Angular momenta and eigenvectors of the weakly coupled T ⊗ t Jahn‐Teller system

The eigenvalues of the weakly coupled T ? t Jahn‐Teller problem are known for several decades, and the same holds also true for the eigenstates. These, however, are only given in the traditional position representation, which proves inconvenient if one attempts to extend the weak‐coupling treatment into the region of stronger coupling. Here the solution of the T ? t eigenvalue problem at weak coupling is derived in terms of creation and annihilation operators. This reformulation of the problem is nontrivial, since the algebraic form of the oscillator eigenvectors, being simultaneous angular‐momentum eigenstates, has been worked out only recently and is probably still widely unknown. The electronic and oscillator eigenstates are then coupled to form eigenvectors of the total angular momentum. Finally, in preparation for an extension of the weak‐coupling treatment, the action of the boson creation and annihilation operators on the oscillator eigenvectors is calculated, thus completing the algebraic approach to the weakly coupled T ? t system.     

磁学研究与三环公司发展

简要回顾了20世纪20年代以来我国现代磁学研究的历史。20世纪80年代初期正值我国改革开放浪潮之时，科技人员纷纷走上科技成果产业化道路。建立于1985年的中国科学院三环公司就是一个成功的代表，同时好也是我国现代磁学研究结出的一颗硕果。     

Optical current transducers using flint glass fiber as the faraday sensor element

This paper describes development of the optical current transducers using flint glass fiber as the Faraday effect sensing element. Excellent polarization properties of the fiber with low birefringence are described, and the design and test data of a current transducer using the fiber manufactured for use in electric power facilities are reviewed. Experimental results on flexible characteristics of a scheme with round trip light transmission in the fiber is also reported.     

Effect of hydrogen on interatomic bonds in austenitic steels

Mössbauer spectroscopy was used to investigate the influence of dissolved hydrogen on the interatomic bonds in austenitic steels. It was carried out to prove the decohesion mechanism of hydrogen embrittlement (HE). It is shown that hydrogen increases Debye temperature, i.e., the interatomic bonds in hydrogenated austenitic steel becomes stronger.     

Chain length effect on dynamical structure of poly (vinyl pyrrolidone)-polar solvent mixtures in dilute solution of dioxane studied by microwave dielectric relaxation measurement

Dielectric relaxation study of the binary mixtures of poly(vinyl pyrrolidone) (PVP) (Mw=24000, 40000 and 360000 g mol⁻¹) with ethyl alcohol (EA) and poly(ethylene glycol)s (PEGs) (Mw=200 and 400 g mol⁻¹) in dilute solutions of dioxane were carried out at 10.1 GHz and 35°C. The relaxation time of PVP-EA mixtures was interpreted by the consideration of a wait-and-switch model in the local structure of self-associated ethyl alcohol molecules and also the PVP chain length as a geometric constraint for the reorientational motion of ethyl alcohol molecules. The formation of complexes and effect of PVP chain length on the molecular dynamics, chain flexibility and stretching of PEG molecules in PVP-PEG mixtures were explored from the comparative values of dielectric relaxation time. Further, relaxation time values in dioxane and benzene solvent confirm the viscosity independent molecular dynamics in PVP-EA mixtures but the values vary significantly with the non-polar solvent environment.     

Reactions of mercury salts with benzo- and tetrafluorobenzobarrelenes

Regiochemistry and stereochemistry of the addition of mercury salts to benzobarrelene and tetrafluorobenzobarrelene have been studied in acetic acid and methanol. The effect of the substrate structure on the regiochemistry of the reaction is discussed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1105–1108, June, 1994.     

高功率板条固体激光器研究的进展

本文对高功率板条固体激光器研究的进展和应用前景作了综合评述。结合作者部分工作,对板条激光器的热效应、聚光器和光学谐振腔等关键问题和技术进行了物理分析。     

High spin chemistry underlying organic molecular magnetism: Topological symmetry rule as the first principle of spin alignment in organic open-shell systems of π-conjugation and their ions

This review paper deals with an overview of molecule-based magnetism as a rapidly developing interdisciplinary field, topological symmetry rule as the first principle of spin alignment in organic open-shell systems in the ground state, the proposal of organic through-bond 1D and 2D ferro- and superparamagnets and the detection of the first organic high-spin molecule, m-phenylenebis(phenylmethylene) in the quintet ground state (S = 2), followed by extended organic high-spin systems with π-conjugation such as aromatic hydrocarbons having S = 3, 4, 5. The paper also describes a theoretical approach to the understanding of electronic spin structures of organic high-spin molecules by invoking both Heisenberg and Hubbard model Hamiltonians, weakly interacting intramolecular high-spin systems from both experimental and theoretical sides, the spin density distribution of the first organic high-spin molecule in terms of electron- nuclear multiple resonance spectroscopy and the detection and characterization of ionic high-spin hydrocarbons, emphasizing the establishment of high spin chemistry underlying organic molecular magnetism.     

基于移动端多天线系统的无线衰落信道模型

根据当前无线移动通信对多天线移动接收端性能仿真的要求，讨论并建立了适于空时信号处理的移动端矢量信道模型。通过分析无线移动信道特点。研究了影响接收信号幅度相位的诸多因素，建立了相应的数学模型。并对随机参数选取进行了探讨。其中考虑到移动端接收信号到达角扩散的特点，采用GBSB椭圆模型产生了适于移动端接收信号仿真的随机角度，改进了一种瑞利衰落生成算法。最后信道的数值仿真结果符合理论和经验。同时，通过TD-SCDMA系统链路级仿真，也证明了该信道模型的有效性。     

自成像列阵共振腔的分析——Ⅰ.Talbot共振腔

利用自成像效应进行半导体列阵激光器锁相是一种重要的外腔锁相技术,所构成的共振腔可分为Talbot腔和带相位补偿板的Lau腔。我们用Fox-Li方法计算了共振模式。本文给出了Talbot腔的计算结果和分析,表明同相和反相模的损耗随腔长变化存在临界点。