全文获取类型
收费全文 | 6396篇 |
免费 | 1508篇 |
国内免费 | 804篇 |
专业分类
化学 | 2776篇 |
晶体学 | 91篇 |
力学 | 121篇 |
综合类 | 41篇 |
数学 | 138篇 |
物理学 | 2564篇 |
无线电 | 2977篇 |
出版年
2024年 | 35篇 |
2023年 | 92篇 |
2022年 | 181篇 |
2021年 | 197篇 |
2020年 | 201篇 |
2019年 | 157篇 |
2018年 | 152篇 |
2017年 | 231篇 |
2016年 | 289篇 |
2015年 | 266篇 |
2014年 | 433篇 |
2013年 | 786篇 |
2012年 | 516篇 |
2011年 | 530篇 |
2010年 | 423篇 |
2009年 | 389篇 |
2008年 | 430篇 |
2007年 | 442篇 |
2006年 | 440篇 |
2005年 | 402篇 |
2004年 | 349篇 |
2003年 | 318篇 |
2002年 | 318篇 |
2001年 | 176篇 |
2000年 | 180篇 |
1999年 | 147篇 |
1998年 | 109篇 |
1997年 | 86篇 |
1996年 | 77篇 |
1995年 | 70篇 |
1994年 | 72篇 |
1993年 | 37篇 |
1992年 | 37篇 |
1991年 | 37篇 |
1990年 | 16篇 |
1989年 | 17篇 |
1988年 | 9篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 9篇 |
1981年 | 8篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有8708条查询结果,搜索用时 15 毫秒
81.
《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(1):303-313
The reaction of electron‐deficient alkenes with alkoxyalkynyl Fischer carbene complexes (FCCs) represents a straightforward route to a new type of captodative (donor–acceptor) alkynylcyclopropanes, which have been prepared in moderate to high yields and in a diastereoselective manner. Some studies regarding the employment of additives to facilitate the recovery of the metal moiety after the reaction are also described. Finally, the first example of a cyclopropanation reaction through employing Fischer carbene complexes under microwave irradiation is presented; this method proved to be an advantageous alternative to the thermal reaction. 相似文献
82.
微波消解-火焰原子吸收光谱法测定兰州鲶中微量元素 总被引:3,自引:0,他引:3
使用微波消解处理样品,火焰原子吸收光谱法测定了兰州鲶中的铁、锌、镁含量。结果显示,兰州鲶中含有丰富的铁、锌、镁三种人体必需微量元素。该法测定快速、简单,结果满意。 相似文献
83.
Diamy A.-M. Hochard L. Legrand J.-C. Ricard A. 《Plasma Chemistry and Plasma Processing》1998,18(4):447-460
Measurements of nitrogen atom density, by means of NO chemical titration, along with an evaluation of the densities of some excited species N
2
(B, v=11), N
2
(B, v=2), N
2
(C, v=0), and N
2
+
(B,v=0), by means of a spectroscopic study of some bands of dinitrogen, are achieved along the flowing afterglow of a dinitrogen microwave plasma (2450 MHz) for several pressures. The concentrations obtained are in the following range: [N]10
+15
, [N
2
(B, 2)]10
+9
–10
+10
, [N
2
(B, 11)]10
+8
–10
+9
, [N
2
(C, 0)]10
+6
–10
+7
, [N
2
+
(B,0)]10
+6
-10
+8
(cm-3). From a kinetic study of the formation and decay of excited and charged species, an estimation of N
2
(A, v), N
2
(X, v, and N
2
+
(X) densities can be derived: [N
2
(A, v)]10
+12
, [N
2
(X, v6)]10
+15
–10
+16
, [N
2
(X, v12)]10
+14
–10
+15
, [N
2
+
(X)]10
+10
(cm
-3
). 相似文献
84.
MgFe2O4-Fe2O3纳米粉体的软化学合成及电磁学特性 总被引:1,自引:0,他引:1
Nano-MgFe2O4-Fe2O3 magnetic powders were synthesized by citrate gel under microwave irradiation. The structure,particle size distribution,electromagnetic characteristics of nano-MgFe2O4-Fe2O3 were characterized by using TG-DTA, X-ray, electronic microscope, nano-size measurement and electromagnetism measurement apparatus。The results show that the product is a mixture of MgFe2O4 and Fe2O3 with average size of 44 nm, tanδ for the product is 0.265 and 0.610 at frequency of 1.0 GHz and 1.8 GHz respectively. 相似文献
85.
