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51.
E.?DesimoniEmail author B.?Brunetti R.?Cattaneo 《Accreditation and quality assurance》2004,9(8):445-449
Considering the uncertainty of measurement when assessing compliance with reference values given in compositional specifications and statutory limits is still a controversial matter. In theory, assessing compliance requires considering both type I (false positive) and type II (false negative) errors. The more the concentration of the analyte in the sample under investigation is close to the allowed concentration limit, the more critical it is to consider both types of errors. This paper describes how this could be done. The matter is discussed in the light of the most recent literature information. 相似文献
52.
Nabel A. Negm Mohamed F. Zaki Mounir A. I. Salem 《Journal of Dispersion Science and Technology》2013,34(10):1390-1395
A novel series of cationic Gemini amphiphiles containing Dischiff base species were synthesized and their chemical structures were determined using different analytical tools. Their surface properties were determined using surface tension measurements. The adsorption and micellization thermodynamic parameters were calculated using Gibb's equations at 25°C. The surface parameters were also determined including critical micelle concentration, effectiveness, efficiency, maximum surface excess, minimum surface area, interfacial tension, and emulsification power. The synthesized cationic Gemini surfactants were evaluated as bactericides for gram negative and gram positive bacteria and also against sulfur reducing bacteria (SRB). The results of the cytotoxicity of the synthesized compounds against the targeted bacterial strains were promising and completely dependent on the surface activity of these compounds. 相似文献
53.
Jianye Ge Benjamin Crysup Dixie Peters Romy Franco Muyi Liu Xuewen Wang Meng Huang Bruce Budowle 《Electrophoresis》2023,44(13-14):1080-1087
Y chromosome Short Tandem Repeat (STR) haplotypes have been used in assisting forensic investigations primarily for identification and male lineage determination. The current SWGDAM interpretation guidelines for Y-STR typing provide helpful guidance on those purposes but do not address the issue of kinship analysis with Y-STR haplotypes. Because of the high mutation rate of Y-STRs, there are complex missing person cases in which inconsistent Y-STR haplotypes between true paternal lineage relatives will arise and cases with two or more male references in the same lineage and yet differ in their haplotypes. Therefore, more useful methods are needed for interpreting the Y-STR haplotype data. Computational methods and interpretation guidelines have been developed specifically addressing this issue, either using a mismatch-based counting method or a pedigree likelihood ratio method. In this study, a software program, MPKin-YSTR, was developed by implementing those more sophisticated methods. This software should be able to improve the interpretation of complex cases with Y-STR haplotype evidence. Thus, more biological evidence will be interpreted, which in turn will result in more investigation leads to help solve crimes. 相似文献
54.
55.
The kinetics of the surface tension of micellar solutions of nonionic surfactant Triton X-100 is measured experimentally by means of three different techniques: oscillating jet, maximum bubble pressure and inclined plate. They allow to study the micellization kinetics at various time scales (from a few milliseconds to a few seconds) in fairly large concentration region up to 50 times CMC. The experimental data are satisfactorily explained by a theoretical model accounting for the kinetics of micellization, diffusion of surfactant species and expansion of the bubble interface. By this model are computed the characteristic times of diffusion and micellization, which are of comparable magnitude (about 5 to 200 ms), and the Gibbs' elasticity. The micellization time constant corresponds to the slow relaxation process known to coincide with the disintegration of micelles. Comparing our data with other data from literature one can conclude that more realistic information for the micellization kinetics is obtained by the maximum bubble pressure and the oscillating jet method. The inclined plate seems too slow to measure the relaxation processes in micellar solutions of this surfactant. 相似文献
56.
