Accuracy of high‐order density‐based compressible methods in low Mach vortical flows

At low Mach numbers, Godunov‐type approaches, based on the method of lines, suffer from an accuracy problem. This paper shows the importance of using the low Mach number correction in Godunov‐type methods for simulations involving low Mach numbers by utilising a new, well‐posed, two‐dimensional, two‐mode Kelvin–Helmholtz test case. Four independent codes have been used, enabling the examination of several numerical schemes. The second‐order and fifth‐order accurate Godunov‐type methods show that the vortex‐pairing process can be captured on a low resolution with the low Mach number correction applied down to 0.002. The results are compared without the low Mach number correction and also three other methods, a Lagrange‐remap method, a fifth‐order accurate in space and time finite difference type method based on the wave propagation algorithm, and fifth‐order spatial and third‐order temporal accurate finite volume Monotone Upwind Scheme for Conservation Laws (MUSCL) approach based on the Godunov method and Simple Low Dissipation Advection Upstream Splitting Method (SLAU) numerical flux with low Mach capture property. The ability of the compressible flow solver of the commercial software, ANSYS FLUENT , in solving low Mach flows is also demonstrated for the two time‐stepping methods provided in the compressible flow solver, implicit and explicit. Results demonstrate clearly that a low Mach correction is required for all algorithms except the Lagrange‐remap approach, where dissipation is independent of Mach number. © 2013 Crown copyright. International Journal for Numerical Methods in Fluids. © 2013 John Wiley & Sons, Ltd.     

Channel length influenced contribution of hole and electron trapping effect to threshold voltage stability in organic field effect transistors

Effect of channel length on hysteresis and threshold voltage shift in copper phthalocyanine (CuPc) based organic field effect transistors was studied. Contrary to expectation, longer channel length devices exhibited minimum threshold voltage shift. Influence of channel length on the contribution of hole and electron trapping to threshold voltage stability was determined. Shortest channel length devices exhibited highest electron trapping effect while longest channel devices exhibited minimum hole as well as electron trapping. Lower hole trap effect for longer channel length devices was suggested to be due to reduced longitudinal field between source and drain electrodes while minimum electron trapping was attributed to suppression of drain current by increased hole trap centres.     

宽带毫米波大规模MIMO系统中低复杂度波束域信道估计

针对宽带毫米波大规模MIMO系统信道估计精度低及实现复杂度较高的问题，在传统支撑检测方案的基础上提出一种基于Gauss-Seidel方法的串行支撑检测（GS-SSD）方案。该方案不使用共同支撑假设，参考串行干扰删除，将整体信道估计问题分解为一系列子问题，每个子问题仅考虑一个信道成分。同时，利用Gauss-Seidel方法近似高复杂度的矩阵求逆。仿真结果表明，相比于基于串行支撑检测（SSD）的方案， GS-SSD方案在将求逆复乘数降低一个数量级的同时可以取得接近SSD方案的信道估计性能。     

Flat band voltage modulation of AlGaN/GaN MOS capacitor with stacked Al2O3/La2O3 high dielectric structures

AlGaN/GaN metal-oxide-semiconductor (MOS) capacitor structures using atomic layer deposited high-dielectric-constant (High-k) Al₂O₃/La₂O₃ bilayer films as dielectric have been investigated using high-frequency capacitance-voltage measurement. The stable thickness and uniform surface morphology of the bilayer films with different La/Al deposition cycle ratio (La/Al ratio) were observed after rapid thermal annealing by spectroscopic ellipsometry and atomic force microscopy, respectively. We have found that with a decrease of the La/Al ratio, the dipole layer observed by X-ray photoelectron spectroscopy at Al₂O₃/La₂O₃ interfaces is close to the surface of semiconductor and the flat band voltage shifts to the negative direction. Furthermore, the dramatic drop in dielectric constant of the films as La/Al ratio decrease was caused by the formation of La(OH)₃ in La₂O₃. Finally, the reason for the flat band voltage shifts, which is based on the dielectric constant of Al₂O₃ and La₂O₃ comprising the position of dipole layer in the dielectric films, is proposed.     

Thermosetting resins from a tetra-functional vinylbenzene compound possessing cyclic siloxane cores

Cyclic siloxane is an attractive building block for incorporation of silicon-containing units as well as their distinguished properties to polymer materials. This work reports the synthesis and characterization of a tetra-functional vinylbenzene compound possessing cyclic siloxane cores (cD₄-4VB). Synthesis of cD₄-4VB is carried out using cD₄-4SiH as the reactive precursor and multiple-step reactions, including hydrosilylation, deacetylation, and S_N2 substitution. cD₄-4VB is an effective monomer for preparation of the corresponding cyclic silicon-based thermosetting resins (CR-cD₄-4VB). CR-cD₄-4VB shows attractive film formability and good thermo-mechanical properties, including a storage modulus of 2.0 GPa, a glass transition temperature of 282°C, a thermal stability above 400°C, a high char yield (at 800°C in nitrogen) of 55 wt%, and a dielectric constant of 3.12 at 10 GHz. This kind of resins have potential of application for halogen-free flame retardants and high-performance polymer films.     

