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We extend the matrix version of Cochran's statistical theorem to outer inverses of a matrix. As applications, we investigate the Wishartness and independence of matrix quadratic forms for Kronecker product covariance structures. 相似文献
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The crystallization of poly(ethylene terephthalate) under uniaxial tensile strain at different extension rates was investigated with optical polarimetry in a temperature range between the glass-transition temperature and the quiescent crystallization temperature. The evolution of the optical properties of the polymer, including the turbidity, birefringence, and dichroism, were monitored simultaneously with the mechanical parameters. To complete the semicrystalline microstructure characterization of the polymer under strain, an online wide-angle X-ray diffraction (WAXD) technique was used in separate experiments, which were performed under the same thermomechanical conditions. For real-time measurements, a high-energy synchrotron radiation source was used. The optical properties provided information about both the crystalline and amorphous phases, whereas the WAXD patterns essentially gave information about the crystalline phase. The two experimental techniques were then used in a complementary way to characterize the semicrystalline microstructure. Significant deviations from the stress-optical rule were found. This was attributed to both transient effects and the appearance of crystallites, which consisted of highly oriented molecular segments that could contribute to the optical anisotropy but not necessarily to the stress. The behavior of the optical dichroism was found to be qualitatively different from that of the birefringence. The latter monotonically increased with the strain, whereas the former first increased with the strain, passed through a maximum, and then decreased to a steady-state value. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1915–1927, 2004 相似文献
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Sang Kyu Lee Min Ju Cho Jung‐Il Jin Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):531-542
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007 相似文献
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Experiments for the determination of mono-, di and tri-butyltin (MBT, DBT and TBT) by hydride generation/gas chromatography/atomic absorption spectrometry in various matrices (sediment, suspended matter, mussel, algae and water) have revealed that poor butyltin recoveries are obtained in sediments displaying high sulphur and hydrocarbon contents; very poor recoveries were also observed for TBT in sediments with high chlorophyll pigment contents as well as in algal samples. It was however not clear whether the hydride generatin was inhibited by these infering compounds, as was previously assumed in the case of hydrocarbons, or whether interferences affected the atomization rate. Further studies were performed to solve this problem in order to validate this method in the case of analyses of, for example, oil-contaminated sediment and algae. This paper presents the results obtained. It is concluded here that the poor recoveries were due to an inhibition of hydride generation rather than to interference at the atomization stage. 相似文献
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混沌光学系统的前向神经网络系统辨识研究 总被引:2,自引:0,他引:2
为解决混沌光学系统自适应控制所需之控制参考动力学模型问题,以布拉格声光混沌系统的系统辨识为例.研究了利用前向神经网络对混沌光学系统进行系统辩识的可行性。计算机仿真实验发现.在静态BP算法支持下一结构十分简单的三层BP前向神经网络(1:4:1)即可在一定的精度范围内完成对布拉格声光混沌系统的系统辨识.此结果表明.三层前向BP神经网络在静态BP算法的支持下确是一良好的混沌光学系统辨识器,因而可用来处理混沌光学时间序列以进行混沌光学系统的动力学重构。 相似文献
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介绍了一种专为时分复用系统设计的时院分配计算算法。这种算法中主要用到的技术是从一个话务矩阵的各行选出一个区别代表的系统方法。对于任何话务矩阵,这种算法的分配效率都能达到100%,所产生的模式矩阵个数最多为n2-2n+2个(对于n×n矩阵)。 相似文献
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本文提出光束轨迹方程的一般解,导出解析解的存在条件,推广了文献[1]的光线传播理论,文中以一特定梯度折射率棒为例,讨论了高斯光束在棒中的传播特性。 相似文献