LTE通信基站市电引入设计中应该考虑的问题

LTE通信基站市电引入的设计是基站建设的首要环节,直接关系到基站供电的可靠性和安全性,对通信网络的安全运行起到关键的作用。基站市电引入的设计多数由施工单位自行设计施工,造成基站市电引入方式出现较混乱的局面,不合理的设计施工会造成巨大的经济损失。做好基站市电引入设计,使市电引入方式合理化、简单化,在加大可靠性和安全性的基础上,降低投资成本,减少维护量能保障通信畅通,提高经济效益。     

Electrochemical Simultaneous Sensing of Melatonin,Dopamine and Acetaminophen at Platinum Doped and Decorated Alpha Iron Oxide

Simultaneous sensing of dopamine (DA), acetaminophen (AP) and melatonin (MEL) was made by electrochemical method as the drugs melatonin and acetaminophen interact with dopamine in brain to induce neuro disorders. The glassy carbon electrode surface was modified with un‐doped α‐ Fe₂O₃, platinum doped Fe₂O₃ (dPtFe₂O₃), Pt decorated Fe₂O₃ (sPtFe₂O₃) and doped and decorated Fe₂O₃ (sdPtFe₂O₃) nano particles that are synthesized by co‐precipitation method in presence of polyethylene glycol for the first time. These particles were characterized using Ultra‐Violet Visible (UV‐Vis), scanning electron microscopy (SEM), X‐ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), thermo gravimetric analysis (TGA) and electrochemical techniques. The sdPtFe₂O₃ showed the highest catalytic activity than the dPtFe₂O₃, sPtFe₂O₃ and un‐doped α‐ Fe₂O₃ with well separated voltammetric peaks for DA and AP in presence of MEL. This is attributed to higher surface hydration effects of the sdPtFe₂O₃, dPtFe₂O₃ and sPtFe₂O₃ than the un‐doped Fe₂O₃ which plays a vital role in enhancing the melatonin sensing in presence of dopamine and acetaminophen. Linear ranges and lowest detection limits for all three analytes were increased by 10 times for the sdPtFe₂O₃ compared to other Fe₂O₃ modified electrodes. The sensor is validated using commercially available pharmaceutical drugs used in therapeutics.     

Chiral sensing of Eu(III)‐containing achiral polymer complex from chiral amino acids coordination induction

The β‐diketonate‐based achiral polymer P‐1 could be synthesized by the polymerization of 3,7‐dibromo‐2,8‐dimethoxy‐5,5‐dioctyl‐5H‐dibenzo[b,d]silole ( M1 ) with (Z)?1,3‐bis(4‐ethynylphenyl)?3‐hydroxyprop‐en‐1‐one ( M2 ) via typical Sonogashira coupling reaction. The β‐diketonate unit in the main chain backbone of P‐1 can further coordinate with Eu(TTA)_x [TTA^? = 4,4,4‐trifluoro‐1‐(thiophen‐2‐yl)butane‐1,3‐dionate anion, X = 1, 2, 3] to afford corresponding Eu(III)‐containing polymer complexes. The resulting achiral polymer complex P‐2 (X = 2) can exhibit strong circular dichroism (CD) response toward both N‐Boc‐l and d‐ proline enantiomers. The CD signal was preliminarily attributed to coordination induction between chiral N‐Boc‐proline and the Eu(III) complex moiety. The linear regression analysis of CD sensing shows a good agreement between the magnitude of molar ellipticity and concentration of chiral N‐Boc‐l or d‐ proline, which indicates this kind Eu(III)‐containing achiral polymer complex can be used as a chiral probe for enantioselective recognition of N‐Boc‐l or d‐ proline enantiomers based on Cotton effect of CD spectra. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 3080–3086     

Propagating surface plasmon polaritons for remote excitation surface-enhanced Raman scattering spectroscopy

To illustrate the attractive potentials of remote-excitation surface enhanced Raman scattering (RE-SERS), we review the fundamental concepts and typical applications of propagating surface plasmon polaritons (PSPPs). Based on the RE-SERS technic, the adsorbed molecules are protected from being directly illuminated, while the merits of SERS still remained. However, the critical limitations of applying RE-SERS hinder its rapid development. Hence, drawing an overview about the PSPPs would be beneficial for further promoting the significance of RE-SERS in biological application and investigating the mechanism of surface catalytic reactions.     

Ethylthio-substituted sandwich phthalocyaninato europium (III) semiconductors for sensing NO2 and NH3: Effect of the extended π-conjugate systems on tuning the conductivity and sensing behavior

