Applicability of reversed-phase liquid chromatography for the speciation of vanadyl and nickel metalloporphyrins in oil extracts

Summary Gradient reversed-phase liquid chromatography was examined with a view to using it as a separation technique for the speciation of vanadyl and nickel porphyrins in oil extracts. Poor separations were obtained when precipitation of the sample constituents occurred in the starting mobile phase. The reasons for the precipitation phenomena were found to be highly complex. Mixed crystal formation, slow dissolution kinetics and saturation may influence the elution behaviour of species present in the oil extracts. When precipitation was avoided the separation of the vanadyl porphyrins was significantly improved. Thus far, no satisfactory separations have been obtained for the nickel porphyrinic species.Although the occurrence of precipitation of the extracts hinders the distinct speciation of metalloporphyrins with reversed phase chromatography, the precipitation/dissolution phenomena showed some interesting features as a clean-up step for diluted crude oil samples and oil fractions.     

Numerical Experiments with Various Formulations for Two Phase Flow in Petroleum Reservoirs*

Two phase immiscible flow in petroleum reservoirs is considered. Various formulations of the governing equations that describe this flow, including phase, global, and weighted formulations, are numerically experimented. Mixed finite element methods are used to solve these formulations. Our experiments show that the numerical results obtained using the phase and global formulations match well in terms of production rates, characterization curves, and water cuts.     

机载激光水深测量精度分析

分析了机载激光水深测量系统中的深度反演方法，着重讨论波浪潮汐改正法和利用动态全球定位系统-相位模糊度解算技术(KGPS-OTF)所测参量进行归算的方法(无修正法)。综合分析影响机载激光测深精度的各项参量，并利用机载激光雷达的技术参数，定量估算了两种方法的水深提取精度。结果表明，波浪潮汐改正法的精度略高于无修正法，但是无修正方法更加简单明了，数据后处理的计算量也可大大减小。     

An application of the capacitance matrix method to accommodate masked land areas and island circulations in a primitive equation ocean model

The capacitance matrix method has been implemented in a primitive equation ocean model to accommodate islands and portions of irregular coastal boundaries that cannot be treated adequately by boundary-fitted orthogonal curvilinear co-ordinates. The algorithm preserves the ability to solve the streamfunction equation using fast and accurate elliptic solvers that require a rectangular computational domain. By superposition of a set of island Green functions, the solution is adjusted to ensure continuity of pressure around each island. The implementation is tested by comparison with an analytic solution for wind-driven flow in a closed basin similar to the southwest Pacific Ocean.     

利用星载ERS-2 SAR进行长江口海面风场反演研究

基于SAR图像反演原理,提出一种后向散射系数反演海面风场的新方法,以相关长度确定风向,再利用随机粗糙海面理论模型反演风速.并以ERS-2 SAR为数据源,以长江口海区为研究区,获取了海面风场，反演结果和浮标测量风场对比,相符得很好,证明了该方法的可行性。     

Bioremediation of Aged Petroleum Oil Contaminated Soil: From Laboratory Scale to Full Scale Application

Large quantity of aged petroleum oil contamination such as dehydrated oil sludge, generated in the disposal process of oil-containing sewage in Indonesia. This study aims to investigate the OSCS removal by mean of bioremediation technique. Results found that petrofilic consortia and biosurfactants addition increased the removal efficiency up to 46% and 85%, respectively. At full scale application, this technique succeed in removing of 46 g TPH per kg soil from 4 883 m³ of OSCS during 16 mo of treatment. These results suggest that petrofilic consortia and biosurfactants addition stimulate the biodegradation and overcome the limitation of OSCS degradation process.     

复模态理论在近海平台中的应用

运用复模态理论对考虑海洋平台结构与流体相互作用而引起的非经典阻尼问题进行了理论分析。水中耦合阻尼矩阵运用复模态解法，可以不必近似对角化。推导了随机波浪荷载作用下结构各种反应的能量谱密度函数及结构反应的统计特性，得到了结构反应的均方差和峰值的表达式。针对某典型平台在随机波浪荷载作用下动力反应用复模态法进行了计算并与运用实模态方法多重叠代方法的结果进行了比较。     

不同滤波方法对揭示全球海洋条带结构的比较

海洋条带结构是近年物理海洋学研究的一个新热点. 在海洋中, 条带结构往往被大尺度环流过程所掩盖. 把这种隐蔽的海水运动现象显现出来的办法是对时间平均的速度场进行空间滤波. 利用全球简单海洋资料同化分析系统资料和中国科学院大气物理研究所大气科学和地球流体力学数值模拟国家重点实验室的气候系统海洋模式模拟数据对三种一维滤波方法进行了比较, 分别是常用的高斯和汉宁滤波方法, 以及本文引入的切比雪夫滤波方法. 结果表明, 尽管三种方法均可获得条带结构, 但以切比雪夫方法为最佳; 另外, 设计高通滤波器时需设定截断频率, 而它的选定取决于对具体数据的频谱分析, 当选取的归一化的截断频率值在0.1和0.4之间时, 可以有效地揭示出条带结构在全球海域内的分布. 因此本文的研究方法为海洋条带结构的深入研究提供了一个有力工具.     

毛细管气相色谱法分析液化石油气中二甲醚

建立了液化石油气中二甲醚的毛细管气相色谱分析方法.利用丙酮作为溶剂吸收液化石油气中二甲醚,采用HP-1毛细管色谱柱进行分离,以氢火焰离子化检测器检测,外标法进行定量分析.二甲醚的体积分数在0.5%～30.0%范围内与色谱峰面积呈良好线性关系,二甲醚的定量下限为0.2%,测定结果的相对标准偏差为2.3%～7.3%(n=6...     

探讨石油专网中通信电源的管理与维护

随着通信行业的不断发展,通信电源在各网络系统中的地位越发提高,尤其对于石油专网而言。文中针对石油专网中的通信电源系统进行了研究,分析了该系统的工作原理及结构组成,在此基础上,总结了石油专网通信电源系统维护管理的工作项目及方法。