2-乙酰基-6-甲氧基萘的多相催化氢化

乙酰基溴甲基萘;甲氧基萘基;2-乙酰基-6-甲氧基萘的多相催化氢化     

A parallel computational method for simulating two‐phase gel dynamics on a staggered grid

We develop a parallel computational algorithm for simulating models of gel dynamics where the gel is described by two phases, a networked polymer and a fluid solvent. The models consist of transport equations for the two phases, two coupled momentum equations, and a volume‐averaged incompressibility constraint. Multigrid with Vanka‐type box‐relaxation scheme is used as preconditioner for the Krylov subspace solver (GMRES) to solve the momentum and incompressibility equations. Through numerical experiments of a model problem, the efficiency, robustness and scalability of the algorithm are illustrated. Copyright © 2008 John Wiley & Sons, Ltd.     

On Efficient Computation of the Optimization Problem Arising in the Inverse Modeling of Non-Stationary Multiphase Multicomponent Flow Through Porous Media

In this paper we discuss a method of solving inverse problems in non-isothermal multiphase multicomponent flow through porous media. The conceptual model is described by a system of non-linear partial differential equations which involve unknown parameters. These parameters are to be determined using a set of observations at discrete points in space and time by an optimization method. It is based on a reduced Gauss-Newton iteration in combination with an efficient gradient computation which takes advantage of a recently developed efficient numerical simulation technique. A sensitivity analysis is carried out for the optimum parameter set. Numerical experiments are performed for a one dimensional column experiment carried out at the VEGAS, University of Stuttgart, Germany.     

Experimental investigation of a maximum entropy assumption for acceleration terms within a poly‐disperse moment framework

Moment transport methods are being developed to model poly‐dispersed multiphase flows by transporting statistical moments of the particle size–velocity joint probability density function (JPDF). A common feature of these methods is the requirement to reproduce or approximate the form of the JPDF from the transported moments for calculation of body force terms and other source terms. This paper examines the application of a maximum entropy technique against phase Doppler anemometry data sets from an electrostatically charged kerosene spray and also an automotive pressure swirl atomizer. An assessment of which moments are required to reproduce the JPDFs using a maximum entropy assumption to a sufficient level of accuracy is made. It is found that it is possible to reproduce the JPDFs to a high level of accuracy using a large number of moments; however, this incurs large computational overheads. If the moments to be transported are chosen on the basis of physical reasoning (such as the relationship between size and velocity due to drag) it is possible to reduce the number of moments to those which would be conserved via balance equations. This permits an approximation to the JPDF commensurate with the closure level of the moment transport method and thus the closure model method is naturally scalable with the degree of information from available conservation equations. Copyright © 2008 John Wiley & Sons, Ltd.     

On pressure separation algorithms (PSepA) for improving the accuracy of incompressible flow simulations

We investigate a special technique called ‘pressure separation algorithm’ (PSepA) (see Applied Mathematics and Computation 2005; 165 :275–290 for an introduction) that is able to significantly improve the accuracy of incompressible flow simulations for problems with large pressure gradients. In our numerical studies with the computational fluid dynamics package FEATFLOW ( www.featflow.de ), we mainly focus on low‐order Stokes elements with nonconforming finite element approximations for the velocity and piecewise constant pressure functions. However, preliminary numerical tests show that this advantageous behavior can also be obtained for higher‐order discretizations, for instance, with Q₂/P₁ finite elements. We analyze the application of this simple, but very efficient, algorithm to several stationary and nonstationary benchmark configurations in 2D and 3D (driven cavity and flow around obstacles), and we also demonstrate its effect to spurious velocities in multiphase flow simulations (‘static bubble’ configuration) if combined with edge‐oriented, resp., interior penalty finite element method stabilization techniques. Copyright © 2008 John Wiley & Sons, Ltd.     

