一种蓄电池组智能巡检仪的设计与实现

介绍了一种用于检测、维护和管理蓄电池组的分布式智能巡检仪,通过MCU(微控制单元)检测24路蓄电池组单体电压和温度信号,将数据打包并实时地传送到CAN总线,供上位机接收、处理、分析、显示和诊断等。巡检仪可靠性强,控制电路简单,适用于各种蓄电池组的监测维护。     

铁粉为原料催化改性铁氧化物的储氢性能

以Fe粉为原料, 以金属Mo, Al和Ni可溶性盐作为添加剂, 通过浸渍法制备单金属添加和双金属添加的改性铁氧化物储氢材料Fe-Mo, Fe-Al, Fe-Mo-Ni和Fe-Mo-Al, 并研究了它们的储氢性能. 结果表明样品Fe-Mo改性效果最好: 如放氢温度由改性前的500 ℃降至改性后的290 ℃左右; 300 ℃时放氢速率最高, 由改性前的低于50 μmol•min^－1• Fe-g^－1到改性后的325 μmol•min^－1•Fe-g^－1 (10次平均); 4.53 wt%的平均实验储氢量与理论值4.8 wt%较接近; 储-放氢循环稳定性随着循环次数的增加呈逐渐增加的趋势. SEM微观结构和BET比表面积分析表明添加剂的种类对样品的改性作用更重要.     

Impact of Different Storage Regimes on the Levels of Physicochemical Characteristics,Especially Free Acidity in Talh (Acacia gerrardii Benth.) Honey

This study investigates how storage conditions (temperature and duration) may affect the physicochemical parameters, especially free acidity (FA), of Talh honey originating from Acacia gerrardii that have naturally high FA levels. Fresh Talh honey samples were kept at 0, 25, 35, and 45 °C, and analyzed monthly over a period of eight months. The Talh honey was monofloral with 69% A. gerrardii pollen content. The free acidity (FA) of freshly harvested Talh honey samples was higher (93 ± 0.3 meq/kg) than that of standard limits (≤50 meq/kg) and remained stable at 0 °C throughout the storage period. A significantly increase in FA started to occur after storage for 6 months at 25 °C (103 ± 0.2 meq/kg), 2 months at 35 °C (108 ± 0.3 meq/kg), and 1 month at 45 °C (112 ± 0.3 meq/kg). After 8 months of storage, the highest FA level was recorded at 45 °C (159 ± 0.5 meq/kg), followed by 127 ± 0.3 meq/kg at 35 °C, 105 ± 0.2 meq/kg at 25 °C, and 94 ± 0.3 meq/kg at 0 °C. It was found that 0 °C was an appropriate temperature for storing honey for long time. The electrical conductivity (EC) of fresh Talh samples (1.46 ± 0.0 mS/cm) was above the accepted limit (≤0.8 mS/cm), which was slightly increased (non-significant) throughout the storage period under all the storage temperatures. Hydroxymethylfurfural (HMF), diastase activity (DN), and reducing sugars (RSs) showed normal levels only at 0 °C and 25 °C throughout the storage period. However, HMF exceeded the standard limits after the first month at 45 °C (127 ± 9.6 mg/kg) and after the second month at 35 °C (90 ± 23.5 mg/kg), DA decreased below standard limits after the second month (5 ± 1 DN) under 45 °C and after the seventh month under 35 °C (7 ± 2 DN, and RSs decreased below 60% after 2 months under 45 °C and after 6 months at 35 °C. The physicochemical parameters (moisture content, pH, color, and sucrose) were the least affected and were within the standard range throughout the storage period under all the storage temperatures. The levels of FA and EC in fresh Talh samples were higher than the acceptable limits. The moisture content, pH, color, and sucrose content were not affected by storage conditions and remained within the acceptable limits. HMF, DA, and RSs were significantly affected by storage conditions only at 35 and 45 °C. The storage of honey at low temperatures (0 and 25 °C) for up to eight months presented the least amount of changes in the honey, and the honey was unchanged from its fresh status. Honey storage at 35 and 45 °C resulted in significant changes. It is recommended that Talh honey, which normally has high acidity levels, should be stored at temperatures not exceeding 25 °C.     

