微纳尺度光纤布拉格光栅折射率传感的理论研究

亚波长直径微纳光纤强倏逝场传输的光学特性,使其对周围介质折射率的变化具有极高的灵敏度.本文提出一种基于微纳尺度光纤布拉格光栅(MNFBG)的折射率传感器,结合微纳光纤倏逝场传输和光纤布拉格光栅(FBG)强波长选择的特性来实现高精度折射率传感,对其制备可行性进行了讨论.论文中对MNFBG折射率传感机理进行了深入的理论分析,并使用OptiGrating软件进行了数值模拟,模拟数据显示MNFBG折射率测量的灵敏度随着光纤半径的减小而增加,其中光纤半径为400 nm的MNFBG灵敏度可达到993 nm/RIU,相比于包层蚀刻的FBG灵敏度增加了170倍,说明MNFBG对发展微型化、高灵敏度折射率传感器具有良好的应用前景. 关键词： 微纳光纤 光纤布拉格光栅 折射率传感     

金银/氮化钛表面增强拉曼基底制备及对烟酸的定量检测

表面增强拉曼光谱技术对分子具有特异性识别以及快速无损检测的能力,使其在药物检测方面具有重大的潜力。通过贵金属和氮化钛之间协同作用,使复合基底具有较高的SERS性能,提供了一种基于SERS技术的药物检测方法。采用电化学沉积及自组装法,制备出贵金属/氮化钛复合薄膜。研究表明,在复合薄膜中存在面心立方晶型TiN、金属单质Au和Ag三种物相;电子显微镜显示平均粒径分别为90和50 nm的金属Au和Ag颗粒均匀分布在TiN薄膜表面;基底的紫外-可见吸收图谱中出现了贵金属金与银纳米颗粒及TiN薄膜三者的特征等离子体共振吸收峰。以该复合薄膜为SERS基底,对烟酸溶液进行拉曼检测。结果显示,贵金属/氮化钛复合薄膜对烟酸具有显著的SERS效应,最低检测浓度为10-5 mol·L-1,对1 033 cm-1处烟酸拉曼信号强度及浓度取对数,发现两者间呈一定线性关系,其R2为0.969,得益于TiN,Au和Ag之间可发生表面等离子体共振引起电磁场增强,以及电荷转移效应。研究还发现,烟酸通过COO-基团垂直吸附在贵金属/氮化钛基底表面;在酸性环境下,烟酸N原子质子化主要以阳离子N＋H（Ⅰ）形式存在;在碱性环境时,主要以阴离子COO-（Ⅲ）形式存在。绞股蓝总甙溶液中模拟烟酸非法添加,该复合基底对其最低的拉曼检测浓度是10-5 mol·L-1,为现场快速检测非法添加药物提供了新途径。     

特种微型光缆外护层固化度的研究

由于固化前后紫外光(UV)固化涂层材料分子链中>C-C<键上的C-H键面外弯曲振动在810cm-1附近产生的红外特征吸收峰会发生变化,因而采用了傅里叶变换红外光谱法(FTIR)对特种微型光缆外护层固化度进行测定.借此对不同抗氧阻聚、辐照时间等工艺条件下以及长期储存过程中特种微型光缆外护层的固化度进行研究及原因分析,为控...     

微流控通道加工技术的研究进展

在微流控芯片中,微通道是进行微分析的重要保证,其成型质量直接影响芯片的分析性能.从加工机理、技术特点以及适用范围等方面对激光直写加工、光刻加工、热压印技术、微细铣削加工和3D打印等微流控通道主要加工方法进行了阐述,并总结了这几种加工技术的优缺点,这为实际生产提供了一定参考.最后,对微流控通道加工技术的发展进行了展望,未...     

氘化对KH2PO4晶体微观缺陷影响的正电子湮没研究

采用传统降温法从不同程度氘化(x=0, 0.51, 0.85)的生长溶液中生长氘化KH₂PO₄(KDP) 晶体, 利用正电子湮没技术(正电子寿命谱和多普勒展宽谱)、结合X射线衍射谱(XRD) 结构分析, 对KDP晶体氘化生长的微观缺陷进行了研究, 讨论了氘化程度对晶体内部微观结构特性、缺陷类型和浓度的影响. XRD结果显示晶胞参数a, b值随氘含量的增加而增加, c值无明显变化; 正电子寿命谱结果发现随着氘化浓度的提高, KDP晶体内部中性填隙缺陷以及氧缺陷不断增加, 引起晶体晶格畸变; 氢空位、K空位、杂质替位缺陷不断发生缔合反应形成复合缺陷, 缺陷浓度不断减少; 团簇、微空洞等大尺寸缺陷也在不断发生聚合反应, 缺陷浓度表现为不断减少. 多普勒实验结果表明随着氘化程度的提升, 晶体内部各类缺陷表现为同步变化. 实验结果表明, KDP晶体在低浓度氘化生长(50%以内)下缺陷反应较弱, 而在高浓度氘化(50%以上)下的缺陷反应显著增强.     

