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21.
B. Hlavőček J. Šestők L. Koudelka P. Mošner J. J. Mareš 《Journal of Thermal Analysis and Calorimetry》2005,80(2):271-283
Summary The forms of vibrations and displacements of particles in amorphous structures have been investigated. The particles, moving on highly non-linear amplitude, are responsible for the creation of disordered structures of amorphous bodies. The non-linear oscillators, even if 'few' in concentration, are characterized by unpredictable trajectories in phase space. The non-linear oscillators are fully developed in the liquid state above the crossover temperature Tcr and between Tcr and Tg their number decreases. Under Tg they completely disappear. The interconnection between the linear oscillators in blocks plays the most important role in the characteristic time spectra in liquid state. Using the additive properties of elements polarizibilities, the number of acoustical units in individual blocks at Tcr is estimated to be about 600 units. The diameter of blocks at Tcr was estimated to be about 1.8 nm. Even if the non-linear high amplitude motions disappear at solidification, the remnants of structural irregularity remain and the disordered structure of glass is formed. 相似文献
22.
环多肽晶体的浮动电荷极化力场模拟 总被引:2,自引:0,他引:2
利用原子键电负性均衡结合分子力场方法(ABEEM/MM)对五种环多肽晶体进行了研究. 与传统力场相比, 该方法中的静电势包含了分子内和分子间的静电极化作用, 以及分子内电荷转移影响, 同时加入了化学键等非原子中心电荷位点, 合理地体现了分子中的电荷分布. 相对其他极化力场模型, 具有计算量较小的特点. 该模型下计算得到的环多肽分子单元相对实验测得的结构的原子位置、氢键长度和二面角的均方根偏差分别为0.009 nm、0.013 nm和5.16°, 能够很好地重复实验结果. 总体上, 其结果优于或相当于其他力场模型, 适用于对实际蛋白质体系的模拟和研究. 相似文献
23.
以分子基材料为目标的功能配合物的设计合成是近年来材料化学研究的重要领域,传统的分子设计尽管在分子水平上获得了很大的成功,但在由分子到晶体,由微观性质到宏观功能的晶体工程研究中遇到了极大的困难。因为宏观功能不仅要求分子本身具有良好的性能,同时还要求分子按照一定的方式堆积和排列犤1~3犦。例如二阶非线性光学材料不但要求分子具备较大的非线性超极化率和非对称中心,而且还要求分子在堆积过程中形成无心空间群的晶体。而自然界中大约超过70%的手性分子在结晶时都形成有心的空间群,因此,如何实现分子的无心堆积是非… 相似文献
24.
Marek Czachor 《Foundations of Physics Letters》1991,4(4):351-361
A mobility phenomenon is typical for a large class of non-linear evolutions. It is shown that the mobility can be responsible for a malignant form of quantum mechanical non separability of two correlated systems. An explicit example based on Weinberg's non linear quantum mechanics is considered. We show that in such a theory a transfer of information without a transfer of energy is possible and discuss physical roots of this phenomenon. In Polchinski's approach this effect is not present.1 Permanent address: Laboratory of Dielectrics and Organic Semiconductors, Technical University of Gdask, Gdask, Poland. 相似文献
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26.
Robert F.H. Fischer 《AEUE-International Journal of Electronics and Communications》2012,66(11):871-879
Over the last years, numerous equalization schemes for multiple-input/multiple-output channels have been studied in the literature. New low-complexity approaches based on lattice basis reduction are of special interest, since they achieve the optimum diversity behavior. Although the per-symbol equalization complexity of these schemes is very low, the initial calculation of the required matrices may impose an enormous burden in arithmetic complexity. In this paper, we give a tutorial overview and assess algorithms, which, given the channel matrix, result in the feedforward, feedback, and unimodular matrix required in lattice-reduction-aided decision-feedback equalization or precoding. To this end, via a unified exposition of the Lenstra–Lenstra–Lovász (LLL) algorithm, the LLL with deep insertions, and the reversed Siegel approach similarities and differences of these approaches are enlightened. A modification of the LLL swapping criterion, better matched to the equalization setting, is discussed. It is shown that using lattice-reduction-aided equalization/precoding better performance can be achieved at lower complexity compared to classical equalization or precoding approaches. 相似文献
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28.
《Optimization》2012,61(5):677-687
We consider the problem of approximate minimax for the Bolza problem of optimal control. Starting from the method of dynamic programming (Bellman) we define the ?-value function to be the approximation for the value function being a solution to the Hamilton–Jacobi equation. 相似文献
29.
Image fusion refers to the techniques that integrate complementary information from multiple image sensors’ data in a way that makes the new images more suitable for human visual perception. The paper focuses on the low color contrast problem of linear fusion algorithms with color transfer method. Firstly, the contrast of infrared and visible images is enhanced using local histogram equalization and median filter. Then the two enhanced images are fused into the three components of a Lab image in terms of a simple linear fusion strategy. To enhance the color contrast between the target and the background, the scaling factor is introduced into the transferring equation in the b channel. Experimental results based on three different data sets show that the hot and cold targets are all popped out with intense colors while the background details present natural color appearance. Target detection experiments through target recognition area, detection rate, target-background discrimination also show that the presented method has a better performance than the former methods. 相似文献
30.
In this paper, we develop an image pixel based histogram equalization model for image contrast enhancement. The approach is to propose a variational model containing an energy functional to adjust the pixel values of an input image directly so that the resulting histogram can be redistributed to be uniform. This idea is different from existing histogram equalization algorithms where a histogram based on the input image is constructed, a mapping is determined to output a uniform histogram and then the pixel values of the input image are adjusted based on the mapping. In the variational model, a mean brightness term is incorporated to preserve the brightness of the input image, and a geometry constraint can also be added to keep the geometry structure of the input image. Theoretically, the existence of the minimizer of the proposed model, and the convergence of the proposed algorithm are given. Experimental results are reported to demonstrate that the performance of the proposed model are competitive with the other testing histogram equalization methods for several testing images. 相似文献