Molecular Engineering of Quinone-Based Nickel Complexes and Polymers for All-Organic Li-Ion Batteries

All-organic Li-ion batteries appear to be a sustainable and safer alternative to the currently-used Li-ion batteries but their application is still limited due to the lack of organic compounds with high redox potentials toward Li⁺/Li⁰. Herein, we report a computational design of nickel complexes and coordination polymers that have redox potentials spanning the full voltage range: from the highest, 4.7 V, to the lowest, 0.4 V. The complexes and polymers are modeled by binding low- and high-oxidized Ni ions (i.e., Ni(II) and Ni(IV)) to redox-active para-benzoquinone molecules substituted with carboxyl- and cyano-groups. It is found that both the nickel ions and the quinone-derived ligands are redox-active upon lithiation. The type of Ni coordination also has a bearing on the redox potentials. By combining the complex of Ni(IV) with 2-carboxylato-5-cyano-1,4-benzoquinones as a cathode and Ni(II)-2,5-dicarboxylato-3,6-dicyano-1,4-benzoquinone coordination polymer as an anode, all-organic Li-ion batteries could be assembled, operating at an average voltage exceeding 3.0 V and delivering a capacity of more than 300 mAh/g.     

Effect of Traditional Cooking and Sous Vide Heat Treatment,Cold Storage Time and Muscle on Physicochemical and Sensory Properties of Beef Meat

Consumers are avoiding the consumption of highly processed foods, aware of the negative effects of the additives or high temperatures used on the biological value of the food. This causes an interest in ways of minimal processing or low-temperature cooking procedures. However, to achieve the desired organoleptic quality, it is necessary to know the relationship between the parameters of the treatments and the type of raw material. The purpose of this study was to investigate the complex effects of traditional cooking and sous vide heat treatment, cold storage time and muscle on the physicochemical and sensory properties of beef. The study material consisted of samples of musculus longissimus thoracis and musculus semitendinosus obtained from beef half-carcasses. The muscles were subjected to traditional cooking in water at 95 °C until the temperature inside the piece reached 65 °C and sous vide treatment at 65 °C for 2 h. The study was performed after 2 and 21 days of cold storage. Instrumental evaluation of texture parameters, color and sensory evaluation of meat was carried out. Meat stored for 21 days was characterized by more favorable TPA test (Texture Profile Analysis) results compared to meat evaluated 48 h post mortem. The study also showed positive effects of sous vide heat treatment on texture parameters and sensory properties (especially on tenderness and palatability), as well as differences in the formation of quality traits between muscles. Given the trends associated with energy-saving technologies, it is desirable to seek the optimal combination of temperature and time of fixation treatments at an acceptable level of quality. The use of low-temperature cooking for as little as 2 h, yields positive results in sensory evaluation of juiciness, tenderness, or palatability.     

Development of Novel Polypropylene Syntactic Foams Containing Paraffin Microcapsules for Thermal Energy Storage Applications

polypropylene (PP) syntactic foams (SFs) containing hollow glass microspheres (HGMs) possess low density and elevated mechanical properties, which can be tuned according to the specific application. A possible way to improve their multifunctionality could be the incorporation of organic Phase Change Materials (PCMs), widely used for thermal energy storage (TES) applications. In the present work, a PCM constituted by encapsulated paraffin, having a melting temperature of 57 °C, was embedded in a compatibilized polypropylene SF by melt compounding and hot pressing at different relative amounts. The rheological, morphological, thermal, and mechanical properties of the prepared materials were systematically investigated. Rheological properties in the molten state were strongly affected by the introduction of both PCMs and HGMs. As expected, the introduction of HGMs reduced both the foam density and thermal conductivity, while the enthalpy of fusion (representing the TES capability) was proportional to the PCM concentration. The mechanical properties of these foams were improved by the incorporation of HGMs, while they were reduced by addition of PCMs. Therefore, the combination of PCMs and HGMs in a PP matrix generated multifunctional materials with tunable thermo-mechanical properties, with a wide range of applications in the automotive, oil, textile, electronics, and aerospace fields.     