Recent developments in quantitative surface analysis by Auger (AES) and x-ray photoelectron (XPS) spectroscopies are reviewed and problems relating to a more accurate quantitative interpretation of AES/XPS experimental data are discussed. Special attention is paid to consideration of elementary physical processes involved and influence of multiple scattering effects on signal line intensities. In particular, the major features of core-shell ionization by electron impact, Auger transitions and photoionization are considered qualitatively and rigorous approaches used to calculate the respective transition probabilities are analysed. It is shown that, in amorphous and polycrystalline targets, incoherent scattering of primary and signal Auger and photoelectrons can be described by solving analytically a kinetic equation with appropriate boundary conditions. The analytical results for the angular and energy distribution, the mean escape depth, and the escape probability as a function of depth of origin of signal electrons as well as that for the backscattering factor in AES are in good agreement with the corresponding Mote Carlo simulation data. Methods for inelastic background subtraction, surface composition determination and depth-profile reconstructions by angle-resolved AES/XPS are discussed. Examples of novel techniques based on x-ray induced photoemission are considered. 相似文献
57.
Meena Kumari Upendra Kumar Singh Abbul Bashar Khan Maqsood Ahmad Malik 《Journal of Dispersion Science and Technology》2018,39(10):1462-1468
The effect of bovine serum albumin on the surface properties of IL-type gemini surfactant ([C10-4-C10im]Br2), have been investigated by surface tension method. The critical micelle concentration (CMC) as a function of BSA concentrations at various temperatures was investigated. The CMC of [C10-4-C10im]Br2 increases with increasing the concentration of BSA as well as the temperature of the system. The interfacial parameters viz; maximum surface excess concentration (Γmax), the minimum area per molecule (Amin), and surface pressure at CMC (Πcmc) were calculated. In addition, thermodynamic parameters of adsorption and micellization were evaluated by using surface tension data. The results indicated that the binding of [C10-4-C10im]Br2 to BSA is spontaneous and exothermic in nature. The process is entropy driven and hydrophobic interactions are the major driving forces. 相似文献
58.
The effect of the micelles on the dynamic surface tension of micellar surfactant solutions is studied experimentally by means of the maximum bubble pressure method. Different frequencies of bubbling ranging approximately between 1 and 30 s–1 are applied. The time dependence of the surface tension is calculated using a dead time correction. Water solutions of two types of surfactants with different concentrations are investigated: sodium dodecyl sulfate and nonylphenol polyglycol ether. The surface tension relaxes more quickly in the presence of micelles. The characteristic times of relaxation of the surface tension seem to be in the millisecond range. The time constants observed experimentally are explained in terms of the theory of surfactant diffusion affected by micellization kinetics. 相似文献
59.
虽然双系统估计量目前是人口普查质量评估领域估计总体实际人口数的主要方法,但其内在固有的缺陷却依然存在,即由于人口普查与其质量评估调查不独立引起的交互作用偏差使其低估或高估人口数。独立性假设失败源于在普查及其质量评估调查中登记的因果相关性,以及在普查及质量评估调查中登记概率的异质性。Bell模型是当前公认的测算交互作用偏差的有效方法。该方法建立在0-17岁及成年女性的双系统估计值不存在交互作用偏差的假设条件下。利用美国普查局提供的2010年资料全面展示了双系统估计量交互作用偏差的测算过程。实证结果表明,黑人成年男性的双系统估计值存在显著的交互作用偏差。研究有助于我国在未来人口普查质量评估工作中意识到交互作用偏差的存在,把测算的交互作用偏差添加到双系统估计量估计的人口数中,并依据修正后的双系统估计值计算人口普查净误差。 相似文献
60.
Kaylea Haynes Idris A. Eckley Paul Fearnhead 《Journal of computational and graphical statistics》2017,26(1):134-143
In the multiple changepoint setting, various search methods have been proposed, which involve optimizing either a constrained or penalized cost function over possible numbers and locations of changepoints using dynamic programming. Recent work in the penalized optimization setting has focused on developing an exact pruning-based approach that, under certain conditions, is linear in the number of data points. Such an approach naturally requires the specification of a penalty to avoid under/over-fitting. Work has been undertaken to identify the appropriate penalty choice for data-generating processes with known distributional form, but in many applications the model assumed for the data is not correct and these penalty choices are not always appropriate. To this end, we present a method that enables us to find the solution path for all choices of penalty values across a continuous range. This permits an evaluation of the various segmentations to identify a suitable penalty choice. The computational complexity of this approach can be linear in the number of data points and linear in the difference between the number of changepoints in the optimal segmentations for the smallest and largest penalty values. Supplementary materials for this article are available online. 相似文献