化学链分级气化燃料反应器气固流动数值模拟

本文基于多相粒子单元法对化学链分级气化燃料反应器（下部为气化反应器,上部为重整反应器）开展了气固流动数值模拟研究,验证了曳力模型、模型参数（法向和切向颗粒–壁面碰撞恢复系数e_wn和e_wτ）对计算结果的敏感性,并确定了合适的曳力模型及模型参数。探究了表观气速和两床接口处狭缝尺寸对颗粒连通量的影响规律,研究结果表明：颗粒连通量随表观气速的增加而增加,随狭缝尺寸的增加而减小。

     

多相等离子体气动激励流动特性

等离子体激励器电极组相位不同便产生多相等离子体气动激励,建立了粒子图像测速仪流场参数测试系统,利用粒子图像测速仪技术,研究了非对称布局等离子体气动激励诱导空气流动特性,分析了多相等离子体气动激励对诱导空气流动速度的影响。结果表明：粒子图像测速仪流场测试系统能够准确地反映等离子体气动激励诱导空气流动的流场空间结构,等离子体气动激励诱导空气流动是平行于激励器的近壁面射流,多相等离子体气动激励能够增大等离子体气动激励诱导气流速度,或者使等离子体气动激励影响流场区域增大。粒子图像测速仪系统是深入研究等离子体气动激励的流场结构最佳的方式之一。     

Towards numerical simulations of supersonic liquid jets using ghost fluid method

A computational tool based on the ghost fluid method (GFM) is developed to study supersonic liquid jets involving strong shocks and contact discontinuities with high density ratios. The solver utilizes constrained reinitialization method and is capable of switching between the exact and approximate Riemann solvers to increase the robustness. The numerical methodology is validated through several benchmark test problems; these include one-dimensional multiphase shock tube problem, shock–bubble interaction, air cavity collapse in water, and underwater-explosion. A comparison between our results and numerical and experimental observations indicate that the developed solver performs well investigating these problems. The code is then used to simulate the emergence of a supersonic liquid jet into a quiescent gaseous medium, which is the very first time to be studied by a ghost fluid method. The results of simulations are in good agreement with the experimental investigations. Also some of the famous flow characteristics, like the propagation of pressure-waves from the liquid jet interface and dependence of the Mach cone structure on the inlet Mach number, are reproduced numerically. The numerical simulations conducted here suggest that the ghost fluid method is an affordable and reliable scheme to study complicated interfacial evolutions in complex multiphase systems such as supersonic liquid jets.     

磁电热弹耦合材料三维多裂纹超奇异积分法

用超奇异积分方程法将多场耦合载荷作用下磁电热弹耦合材料内含任意形状和位置三维多裂纹问题转化为求解一以广义位移间断为未知函数的超奇异积分方程组问题,退化得到内含任意形状平行三维多裂纹问题的超奇异积分方程组;推导出平行三维多裂纹问题的裂纹前沿广义奇异应力场解析表达式、定义了广义(应力、应变能)强度因子和广义能量释放率;应用有限部积分概念及体积力法,为超奇异积分方程组建立了数值求解方法,编制了FORTRAN程序,以平行双裂纹为例,通过典型算例,研究了广义(应力、应变能)强度因子随裂纹位置、裂纹形状及材料参数变化规律,得到裂纹断裂评定准则. 最后,分析了裂纹间干扰、屏蔽作用及其在工程实际中的应用.      

离散型湍流多相流动的研究进展和需求

离散型多相流动,指气体-颗粒(气-固)、液体-颗粒(液-固)、液体-气泡、气体-液雾以及气泡-液体-颗粒等两相或三相流动.这种类型的多相流动广泛存在于能源, 航天和航空, 化工和冶金,交通运输, 水利, 核能等领域.本文阐述了离散型多相流动的国内外基础研究,包括颗粒/液滴/气泡在流场中受流体动力作用力的研究, 颗粒-颗粒,液滴-液滴,气泡-气泡之间以及颗粒/液滴和壁面之间碰撞和聚集规律的研究,颗粒-气体和气泡-液体湍流相互作用的研究, 和数值模拟的研究,包括多相流动的雷诺平均模拟、大涡模拟和直接数值模拟的研究进展.最后, 归纳了目前尚待研究的需求.