新型全息用光致聚合物的研究

研制了一种新型全息用光致聚合物材料,其成膜树脂为胺固化环氧体系,全息记录组分为光引发自由基聚合体系.用新合成的高效光敏染料DEAMC做光敏剂,通过配方调整,制备了一系列的样片,以457 nm的蓝光为记录光,632.8 nm的红光为探针光,研究了样片的衍射效率、灵敏度、折射率调制度等全息性能.结果表明,通过调整材料的配方组成、各组分的含量及样片的膜厚等因素,可以优化样片的全息性能.对样片的信噪比损失(LSNR)测试结果表明,在全息存储的曝光量范围内对样片曝光引起的图像信噪比损失仅有0.40 dB,说明样片的光学质量高,在全息存储上将具有很好的应用前景.     

云存储中一种支持可验证的模糊查询加密方案

针对当前可查询加密方案大多不支持模糊查询的不足,并且无法应对恶意服务器的威胁,云计算亟需为用户提供一种允许拼写错误并且可以验证查询结果正确性的加密方案。同时考虑到云存储中数据经常更新,提出一种动态云存储中支持可验证的模糊查询加密方案。该方案通过编辑距离生成模糊关键词集,并基于伪随机函数、随机排列函数等技术构建安全索引,从而保护用户的数据隐私。通过RSA累加器和哈希函数验证查询结果的正确性,用于检测恶意攻击者的非法行为。安全分析证明该方案能够保护用户的隐私安全,并具有可验证性。实验结果表明该方案具有可行性与有效性。     

椭圆曲线密码处理器的高效并行处理架构研究与设计

为了解决当前椭圆曲线密码处理器普遍存在灵活性低、资源占用大的问题,该文采用统计建模的方式,以面积-时间(AT)综合性能指标为指导,提出了一种面向椭圆曲线密码并行处理架构的量化评估方式,并确定3路异构并行处理架构可使处理器综合性能达到最优。其次,该文提出一个分离分级式存储结构和一个运算资源高度复用的模运算单元,可增强存储器的访问效率和运算资源的利用率。在90 nm CMOS工艺下综合,该文处理器的面积为1.62mm2,完成一次GF(2571)和GF(p521)上的点乘运算分别需要2.26 ms/612.4J和2.63 ms/665.4J。与同类设计相比,该文处理器不仅具有较高的灵活性、可伸缩性,而且其芯片面积和运算速度达到了很好的折中。     

Wet-Chemical Synthesis of TiO2/PVDF Membrane for Energy Applications

To satisfy the ever-increasing energy demands, it is of the utmost importance to develop electrochemical materials capable of producing and storing energy in a highly efficient manner. Titanium dioxide (TiO₂) has recently emerged as a promising choice in this field due to its non-toxicity, low cost, and eco-friendliness, in addition to its porosity, large surface area, good mechanical strength, and remarkable transport properties. Here, we present titanium dioxide nanoplates/polyvinylidene fluoride (TiO₂/PVDF) membranes prepared by a straightforward hydrothermal strategy and vacuum filtration process. The as-synthesized TiO₂/PVDF membrane was applied for energy storage applications. The fabricated TiO₂/PVDF membrane served as the negative electrode for supercapacitors (SCs). The electrochemical properties of a TiO₂/PVDF membrane were explored in an aqueous 6 M KOH electrolyte that exhibited good energy storage performance. Precisely, the TiO₂/PVDF membrane delivered a high specific capacitance of 283.74 F/g at 1 A/g and maintained capacitance retention of 91% after 8000 cycles. Thanks to the synergistic effect of TiO₂ and PVDF, the TiO₂/PVDF membrane provided superior electrochemical performance as an electrode for a supercapacitor. These superior properties will likely be used in next-generation energy storage technologies.