A New Chemo‐Enzymatic Route to Side‐Chain Liquid‐Crystalline Polymers: The Synthesis and Polymerization of 6‐(4‐Methoxybiphenyl‐4′‐oxy)hexyl Vinyl Hexanedioate

A novel synthetic method combining chemo and enzymatic synthesis strategies was employed to prepare a vinyl acetate type monomer, 6‐(4‐methoxybiphenyl‐4′‐oxy)hexyl vinyl hexanedioate (VA‐LC). Homo‐ and copolymers of VA‐LC with maleic anhydride (MAn) were prepared by conventional free radical polymerization using 2,2′‐azobisisobutyronitrile (AIBN) and 1,1′‐azobis (cyclohexane carbonitrile) (AHCN) as an initiator at 95 and 60 °C, respectively. The thermal properties of the generated polymeric material were investigated by differential scanning calorimetry (DSC), and the optical texture was inspected by polarizing optical microscopy (POM). While the monomer VA‐LC does not exhibit liquid‐crystalline properties, poly(VA‐LC), and the alternating copolymer of VA‐LC with maleic anhydride both displayed such properties.

     

Trifluoromethyl- and difluoromethyl-β-lactams as useful building blocks for the synthesis of fluorinated amino acids, dipeptides, and fluoro-taxoids

Enantiopure 1-acyl-3-hydroxyl-4-CF₂H-azetidin-2-ones and 1-acyl-3-hydroxy-4-CF₃-azetidin-2-ones serve as versatile intermediates for the syntheses of CF₂- and CF₃-containing α-hydroxy-β-amino acids, dipeptides, and taxoid anticancer agents. Both enantiomers of 3-hydroxy-4-CF₂H-β-lactams can be obtained in high yields through the diethylaminosulfur trifluoride (DAST) reaction of the corresponding enantiopure 4-formyl-β-lactam that is prepared through [2+2] cycloaddition of acetoxyketene to a 3-methyl-2-butenaldimine, followed by enzymatic optical resolution and ozonolysis. (+)-3-Hydroxy-4-CF₃-β-lactams and (−)-3-hydroxy-4-CF₃-β-lactams can also be readily obtained in enantiopure form through [2+2] cycloaddition of a CF₃-imine with a ketene, followed by enzymatic optical resolution. Practical processes for the preparations of these enantiopure 3-hydroxy-4-R_f-β-lactams as well as their synthetic applications are described.     

DWDM上25.344 Mbit/s光监控信息传送系统的设计

采用25.344 Mbit/s光监控信息传送技术可以更好地满足当前密集波分复用(DWDM)系统中不断增加的网络监控信息和附加业务的需要.文章首先介绍了25.344 Mbit/s光监控信息传送系统的技术方案,然后详细描述了其帧结构、码型设计以及硬件实现的框图,最后介绍了该技术的优点.     

Quantum Stream Cipher Based on Holevo–Yuen Theory

In this review paper, we first introduce the basic concept of quantum computer-resistant cryptography, which is the cornerstone of security technology for the network of a new era. Then, we will describe the positioning of mathematical cryptography and quantum cryptography, that are currently being researched and developed. Quantum cryptography includes QKD and quantum stream cipher, but we point out that the latter is expected as the core technology of next-generation communication systems. Various ideas have been proposed for QKD quantum cryptography, but most of them use a single-photon or similar signal. Then, although such technologies are applicable to special situations, these methods still have several difficulties to provide functions that surpass conventional technologies for social systems in the real environment. Thus, the quantum stream cipher has come to be expected as one promising countermeasure, which artificially creates quantum properties using special modulation techniques based on the macroscopic coherent state. In addition, it has the possibility to provide superior security performance than one-time pad cipher. Finally, we introduce detailed research activity aimed at putting the quantum stream cipher into practical use in social network technology.     

