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81.
低RCS栅格微带天线研究 总被引:1,自引:0,他引:1
研究了栅格微带天线在微带天线RCS减缩中的应用。分析了栅格线宽度、栅格线间距、栅格化方式等参数对天线的谐振频率、增益的影响。设计了一副具有低RCS特性的栅格微带天线,与谐振在同频率的微带贴片天线相比,天线的增益仅降低0. 6dBi,而天线在2~10GHz频带内的平均RCS降低4dBsm。 相似文献
82.
宏孔硅阵列(MSA)在光子晶体、硅微通道板、MEMS 器件等领域应用前景广阔,引起人们广泛关注。为制备理想的MSA结构,本文开展了MSA光电化学方法腐蚀实验,重点研究了腐蚀电流密度对宏孔形貌的影响。给出了n型硅抛光片背面光照情况下在氢氟酸溶液中的电流-电压扫描曲线,讨论了临界电流密度JPS的意义和MSA稳定生长的基本电流密度条件。提出了一种间接地测量JPS与腐蚀时间关系的方法,并根据JPS的测量结果调整腐蚀电流,实现了理想的MSA等径生长,制备出孔深度为295m,长径比为98的MSA结构。 相似文献
83.
Hao Zhang Dr. Benhua Wang Dr. Kai Seehafer Prof. Dr. Uwe H. F. Bunz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(35):7779-7782
A cross-reactive optical sensor array based on poly(p-phenyleneethynylene)s (PPEs) determines Edman degraded amino acids. We report a sensor array composed of three anionic PPEs P1–P3 , and their electrostatic complexes with metal ions (Fe2+, Cu2+, Co2+). We recorded distinct fluorescence intensity response patterns as “fingerprints” of this chemical tongue toward standard phenylthiohydantoin (PTH) amino acids—degradation products of the Edman process. These “fingerprints” were converted into canonical scores by linear discrimination analysis (LDA), which differentiates all of the PTH-amino acids. This array discriminates PTH-amino acid residues degraded from an oligopeptide through Edman sequencing. This approach is complementary to chromatography approaches which rely on mass spectrometry; our array offers the advantage of simplicity. 相似文献
84.
A novel electrochemical biosensor based on functionalized polypyrrole (PPy) nanotube arrays modified with a tripeptide (Gly-Gly-His) proved to be highly effective for electrochemical analysis of copper ions (Cu2+). The vertically oriented PPy nanotube arrays were electropolymerized by using modified zinc oxide (ZnO) nanowire arrays as templates which were electrodeposited on indium–tin oxide (ITO) coated glass substrates. The electrodes were functionalized by appending pyrrole-α-carboxylic acid onto the surface of polypyrrole nanotube arrays by electrochemical polymerization. The carboxylic groups of the polymer were covalently coupled with the amine groups of the tripeptide, and its structural features were confirmed by attenuated total reflection infrared (ATR-IR) spectroscopy. The tripeptide modified PPy nanotube arrays electrode was used for the electrochemical analysis of various trace copper ions by square wave voltammetry. The electrode was found to be highly sensitive and selective to Cu2+ in the range of 0.1–30 μM. Furthermore, the developed biosensor exhibited a high stability and reproducibility, despite the repeated use of the biosensor electrode. 相似文献
85.
基于暗电流模型,通过变温I-V分析长波器件(截止波长为9~10μm)的暗电流机理和主导机制.实验对比了不同衬底、不同成结方式、不同掺杂异质结构与暗电流成分的相关性.结果表明,对于B+离子注入的平面结汞空位n~+-on-p结构,替代衬底上的碲镉汞(HgCdTe)器件零偏阻抗(R0)在80 K以上与碲锌镉(CdZnTe)基碲镉汞器件结阻抗性能相当.但替代衬底上的HgCdTe因结区内较高的位错,使得从80 K开始缺陷辅助隧穿电流(I_(tat))超过产生复合电流(I_(g-r)),成为暗电流的主要成分.与平面n~+-on-p器件相比,采用原位掺杂组分异质结结构(DLHJ)的p~+-on-n台面器件,因吸收层为n型,少子迁移率较低,能够有效抑制器件的扩散电流.80 K下截止波长9.6μm,中心距30μm,替代衬底上的p~+-on-n台面器件品质参数(R0A)为38Ω·cm2,零偏阻抗较n-on-p结构的CdZnTe基碲镉汞器件高约15倍.但替代衬底上的p+-on-n台面器件仍受体内缺陷影响,在60 K以下较高的Itat成为暗电流主导成分,其R0A相比CdZnTe基n~+-on-p的HgCdTe差了一个数量级. 相似文献
86.
