2012年 | 1592篇 |
2011年 | 1602篇 |
2010年 | 1254篇 |
2009年 | 1382篇 |
2008年 | 1654篇 |
2007年 | 1687篇 |
2006年 | 1673篇 |
2005年 | 1307篇 |
2004年 | 1151篇 |
2003年 | 895篇 |
2002年 | 608篇 |
2001年 | 588篇 |
2000年 | 551篇 |
1999年 | 434篇 |
1998年 | 402篇 |
1997年 | 373篇 |
1996年 | 343篇 |
1995年 | 278篇 |
1994年 | 263篇 |
1993年 | 196篇 |
1992年 | 173篇 |
1991年 | 142篇 |
1990年 | 117篇 |
1989年 | 70篇 |
1988年 | 54篇 |
1987年 | 33篇 |
1986年 | 23篇 |
1985年 | 28篇 |
1984年 | 17篇 |
1983年 | 14篇 |
1982年 | 16篇 |
1981年 | 6篇 |
1979年 | 6篇 |
1978年 | 2篇 |
1976年 | 4篇 |
1975年 | 7篇 |
1974年 | 3篇 |
1973年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
355nm Nd∶YAG激光在H_2中的高效一级斯托克斯转换 总被引:1,自引:1,他引:0
对脉冲Nd∶YAG激光(355 nm)在H2和H2∶He-Ar混合气体中的受激拉曼散射(SRS)进行了研究。在0.5 MPa的氢气中,同时测量到从二级反斯托克斯到三级斯托克斯的多波长输出,其总转化效率达88%;而高压下只剩下一级和二级斯托克斯输出,其中二级斯托克斯最大能量转化效率达44%(对应量子效率为63%)。由于高级斯托克斯的竞争,纯氢气中一级斯托克斯的最大能量转换效率不超过43%。通过向3 MPa氢气中掺入2 MPaAr气后,很好地抑制了二级斯托克斯的产生,从而获得了能量转换效率高达71%(对应量子效率为83%)的一级斯托克斯输出。对四波混频和级联受激拉曼散射在氢气多级斯托克斯产生中的作用以及惰性气体对它们的影响进行了讨论。 相似文献
12.
13.
通过分析计算,设计了一种大口径宽视场折射式红外相机光学系统。该系统设计用于超长线阵扫描红外相机的地面演示成像,它能同时对短波2μm—3μm、中波3μm—4.5μm双波段成像,且同时具有24°的大视场和150mm的宽口径,成像质量接近衍射极限。该系统在航天遥感领域应用广泛。 相似文献
14.
15.
16.
V. Balek T. Mitsuhashi I.M. Bountseva H. Haneda Z. Malek J. Šubrt 《Journal of Sol-Gel Science and Technology》2003,26(1-3):185-189
The diffusion structural analysis (DSA) was used to characterize microstructure changes of hydrous titania gel films under in situ conditions of heating. TG and DTA were used in order to elucidate the processes controlling the formation of anatase film during heating of hydrous titania gel film. The annealing of porosity and near surface structure defects of the dehydrated titania films was indicated by DSA in the temperature range 255–700°C as the decrease of radon release rate. It was demonstrated that the annealing was enhanced on heating in oxygen in comparison with heating in argon. The DSA experimental results were compared with model curves describing the radon diffusion mobility and the annealing of radon diffusion paths. 相似文献
17.
18.
Philip A. Wheeler Michael Brungs Graham R. Atkins 《Journal of Sol-Gel Science and Technology》2003,27(3):321-326
Organically modified silicates (ormosils) have been viewed as possible materials for optical signal processing devices for communications networks. One significant problem obstructing their use in this application is the absorption of infrared light by hydroxy species (present for example in silanol groups (SiOH) and water) around the communications wavelengths (1310 and 1550 nm). We have investigated several ormosil compositions, synthesised via an aqueous sol-gel method, to determine if residual hydroxy groups can be removed more effectively via reducing the connectivity of the material by increasing the number of organic groups (such as Si—CH3). Furthermore, we have investigated the effect of different inert atmospheres on the drying process. It was found that reducing the connectivity does promote the removal of hydroxy absorption, mainly via the condensation of residual silanol groups, but also by removal of residual water, depending on the other precursors in the system. It was also found that the drying atmosphere used (nitrogen or helium) had no effect on the drying process. 相似文献
19.
Junchai Zhao Shichun Jiang Xiangling Ji Lijia An Bingzheng Jiang 《Journal of Polymer Science.Polymer Physics》2004,42(18):3496-3504
The surface morphologies of poly(styrene‐b‐4vinylpyridine) (PS‐b‐P4VP) diblock copolymer and homopolystyrene (hPS) binary blend thin films were investigated by atomic force microscopy as a function of total volume fraction of PS (?PS) in the mixture. It was found that when hPS was added into symmetric PS‐b‐P4VP diblock copolymers, the surface morphology of this diblock copolymer was changed to a certain degree. With ?PS increasing at first, hPS was solubilized into the corresponding domains of block copolymer and formed cylinders. Moreover, the more solubilized the hPS, the more cylinders exist. However, when the limit was reached, excessive hPS tended to separate from the domains independently instead of solubilizing into the corresponding domains any longer, that is, a macrophase separation occurred. A model describing transitions of these morphologies with an increase in ?PS is proposed. The effect of composition on the phase morphology of blend films when graphite is used as a substrate is also investigated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3496–3504, 2004 相似文献
20.
The crystallization of poly(ethylene terephthalate) under uniaxial tensile strain at different extension rates was investigated with optical polarimetry in a temperature range between the glass-transition temperature and the quiescent crystallization temperature. The evolution of the optical properties of the polymer, including the turbidity, birefringence, and dichroism, were monitored simultaneously with the mechanical parameters. To complete the semicrystalline microstructure characterization of the polymer under strain, an online wide-angle X-ray diffraction (WAXD) technique was used in separate experiments, which were performed under the same thermomechanical conditions. For real-time measurements, a high-energy synchrotron radiation source was used. The optical properties provided information about both the crystalline and amorphous phases, whereas the WAXD patterns essentially gave information about the crystalline phase. The two experimental techniques were then used in a complementary way to characterize the semicrystalline microstructure. Significant deviations from the stress-optical rule were found. This was attributed to both transient effects and the appearance of crystallites, which consisted of highly oriented molecular segments that could contribute to the optical anisotropy but not necessarily to the stress. The behavior of the optical dichroism was found to be qualitatively different from that of the birefringence. The latter monotonically increased with the strain, whereas the former first increased with the strain, passed through a maximum, and then decreased to a steady-state value. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1915–1927, 2004 相似文献