By using the π-conjugated phthalocyanine macrocycle as the versatile building block, a series of five sandwich-type ethylthio substituted phthalocyaninato europium complexes, namely double-decker Eu[Pc(SC₂H₅)₈]₂ (Pc-1), triple-decker Eu₂[Pc(SC₂H₅)₈]₃ (Pc-2), and their corresponding dimers, [Pc(SC₂H₅)₈]₂Eu₂[BiPc(SC₂H₅)₁₂] (Pc-1@Pc-1), [Pc(SC₂H₅)₈]₃Eu₃[BiPc(SC₂H₅)₁₂] (Pc-1@Pc-2) and [Pc(SC₂H₅)₈]₄Eu₄[BiPc(SC₂H₅)₁₂] (Pc-2@Pc-2), are synthesized and prepared into the solution-processed films by a simple quasi-Langmuir-Shäfer (QLS) method. Combination between the extending π-conjugated system in the longitudinal and transverse directions of Pc macrocycles and/or radical nature of Pc-1 unit among different semiconducting molecules result in unusually small energy gaps (0.345–0.91 eV). Consequently, all of the semiconductors exhibit excellent conductivities. Among these materials, the conductivity for the radical species Pc-1@Pc-1, Pc-1@Pc-2 and Pc-1 is about 3–4 times larger than that for the non-radical compounds Pc-2@Pc-2 and Pc-2. Moreover, the QLS films of five semiconductors take excellent linear responses for both oxidizing NO₂ (100–300 ppb) and reducing NH₃ (4–8.6 ppm). Respectively, the sensitivity (in % ppm⁻¹) gets increased in the order of Pc-1 < Pc-2 < Pc-1@Pc-1 < Pc-1@Pc-2 < Pc-2@Pc-2 for NO₂, and Pc-1@Pc-2 < Pc-1 < Pc-1@Pc-1 < Pc-2@Pc-2 < Pc-2 for NH₃. Depending on the highly extended π-conjugated systems, Pc-2@Pc-2 and Pc-2 films achieve the highest sensitivity of 208.2% ppm⁻¹ and 0.97% ppm⁻¹ to NO₂ and NH₃, respectively. In addition, with a less than 2 min response time within a limit of detection at 10 ppb for NO₂ and 0.48 ppm for NH₃, good reproducibility and selectivity have been revealed for the Pc-2@Pc-2 and Pc-2 films among the best gas sensors obtained so far for all the solution-processed films based on organic semiconductors in dry air at room temperature. More importantly, it is firstly demonstrated that the high NO₂ sensing is resulted from low Oxd₁, and high NH₃ sensing is resulted from high Red₁ among the sandwich Pc-based semiconductors.     

Sensing and photocatalytic properties of nanosized Cu(I)CN organotin supramolecular coordination polymer based on pyrazine

Orange prismatic crystals of the supramolecular coordination polymer (SCP) _∞³[Cu(CN)₂(Me₃Sn)(Pyz)], SCP 1 , were synthesized using a self‐assembly method under ambient conditions. Nanosized 1 was obtained using the same molar ratio in water by ultrasonic irradiation. SCP 1 was characterized using single‐crystal X‐ray diffraction, elemental analysis, thermal analysis and Fourier transform infrared spectroscopy. SCP 1 and its nanosized 1 particles were also examined using powder X‐ay diffraction and scanning electron microscopy. The luminescence emission of SCP 1 was studied as well as its use as a sensor for the detection of common organic solvents and metal ions. Also, the catalytic activities of nanosized 1 towards various organic dyes were investigated under ambient conditions, UV irradiation and ultrasonic irradiation. Nanosized 1 as a heterogeneous nanoparticle catalyst exhibits high catalytic activity for the degradation of eosin‐Y and acid blue dyes. The mechanism of degradation investigated using various scavenger techniques is proposed and discussed. The catalytic oxidation process is mainly caused by ?OH radicals.     

Joint optimal fair cooperative spectrum sensing and transmission in cognitive radio

Since the sensing power consumption of cooperative spectrum sensing (CSS) will decrease the throughput of secondary users (SU) in cognitive radio (CR), a joint optimal model of fair CSS and transmission is proposed in this paper, which can compensate the sensing overhead of cooperative SUs. The model uses the periodic listen-before-transmission method, where each SU is assigned a portion of channel bandwidth, when the primary user (PU) is estimated to be free by the coordinator. Then, a joint optimization problem of local sensing time, number of cooperative SUs, transmission bandwidth and power is formulated, which can compensate the sensing overhead of cooperative SUs appropriately through choosing suitable compensating parameter. The proposed optimization problem can be solved by the Polyblock algorithm. Simulation results show that compared with the traditional model, the total system throughput of the fairness cooperation model decreases slightly, but the total throughput of the cooperative SUs improves obviously.     

Thermal measurements using ultrasonic acoustical pyrometry

Reflections from geometric discontinuities can be used with ultrasonic energy to predict the temperature of an interface where classical temperature measurement techniques are impractical because of physical access limitations or harsh environmental conditions. Additionally, these same ultrasonic measurements can be used with inversion methods commonly applied to ill-posed heat transfer problems to increase the accuracy of the measurement of surface temperature or heat flux at the surface of interest. Both methods for determining surface temperature are presented, along with a comparison of results both from a verification example and using data gathered in a field test of the methods. The results obtained with these two methods are shown to be in good agreement with an empirical relationship used in the design of large caliber guns.     

一种快速发现考试作弊信号的方法

简要介绍了基于压缩感知理论,对重构随机出现的考试作弊信号进行了仿真实验,理论实验表明,基于压缩感知理论的信号重构算法可以快速有效的发现随机出现的作弊信号,为后续的阻断工作奠定了基础。