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931.
掺镱硼酸盐和磷酸盐激光玻璃的研究 总被引:10,自引:1,他引:10
制备了掺Yb∶硼酸盐和Yb∶磷酸盐玻璃 ,并研究了它们的玻璃物理性质和光谱性质。掺Yb∶磷酸盐玻璃的热机械性质优于掺Yb∶硼酸盐玻璃。掺Yb∶硼酸盐玻璃的受激发射截面和荧光寿命分别为 0 5 3× 10 -2 0 cm2 和 0 85ms。掺Yb∶磷酸盐玻璃的受激发射截面和荧光寿命分别为 0 4 5× 10 -2 0 cm2 和 1 8ms。作为激光材料 ,掺Yb∶磷酸盐玻璃的综合性能优于掺Yb∶硼酸盐玻璃。用钛宝石激光器抽运Yb∶硼酸盐玻璃实现 8mW准连续激光输出。用波长为 976nm ,6W的LD抽运Yb∶磷酸盐玻璃获得了 6 2mW的连续激光输出 ,其斜率效率为 4 4 %。 相似文献
932.
运用频域有限元法研究了一种二维正三角晶格金属光子晶体在太赫兹波段的传输特性。该模型选取空气为背景材料,金属铜为介质柱。通过改变太赫兹波的入射方向、晶格常数和介质柱填充率,对TM模和TE模的传输特性进行了系统完整的分析,获得了太赫兹波在正三角晶格金属光子晶体中的传输规律。结果表明,传输特性随着介质柱填充率、晶格常数及太赫兹波入射方向的变化而变化,且TE模和TM模带隙差异很大,这为太赫兹波段的光子晶体滤波器、反射器和极化器的开发与制作提供了参考依据。 相似文献
933.
激光诱导击穿固体样品中金属元素光谱的实验研究 总被引:5,自引:1,他引:5
激光诱导击穿样品产生的等离子体寿命通常在微秒量级,对其时间演化过程进行了解有利于优化信号采集.定标曲线是定量分析的基础,并且与测量灵敏度和准确度密切相关.采用聚焦的脉冲激光束击穿样品形成等离子体,其发射光谱由中阶梯光栅光谱仪分光,并由增强型电荷耦合器件(ICCD)进行光电探测采集.为了实现对金属元素的激光诱导击穿光谱(LIBS)测量,在石墨中分别加入Ca,Al,Na,K等元素制作成片状实验样品,利用实验装置进行了系统的激光击穿光谱探测研究.应用ICCD100 ns光学门宽的时间分辨率,通过实验得到了等离子体的时间演化特性曲线,分析了激光击穿固体样品后各待测元素的演化过程.根据含有不同浓度的同种元素样品的LIBS实验结果,归纳出各元素浓度与谱线强度的定标曲线,且大多数定标曲线的线性拟合相关度较高.同一元素不同波长的谱线,其定标曲线的斜率不同,对其差异进行了分析. 相似文献
934.
太赫兹波段一维金属线栅的偏振特性研究 总被引:2,自引:0,他引:2
基于时域有限差分法(FDTD)对一维金属线栅结构在0.2~2.6THz波段的偏振特性进行了数值分析,研究了其结构参数如金属占空比、狭缝宽度以及线栅周期对相互垂直的两种偏振模式太赫兹波透射系数的影响。利用光刻和金属膜制备工艺,在1mm厚的高阻硅衬底上淀积了200nm厚的金膜,制成了一系列一维金属线栅结构。利用太赫兹时域光谱系统,实验测量了这些线栅结构的太赫兹透射特性,实验结果与模拟结果规律一致。结果表明:适当设计金属线栅周期,同时满足一定的金属占空比要求,其整体偏振和透射性能能够得到优化。金属线栅结构参数与其太赫兹偏振性能之间的关系为制造太赫兹偏振器提供了参考。 相似文献
935.
选取55Bi2O3-25B2O3-10SiO2-7Ga2O3-3Yb2O3系统铋酸盐玻璃,研究了在不同温度(9-350 K)下Yb3+离子的发射光谱和荧光寿命变化情况,计算了不同温度下Yb3+离子在976和1020 nm的有效线宽△λeff,比较了不同温度下Yb3+离子的光谱特性和荧光寿命变化情况.发现随着测试温度的降... 相似文献
936.