一体双驱对称式压电悬臂梁微驱动器

设计了一种一体化加工的双驱对称式压电悬臂梁微驱动器。对压电驱动器工作原理、压电驱动器在准静态工况与共振工况下的输出特性进行了理论分析,确定压电驱动器几何尺寸。介绍了压电驱动器的多层复合结构与一体双驱的实现方式。制作了压电驱动器样机,并通过有限元仿真分析与测试实验相结合的方式得到压电驱动器的阻抗特性与输出特性曲线。将压电驱动器运用在轮式机器人,验证了设计的可行性。     

基于双同步斩波模式的LED声控灯驱动电源设计

提出了基于双同步斩波模式的微功耗LED声控灯驱动电源设计方法。该驱动电源用一个单片机控制两个开关管分别为主电源和待机电源提供工作电流。主电源采用全波斩波工作模式为LED灯组提供工作电流;待机电源采用半波斩波工作模式,从而大幅降低了待机功耗。该驱动电源结构简单,可在50~60 Hz频率的180~250 V的宽电压范围内工作,具有恒流驱动功能和微功耗特性,且稳定可靠和较高的性价比。     

Preparation and characterization of poly(lactic acid)/poly(methyl methacrylate) blend tablets for application in quantitative analysis by micro Raman spectroscopy

Poly(lactic acid) (PLA) is a biodegradable polymer that has a variety of applications, one of which is as biomaterial in surgery or as functional layers on implants, due to its compatibility with living tissue. This paper reports the possibilities of quantification of poly(lactic acid) (PLA) in a polymer matrix such as poly(methyl methacrylate) (PMMA) by micro Raman spectroscopy (MRS). Blends of amorphous poly(DL‐lactic acid) with poly(methyl methacrylate) were prepared by the procedure of dissolution/precipitation. Thermal properties of the blends such as the glass transition temperature (Tg) were characterized by differential scanning calorimetry (DSC). The PLA/PMMA blends exhibited only a single glass transition region, indicating that this system is miscible. The PLA/PMMA system obeys the Gordon–Taylor equation (Tg versus PLA content). Various concentration ratios of PLA blends were prepared to use as a basis for quantitative analysis by MRS. Intensities of the characteristic bands at 813 cm⁻¹ (νCOC of PMMA) and 873 cm⁻¹ (νC―COO of PLA) were used for the calculation. The calibration graph showed a good linear correlation with an R² value of 0.9985. On the basis of the calibration curve obtained, the determined content of several PLA/PMMA blends was in good agreement when compared with nominal contents. The limit of detection (LOD) and quantification (LOQ) were calculated by the calibration data set as signal‐to‐noise method. The relative standard deviation of this method was lower than 10% and the accuracy better than 4%. This study demonstrated that Raman spectroscopy provides an alternative non destructive method for quantitative analysis of PLA in a PMMA matrix. Copyright © 2015 John Wiley & Sons, Ltd.     

Raman micro‐spectroscopy for quantitative thickness measurement of nanometer thin polymer films

The sensitivity of far‐field Raman micro‐spectroscopy was investigated to determine quantitatively the actual thickness of organic thin films. It is shown that the thickness of organic films can be quantitatively determined down to 3 nm with an error margin of 20% and down to 1.5 nm with an error margin of 100%. Raman imaging of thin‐film surfaces with a far‐field optical microscope establishes the distribution of a polymer with a lateral resolution of ~400 nm and the homogeneity of the film. Raman images are presented for spin‐coated thin films of polysulfone (PSU) with average thicknesses between 3 and 50 nm. In films with an average thickness of 43 nm, the variation in thickness was around 5% for PSU. In films with an average thickness of 3 nm for PSU, the detected thickness variation was 100%. Raman imaging was performed in minutes for a surface area of 900 µm². The results illustrate the ability of far‐field Raman microscopy as a sensitive method to quantitatively determine the thickness of thin films down to the nanometer range. Copyright © 2015 John Wiley & Sons, Ltd.     

High pressure studies using two-stage diamond micro-anvils grown by chemical vapor deposition

Ultra-high static pressures have been achieved in the laboratory using a two-stage micro-ball nanodiamond anvils as well as a two-stage micro-paired diamond anvils machined using a focused ion-beam system. The two-stage diamond anvils’ designs implemented thus far suffer from a limitation of one diamond anvil sliding past another anvil at extreme conditions. We describe a new method of fabricating two-stage diamond micro-anvils using a tungsten mask on a standard diamond anvil followed by microwave plasma chemical vapor deposition (CVD) homoepitaxial diamond growth. A prototype two-stage diamond anvil with 300?µm culet and with a CVD diamond second stage of 50?µm in diameter was fabricated. We have carried out preliminary high pressure X-ray diffraction studies on a sample of rare-earth metal lutetium sample with a copper pressure standard to 86?GPa. The micro-anvil grown by CVD remained intact during indentation of gasket as well as on decompression from the highest pressure of 86?GPa.