1INTRODUCTIONInthepastfewyears,potassiumchannelacti-vatorshavegainedincreasingattentionbecauseoftheirclinicalpotentialapplicationsinvariousdiseases.Oneofthemostpotentcompoundsamongthisnewclassofdrugsisthebenzopyranderivativecroma-kalim[1~4].Benzopyranaswellasitsderivativesex-hibitsextensivepharmacologicalandbiologicalacti-vities[5],suchasantibacterialactivities[6,,antitumor7]activity[8],hypotensiveeffect[9],antiproliferationef-fect[10],etc.Thetitlecompoundbearingabenzo-pyranstructuraluni… 相似文献
86.
伯溴代烷的微波快速合成法 总被引:3,自引:0,他引:3
198 6年R .J.Gignere[1 ] 和R .Gedye[2 ] 首次报道将微波用于有机合成反应以来 ,大量实验事实证明[3] 微波不仅能极大地提高某些化学反应速率 ,而且能使一些在常规加热条件下几乎不能进行的反应得以完成、获得满意的收率。用伯醇在溴化氢溶液中微波条件下发生反应制备了伯溴代烷。1 实验部分WhirlpoolT1 2 0X微波炉 (四川大学无线电系改装 ,可连续发射微波 ,功率连续可调 )、WZS -I阿贝折光仪 (未校正 )。工业溴化氢 (C =40 % ,d =1 38) ,其余试剂均为CP级。合成通法 将适量的醇、一定量的浓硫酸和过… 相似文献
87.
88.
Òscar Rubio-Pons Boris Minaev Oleksandr Loboda Hans Ågren 《Theoretical chemistry accounts》2005,113(1):15-27
The phosphorescence spectrum of p-dichlorobenzene has been calculated using multiconfiguration self-consistent-field wave functions and the quadratic response technique. Attention has been paid to the intensity distribution of the singlet–triplet (3B1u1Ag) transition through a number of vibronic subbands. The second order spin–orbit coupling (SOC) contribution to the spin splitting of the 3B1u (3*) state is found to be almost negligible, and the calculations therefore provide a good estimate for the zero-field splitting (ZFS) parameters based only on the electron spin–spin coupling expectation values. Nuclear quadrupole resonance constants for the different Cl isotopes are also calculated to accomplish the ZFS assignment. The electric dipole activity of the spin sublevels in the triplet–singlet transitions to the ground-state vibrational levels is estimated by calculations of derivatives using distorted geometries which are shifted from the equilibrium position along different vibrational modes. A vibrational analysis of the phosphorescence spectrum, based on the SOC-induced mixing of the singlet and triplet states calculated along different vibrational modes, provides reasonable agreement with experimental data.Acknowledgment O. R.-P. would like to thank the European MOLPROP network for support. The authors thank Alexander Baev for fruitful discussions. This work was supported by the Swedish Royal Academy of Science (KVA). 相似文献
89.
标题化合物C24H29NO4?1/2C2H5OH稨2O)由香兰素、5,5-二甲基-1,3-环己二酮、醋酸铵在微波辐射下干反应并经95%乙醇重结晶而得C24H29NO4穀2(C2H5OH稨2O)晶体。结构通过单晶X-射线衍射法确定,其晶体属单斜晶系,空间群P21/n, a = 9.810(2), b = 14.516(3), c = 17.008(3) ? b = 101.03(2), V = 2377.2(8) ?, Z = 4, Mr = 427.52, Dc = 1.195 g/cm3 , m(MoKa) = 0.082 mm-1, F(000) = 920。晶体结构用直接法解出,经全矩阵最小二乘法对原子参数进行修正,最终的偏离因子为R = 0.0406, wR = 0.0892。X-射线衍射分析结果表明,吡啶环和与之稠合的2个六员环均为信封式构象。 相似文献
90.
Crouch R Boyer RD Johnson R Krishnamurthy K 《Magnetic resonance in chemistry : MRC》2004,42(3):301-307
Compensation of refocusing inefficiency in a gHMBC experiment by replacing the rectangular pi pulse with a pair of adiabatic pulses with synchronized inversion sweep (CRISIS) significantly improves the performance of the gHMBC experiment. The CRISIS-gHMBC experiment retains the pure absorptive shapes in F1 and hence results in better lineshape and higher resolution than the current versions of magnitude mode gHMBC spectra. When used as a broadband experiment, CRISIS-gHMBC, owing to better refocusing efficiency of the adiabatic pulse pairs, gives improved performance across the 13C spectral width. Moreover, it is shown that CRISIS-gHMBC is a robust and improved alternative and when used along with the IMPRESS (Improved Resolution using Symmetrically Shifted pulses) technique further increases the sensitivity and resolution without additional experimental time. The IMPRESS-CRISIS combination is demonstrated for broadband gHMBC and band-selective gHMBC experiments. The ICbs-gHMBC [IMPRESS-CRISIS-band-selective gHMBC] experiment is an attractive and better alternative to individual band-selective gHMBC. 相似文献