Due to their small size, differential microphone arrays (DMAs) are very attractive. Moreover, they have been effective in combating noise and reverberation. Recently, a new class of DMAs of different orders have been developed with the MacLaurin’s series and the frequency-independent patterns. However, the MacLaurin’s series does not approximate well the exponential function, which appears in the general definition of the beampattern, when the intersensor spacing is not small enough. To circumvent this problem, we propose in this paper to approximate the exponential function with the Jacobi–Anger expansion. Based on this approximation and the frequency-independent Chebyshev patterns, we derive first-, second-, and third-order DMAs. Furthermore, in order to improve the robustness of DMAs against white noise amplification, we propose to use more microphones combined with minimum-norm filters. It is also shown that the Jacobi–Anger expansion is optimal from a mean-squared error perspective. Simulations are carried out to evaluate the performance of the proposed DMAs. 相似文献
87.
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89.
将阳极氧化与光还原法结合,在TiO_(2)纳米管阵列(TiO_(2)NTAs)表面修饰Ag纳米粒子,获得一种均匀有序、稳定性高且可循环的TiO_(2)NTAs/Ag活性基底。采用X射线粉末衍射(XRD)、X射线光电子能谱(XPS)、紫外可见漫反射光谱(UV-Vis DRS)、表面增强拉曼散射光谱(SERS)和扫描电子显微镜(SEM)等手段对TiO_(2)NTAs/Ag的组成和结构进行了表征。进一步研究了该TiO_(2)-NTAs/Ag阵列对盐酸四环素(TC-HCl)的SERS响应,结果表明,该复合基底对TC-HCl具有较高的检测灵敏度,在水中检测限可达1×10^(−14) mol/L,而TiO_(2)-NTAs与Ag之间的协同效应对其检测性能的提高起着关键作用。此外,TiO_(2)NTAs/Ag基底在光照下对TC-HCl展示了优异的降解活性,且至少可循环使用8次。表明该TiO_(2)NTAs/Ag基底在环境中有机污染物的SERS检测和降解领域具有潜在的应用前景。 相似文献
90.
Mi Ouyang Dacheng Dai Xuming Hu Yuwen Li Zhangxin Chen Bowen Tao Lina Zhang Weijun Li Yujie Dong Ru Bai Xiaojing Lv Cheng Zhang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(15):2269-2279
A new star-shaped structure conjugated microporous polymers, poly (2,8,14-tri[4-diphenyl-benzene]-hexaazatrinaphthylene) (PTPA-HATN), was designed and in-situ electrochemically polymerized on the surfaces of FTO electrodes with a directional alignment TiO2 nanorod array to obtain TiO2/PTPA-HATN core-shell nanocomposite films. Compared with the PTPA-HATN film, the TiO2/PTPA-HATN composite film exhibits higher optical contrast and faster response time, with contrast of 57% at 783 nm, coloring time of 3.62 s and discoloring time of 2.55 s (43%, 4.63 s and 4.77 s for PTPA-HATN film, respectively). After 400 cycles, the contrast of nanocomposite film decreased by 28%, while the PTPA-HATN film basically lost its electrochromic properties. A simple three-layer EC prototype device based on TiO2/PTPA-HATN nanocomposite film constructed with hydrogel electrolyte clearly shows color changes at different voltages. On the one hand, the formation of core-shell porous nanostructure of TiO2/PTPA-HATN composite film provides a larger ion doping/de-doping interface, shortening the average diffusion length of ions. On the other hand, the large indented polymer-nanorods contact interface makes it difficult for the polymer to detach from the electrode, thus significantly improving the cyclic stability of the composite film. 相似文献