On the mechanism of solute retention in RP-HPLC systems with B+AB1+AB2 type eluents

Summary Intermolecular interactions between the solute and the moieties constituting the mobile phase significantly contribute to the overall retention pattern of a given solute in a given chromatographic system. In this paper retention of solute is discussed in the case of the B+AB₁+AB₂ type mobile phase, which, in a quasithermodynamic way, can be divided into seven individual moieties. One evaluates the influence of each moiety on solute retention, and refers these regularities to the polarity of the solutes.     

Microstructural and physicochemical study of the buried Fe/AlGaAs(100) interface by transmission electron microscopy and x‐ray emission spectroscopy

Among the magnetic metal/semiconductor contacts, the Fe/GaAs system has been widely studied owing to its potential applications in electronic devices. In contrast, there are not many studies concerning the Fe/Al_xGa_1?xAs contact, and in particular there are no reports concerning the changes induced in the interfacial zone by the presence of Al. In this work, thin polycrystalline iron films were deposited by ion beam sputtering at room temperature on a 300 nm thick Al_0.25Ga_0.75As layer grown by molecular beam epitaxy onto GaAs(001). X‐ray diffraction analysis showed that the iron films are polycrystalline, and indications of a (002) texture of the film were observed. The fine scale analysis of the interface was achieved by high‐resolution transmission electron microscopy (HRTEM) observations, the results of which are compared with the physicochemical information obtained from electron‐induced x‐ray emission spectroscopy, by analysing the Al 3p valence states at the Fe/Al_xGa_1?xAs interface. The HRTEM experiments on cross‐section samples indicate that the interfacial zone between iron and AlGaAs is limited to <1.5 nm in thickness. X‐ray emission spectroscopy showed the presence of Al atoms in an FeAl‐like environment at the interface, and the existence of wrong bonds and point defects. The estimated width of the perturbed interface (2.0 ± 0.5 nm) is in agreement with the HRTEM results. Copyright © 2003 John Wiley & Sons, Ltd.     

透视/遮阳/控温/红外隐身多功能集成序构薄膜研究

为了解决光学材料多功能耦合与集成的光谱诉求及其材料设计冲突难题,本文提出一种基于［TiAlN/Ag］²/TiAlN序构复合薄膜开展可见光透射诱导与红外辐射抑制的协同设计方法,诠释序构薄膜材料多功能耦合的新原理与新机制,并对其光学兼容性能测试表征。研究表明,构筑的［TiAlN（厚度30 nm）/Ag（厚度15 nm）］²/TiAlN（厚度30 nm）序构复合薄膜具备带通状选择性透射与中远红外低辐射的光学特性,可较好实现透视、遮阳、低辐射控温与红外隐身多功能兼容效果,在军用车辆、绿色建筑等特种玻璃的辐射控温与红外隐身领域有应用潜力。     

Space-Air-Ground Integrated Mobile Crowdsensing for Partially Observable Data Collection by Multi-Scale Convolutional Graph Reinforcement Learning

Mobile crowdsensing (MCS) is attracting considerable attention in the past few years as a new paradigm for large-scale information sensing. Unmanned aerial vehicles (UAVs) have played a significant role in MCS tasks and served as crucial nodes in the newly-proposed space-air-ground integrated network (SAGIN). In this paper, we incorporate SAGIN into MCS task and present a Space-Air-Ground integrated Mobile CrowdSensing (SAG-MCS) problem. Based on multi-source observations from embedded sensors and satellites, an aerial UAV swarm is required to carry out energy-efficient data collection and recharging tasks. Up to date, few studies have explored such multi-task MCS problem with the cooperation of UAV swarm and satellites. To address this multi-agent problem, we propose a novel deep reinforcement learning (DRL) based method called Multi-Scale Soft Deep Recurrent Graph Network (ms-SDRGN). Our ms-SDRGN approach incorporates a multi-scale convolutional encoder to process multi-source raw observations for better feature exploitation. We also use a graph attention mechanism to model inter-UAV communications and aggregate extra neighboring information, and utilize a gated recurrent unit for long-term performance. In addition, a stochastic policy can be learned through a maximum-entropy method with an adjustable temperature parameter. Specifically, we design a heuristic reward function to encourage the agents to achieve global cooperation under partial observability. We train the model to convergence and conduct a series of case studies. Evaluation results show statistical significance and that ms-SDRGN outperforms three state-of-the-art DRL baselines in SAG-MCS. Compared with the best-performing baseline, ms-SDRGN improves 29.0% reward and 3.8% CFE score. We also investigate the scalability and robustness of ms-SDRGN towards DRL environments with diverse observation scales or demanding communication conditions.     

