N-donor ligand complexes of nickel,zinc and copper: Comparisons with tetradentate N-donor ligands derived from Schiff bases

The nickel and zinc complexes of 2-aminomethylaniline (AMA) are reported. Both metals form the octahedral complex [M(AMA)₂(ONO₂)₂] (M = Ni, Zn) where the aromatic ligands lie in the meridial plane with the anilino donors trans to one another. The remaining nitrates coordinate axially. A simple comparison with the nitrogen donor disposition (cis/trans) in nickel complexes of tetradentate N₄ donor ligands derived from symmetric Schiff base ligands is presented. The discussion is extended to interrogate the bonding motifs of the nitrate ligands viz –ONO₂ in the nickel complexes of AMA compared to the two motifs (viz O₂NO and ONO₂) that are isolated for the nickel complexes of the macrocycle hexamethyltetraazacyclotetradecane.     

新型多取代Tr(o)ger's base衍生物的合成及其晶体结构

以邻氨基二苯甲酮为原料,经两分子环化缩合反应制得6,12-二芳基二苯并[b,f][1,5]二氮杂环辛四烯(2a~2d);2a~2d经LiAlH4还原制得6,12-二芳基-5,6,11,12-四氢二苯并[b,f][1,5]二氮杂环辛(3a~3d);3a~3d与醛(或酮)反应,合成了一系列新型的多取代Tr(o)ger's base衍生物(4a~4d和5a~7a),其结构经1H NMR, 13C NMR, HR-MS(ESI)和X-射线单晶衍射表征.通过分析架桥前后3a(CCDC: 1498564)和6a(CCDC: 1498555)的晶体结构,解释了该类化合物1H NMR中NCH质子及桥上取代基质子裂分的原因,并进一步证实了4~7为非C2轴对称结构.     

移动互联网对电信运营商转型的要求

本文试图从转型的观点看电信运营商如何适应数据核心业务.电信运营商的转型至少包括企业战略转型、市场转型与技术转型.     

TD-SCDMA集群系统中部分宏分集组网前向容量分析

TD-SCDMA集群小区使用宏分集技术可以有效的克服大尺度衰落,保证信号质量。本文首先分析了在没有任何措施的前提下进行宏分集组网,但前向容量会随着宏分集基站数的增多而减少。在分析容量损失原因的基础上,我们进一步提出在终端利用Rake接收机对各路信号进行同步、相位调整,再进行最大比值合并,然后发送给用户,由此,前向容量大大提高。     

广播电视微波数字化设备的技术要点

通信技术的不断发展,给广播电视的信号传输技术带来革新与发展。因为计算机的接入,数字信号的传输进入数字化时代,因此大功率的传输发射系统得到广泛应用,其核心技术包括调制发射、接收处理、天线分集设计等,为广播电视数字化提供了必要的技术支持。     

Recognition of Multifunctional Coded Target in Single-camera Mobile 3D-vision Coordination Measurement

Single-camera mobile-vision coordinate measurement is one of the primary methods of 3D-coordinate vision measurement, and coded target plays an important role in this system. A multifunctional coded target and its recognition algorithm is developed, which can realize automatic match of feature points, calculation of camera initial exterior orientation and space scale factor constraint in measurement system. The uniqueness and scalability of coding are guaranteed by the rational arrangement of code bits. The...     

灾难应对通信系统的需求与未来发展

四川汶川地震后，灾难情况下通信系统的重要性越来越被广泛地认识，文章以目、美为例，从灾难发生时不同使用主体通信需求出发，探讨对通信网的需求，并分析未来灾难应对通信系统的发展目标。     

Pinwheel broadcast paradigm in supporting energy‐saving mobile devices

Because of the limited bandwidth and restricted number of channels in the wireless access environment, the broadcast paradigm has become an important technique for accessing messages. Energy saving is an important issue in the mobile computing environment. In this paper, we propose a multichannel broadcast paradigm that constructs the broadcast channels according to the access frequency of each type of message in order to save energy in mobile devices (MDs). The pinwheel scheduling algorithm (PSA) presented in this paper is used to organize all types of messages in the broadcast channels in the most symmetrical distribution in order to reduce both the tuning time and the access time. The performance of the proposed mechanism is analyzed, and the improvement over existing methods is demonstrated numerically. The results show that the proposed mechanism is capable of improving both the tuning time and the access time due to the presence of skewness in the access distribution among the disseminated messages. When the number of message types increases, both the tuning time and the access time can be further improved as long as a small number of broadcast channels are added. Copyright © 2009 John Wiley & Sons, Ltd.     

(4R,5R)-1,3-二氧戊环-2,2-二苯基-4,5-二-[亚甲基-N,N'-(1-甲基-4-羟基苯甲醛)]的合成及其催化性能

以L-酒石酸和二苯甲酮为原料,经酯化、缩酮、加成、消除、还原和缩合等反应合成了一种新型席夫碱类化合物——(4R,5R)-1,3-二氧戊环-2,2-二苯基-4,5-二-[亚甲基-N,N'-(1-甲基-4-羟基苯甲醛)](4),其结构经1H NMR,13C NMR和LC-MS表征。以二烷基锌对苯甲醛的不对称加成为模板反应,考察了4的不对称催化性能。实验结果表明,4对该反应具有一定的催化效果(ee值52%)。     

Bis-chelate Fe(III) complex of an azomethine at the focal point of a branched ester functionalized with cyclohexylbenzoic acid

A Fe(III) complex with Cl counter ion based on a branched Schiff base has been synthesized and studied. The compound was produced by the reaction of the Schiff base with FeCl₃ at room temperature in benzene–ethanol. The complex is symmetric, i.e., bis-chelate, with an octahedral coordination of Fe. The compound revealed phase transitions of the “solid–solid” type. The complex displayed a temperature-induced spin transition (S?=?1/2???5/2) which was detected by EPR.