937.
Crystallization evolution and relaxation behavior of high entropy bulk metallic glasses using microalloying process
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《中国物理 B》2021,30(6):66401-066401
The role of the microalloying process in relaxation behavior and crystallization evolution of Zr_(20) Cu_(20) Ni_(20) Ti_(20) Hf_(20) high entropy bulk metallic glass(HEBMG) was investigated. We selected Al and Nb elements as minor elements, which led to the negative and positive effects on the heat of mixing in the master HEBMG composition, respectively. According to the results, both elements intensified β relaxation in the structure; however, α relaxation remained stable. By using different frequencies in dynamic mechanical analysis, it was revealed that the activation energy of β relaxation for the Nb-added sample was much higher, which was due to the creation of significant structural heterogeneity under the microalloying process. Moreover, it was found that Nb addition led to a diversity in crystallization stages at the supercooled liquid region.It was suggested that the severe structural heterogeneity in the Nb-added sample provided multiple energy-level sites in the structure for enhancing the crystallization stages. 相似文献
938.
Metal-organic frameworks (MOFs) are supramolecular nanomaterials, in which metal ions or clusters are connected by organic ligands to form crystalline lattices with highly ordered periodic porous network structure. MOFs have been widely applied in various fields, such as catalyst, sample preparation, and sensing. In recent years, MOFs based surface enhanced Raman scattering (SERS) substrates have attracted much attention since MOFs can largely improve the performance of metallic SERS substrates toward target enrichment and signal enhancement. MOFs have been exploited in SERS analysis to tackle some challenges that bare metal substrates cannot achieve. Combination of MOFs and SERS improved the sensitivity of traditional SERS analysis and extended the application scope of SERS. With the increasing exploration of MOFs based SERS substrates, there is a great demand to review the advances in these researches. Herein, this review concentrated on summarizing the preparation and applications of MOFs based SERS substrates. Representative researches were discussed to better understand the property of MOFs based SERS substrates. The advantages of MOFs based SERS substrates were highlighted, as well as their limitations. In addition, the challenges, opportunities, and future trends in MOFs based SERS analysis were tentatively discussed. 相似文献
939.
The optical, structural and thermal optimizations of Ge33As12Se55 glass were the aim of this study. In this regards, Ge33As12Se45M10 (M = Se, Te, S and S0.5Te0.5) glasses were synthesized by conventional melt quenching technique in quartz ampule. The prepared samples were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR). The fundamental absorption edge for prepared samples was also analyzed in terms of the theory proposed by Davis and Mott. The addition of S and Te elements to melting batch has deleterious effects on optical properties of Ge33As12Se55 glass. Mg and Al can act as gettering elements for reduction of the intensity of oxide absorption bands from FTIR spectra (without any effects on optical properties of Ge33As12Se55 glass). The precipitation of GeSe phase, during crystallization process, has negligible effects on optical properties of Ge33As12Se55 glass. 相似文献
940.
Understanding notch-related failure is crucial for the design of reliable engineering structures. However, substantial controversies exist in the literature on the notch effect in bulk metallic glasses (BMGs), and the underlying physical mechanism responsible for the apparent confusion is still poorly understood. Here we investigate the physical origin of an inverse notch effect in a Zr-based metallic glass, where the tensile strength of the material is dramatically enhanced, rather than decreased (as expected from the stress concentration point of view), by introduction of a notch. Our experiments and molecular dynamics simulations show that the seemingly anomalous inverse notch effect is in fact caused by a transition in failure mechanism from shear banding at the notch tip to cavitation and void coalescence. Based on our theoretical analysis, the transition occurs as the stress triaxiality in the notched sample exceeds a material-dependent threshold value. Our results fill the gap in the current understanding of BMG strength and failure mechanism by resolving the conflicts on notch effects and may inspire re-interpretation of previous reports on BMG fracture toughness where pre-existing notches were routinely adopted. 相似文献