基于激光器RIN抑制的宽带低噪声微波光传输技术

微波光子链路中的核心器件激光器、调制器、光电探测器均为有源器件,在微波信号的电光光电转换过程中会引入额外的噪声,导致微波信号的噪声性能恶化,高的噪声系数会降低电子信息系统的灵敏度、动态范围、探测精度等关键性能指标,因此抑制噪声成为实现高性能微波光子系统的关键。文章针对当前激光器噪声较高的限制,提出采用常规分布反馈(DFB)激光器与光放大器、窄带光子滤波相组合的方式来抑制激光源噪声,实现微波光子链路的宽带低噪声。建立了微波光子链路传输模型,分析了链路性能与器件参数之间的映射关系。实测对比了采用该组合光源方案与常规微波光子链路的噪声性能,结果表明采用高功率光源结合光滤波可对激光器远端相对强度噪声(RIN)实现高的抑制,通过优化,噪声系数较常规水平可改善15 dB以上。     

基于LTCC带传输零点的带通滤波器

采用低温共烧陶瓷（LTCC）技术设计了带传输零点的带通滤波器,利用三维叠层结构实现了滤波器的小型化设计,借助HFSS仿真软件对滤波器参数进行优化仿真,改善了滤波器的传输特性,有效压缩了本振信号,满足了该带通滤波器设计指标和小型化的目的。     

移动阅读终端介绍及测试方法研究

基于对信息需求的硬性需求,随着通信技术、显示技术、数据版权和计算机技术的飞速发展,移动阅读悄然进入我们的生活,改变着我们传统的阅读方式,由此也产生了信息量无限大而又具备纸质阅读感受的移动阅读终端。本文首先对移动阅读终端的软、硬件和功能进行介绍,进而简要介绍移动阅读终端的测试方法,最后对移动阅读终端发展进行了展望。     

4G网络中位置服务业务解决方案

本文讨论如何综合考虑4G网络不同发展时期的网络特点和位置服务方案,给出在4G网络中部署位置服务增值业务解决方案的建议。     

中波红外火情遥感的大气辐射传输特性

分析2005年在广西武鸣机场进行的人工火情测量试验中获得的由BOMEM MR-154FT高光谱仪测定的火情光谱特征发现:在中波4.34～4.76μm光谱段的辐亮度比火情遥感监测常用通道3.5～4.0μm有更强的响应关系.用模拟计算方法进一步分析了中波红外光谱的大气辐射特性.分别对中波波段主要的吸收气体(水汽、水汽连续、二氧化碳混合、二氧化碳、一氧化二氮、臭氧和气溶胶)影响辐射传输的情况进行模拟计算;选择中国内陆地区18种大气廓线样本和4种大气模型,分别进行辐射传输计算,获得了3～5μm谱段分谱大气透过率和大气程辐射等,并比较了新选择通道(4.42～4.78μm)与传统通道(3.55～3.95μm)在地面和传输到大气层顸后辐亮度的变化情况,为今后应用新探测通道奠定了基础.     

智能终端发展关键技术探讨

智能终端产品(包括手机、平板和混合式的移动计算设备)在个人和商业应用场合大量使用,终端在高速计算能力方面更新迅猛,处理能力军备竞赛将陷入硬件瓶颈,同质现象成为现实,而人机交互技术、终端应用开发环境、终端安全云服务等将成为影响智能终端向纵深人群渗透和更商业化应用领域发展的决定要素。本文旨在探讨、分析和展示上述几个关键技术的新进展和演进趋势。