基于石墨烯的布洛赫表面波调控特性研究

布洛赫表面波(Bloch surface wave,BSW) 具有传输损耗低、显著表面局域场增强、环境敏感等特性,因而被视为研究近场光和物质相互作用的关键技术。其主要在截断的一维光子晶体与外界介质的界面激发并沿此界面传播,通过传播界面微纳结构的设计,可在纳米尺度实现对BSW的有效调控。本文从BSW的模式特性出发,提出了石墨烯加载的一维光子晶体BSW传感器件结构。通过改变石墨烯层的结构参数,调节激发模式在光子带隙中的位置,研究激发模式的光场传输特性,实现对BSW激发波长、振幅和相位的调控。进一步利用其对外界介质折射率变化非常敏感的特性,对其传感检测能力进行研究。结果表明,该器件有望实现高灵敏度的生化传感检测应用。该研究为新型BSW集成光子器件的设计与发展提供了新思路。     

微流控光脉冲调制器

为了解决常见光调制器偏振依赖或结构复杂的问题,本文基于微流控光学提出一种可控光脉冲调制器。利用基于T形结产生的离散液滴和全反射原理的微流控光开关,将连续光变换成数字脉冲信号,并通过调节液滴的长度和生成速率调制光脉冲的宽度和频率。所提微流控光脉冲调制器具有结构简单、插入损耗低、消光比高、易集成的优点。微流控光脉冲调制器的流场与光场特性被分析,结构被优化。研究结果显示：该光脉冲调制器的消光比为17.74 dB,插入损耗为0.49 dB。     

一种高性能太阳敏感器复合光学系统设计

以夫朗禾费衍射理论为基础,结合微透镜,设计了一种高性能的数字式太阳敏感器复合光学系统。分析了光学系统的组成,建立了光学系统的数学模型,设计了光学系统的焦距、孔径和微透镜参量,并进行了成像的数值仿真。仿真结果表明,与基于掩模的光学系统相比,这种新型的复合光学系统成像光斑能量分布集中,保证计算光斑中心位置的高精度,使敏感器具有大视场和高精度的特点。     

动态场景下基于视觉的SLAM技术研究

针对视觉同时定位与地图构建(SLAM)技术在动态环境中存在定位精度低、地图虚影等问题,提出了一种基于深度学习的动态SLAM算法。该算法利用网络参数少且目标识别率高的YOLOv8n改善系统的视觉前端,为视觉前端增加语义信息,提取动态区域特征点。然后采用LK光流法识别动态区域的动态特征点,剔除动态特征点并保留动态区域内的静态特征点,提高特征点利用率。此外,该算法通过增加地图构建线程,剔除YOLOv8n提取的动态物体点云,接收前端提取的语义信息,实现静态语义地图构建,消除由动态物体产生的虚影。实验结果显示,在动态环境下该算法与ORB-SLAM3相比,定位精度提升92.71%,与其他动态视觉SLAM算法相比,也有小幅度改善。     

基于激光器RIN抑制的宽带低噪声微波光传输技术

微波光子链路中的核心器件激光器、调制器、光电探测器均为有源器件,在微波信号的电光光电转换过程中会引入额外的噪声,导致微波信号的噪声性能恶化,高的噪声系数会降低电子信息系统的灵敏度、动态范围、探测精度等关键性能指标,因此抑制噪声成为实现高性能微波光子系统的关键。文章针对当前激光器噪声较高的限制,提出采用常规分布反馈(DFB)激光器与光放大器、窄带光子滤波相组合的方式来抑制激光源噪声,实现微波光子链路的宽带低噪声。建立了微波光子链路传输模型,分析了链路性能与器件参数之间的映射关系。实测对比了采用该组合光源方案与常规微波光子链路的噪声性能,结果表明采用高功率光源结合光滤波可对激光器远端相对强度噪声(RIN)实现高的抑制,通过优化,噪声系数较常规水平可改善15 dB以上。     

基于DFB激光器的振动传感系统改进PGC解调算法

相位生成载波(Phase Generated Carrier, PGC)解调算法是目前光纤干涉传感领域中重要的解调算法。针对目前PGC解调算法中光强扰动和调制深度影响信号解调准确度的问题,提出了一种改进的PGC解调算法(PGC-Ameliorated),并搭建了基于分布反馈(Distributed Feedback, DFB)激光器的振动传感系统进行实验验证。实验结果表明,当被测振动信号的频率为800 Hz时,该算法信噪比为57 dB,优于微分交叉相乘(Differential and Cross Multiplying, DCM)算法和反正切(Arctan)算法近20 dB。在不同光强下,该算法解调信号幅值波动范围在±0.02 rad;在不同调制深度下,该算法总谐波失真最小为0.61%,信纳比最大为25.9 dB,相比于DCM算法和Arctan算法具有更低的总谐波失真和更高的信纳比。