低截止频率多倍频程高增益对跖Vivaldi天线北大核心CSCD

针对传统对跖Vivaldi天线的最低截止工作频率较高、增益较低和方向性较差的问题,文中设计了一种新型超宽带对跖Vivaldi天线。融合运用辐射极板开矩形斜槽、加载吸收电阻和寄生矩形贴片等一系列电磁调控措施,扩展了天线的低频工作带宽;采取在天线极板间加载椭圆寄生贴片的技术方式大幅提高了天线的方向性和辐射增益。最后给出了天线的设计流程,从电场分布和表面电流分布的角度揭示了天线的微观工作机制。仿真和实测结果表明:天线的工作频带为0.85~16 GHz(近20倍频程),相对带宽达180%,在3 GHz以上频段增益均超过10 dBi,并且具有较好的端射方向性,在超宽带无线通信、雷达探测、电子对抗和遥感遥测等领域具有广泛的应用前景。     

Direct model-based predictive control scheme without cost function for voltage source inverters with reduced common-mode voltage

This paper presents a direct model-based predictive control scheme for voltage source inverters (VSIs) with reduced common-mode voltages (CMVs). The developed method directly finds optimal vectors without using repetitive calculation of a cost function. To adjust output currents with the CMVs in the range of –V_dc/6 to +V_dc/6, the developed method uses voltage vectors, as finite control resources, excluding zero voltage vectors which produce the CMVs in the VSI within ±V_dc/2. In a model-based predictive control (MPC), not using zero voltage vectors increases the output current ripples and the current errors. To alleviate these problems, the developed method uses two non-zero voltage vectors in one sampling step. In addition, the voltage vectors scheduled to be used are directly selected at every sampling step once the developed method calculates the future reference voltage vector, saving the efforts of repeatedly calculating the cost function. And the two non-zero voltage vectors are optimally allocated to make the output current approach the reference current as close as possible. Thus, low CMV, rapid current-following capability and sufficient output current ripple performance are attained by the developed method. The results of a simulation and an experiment verify the effectiveness of the developed method.     

High efficiency of Mn–Ce‐modified TiO2 catalysts for the low‐temperature oxidation of Hg0 under a reducing atmosphere

Manganese‐ and cerium oxide‐modified titania catalysts were prepared by the deposition precipitation for the removal of elemental mercury (Hg⁰) from simulated yellow phosphorus off‐gas at low temperature. In addition, these catalysts were characterized by X‐ray diffraction, Brunauer–Emmett–Teller measurements, X‐ray photoelectron spectroscopy and field‐emission scanning electron microscope to determine the surface morphology of the obtained compounds and explore their formation mechanism. The results revealed that a Mn–Ce loading and reaction temperature of 10% and 150 °C, respectively, as well as a Mn/Ce molar ratio of 2:1, led to an optimal efficiency for the oxidation of elemental mercury. Furthermore, the effects of flue gas components were investigated. The presence of O₂ clearly promoted the oxidation of Hg⁰. A CO atmosphere did not affect the Hg⁰ oxidation, when compared with N₂, whereas the presence of H₂S and water vapor inhibited the oxidation process. Furthermore, the X‐ray photoelectron spectroscopy spectra of Hg 4f revealed that the elemental mercury adsorbed by the catalyst is present as HgO. Finally, the Hg⁰ catalytic oxidation mechanism was discussed on the basis of the experimental results and characterization analysis.     

融合前沿研究的液体电介质击穿教学研究

针对《高电压与绝缘技术》课程中液体电介质的教学难点，提出了融合前沿研究的液体电介质击穿教学方法。基于前沿的液体放电应用背景与先进的液体放电研究平台，形象地展示液体电介质的动态击穿过程，在教学内容、教学方法、考核方式等方面进行科教融合改进，实施“以学生为中心”理念的课程教学设计。该教学方式取得了较好的教学效果，能够为其它知识点的教学质量提升提供参考。     

Pitch-Based Laminated Carbon Formed by Pressure Driving at Low Temperature as High-Capacity Anodes for Lithium Energy Storage Systems

Pitch has been used to prepare electrodes by high-temperature heat treatments for supercapacitors, lithium-ion batteries, on account of its rich aromatic ring structure. Here, the toluene-soluble component of pitch is used to prepare a kind of laminated carbon. This was realized by a template-free synthesis at low temperature with the addition of pressure. The toluene-soluble component has a small molecular weight, which makes the thermal deformation ability stronger and then enhances the orientation of the carbon layer with the help of pressure. The prepared anode exhibits a splendid electrochemical performance compared with the traditional graphite anode. A high stable capacity of approximately 550 mAh g⁻¹ at 50 mA g⁻¹, which is much higher than graphite (372 mAh g⁻¹), is obtained. Also, when the current density is up to 2 A g⁻¹, the capacity is about 150 mAh g⁻¹. Surprisingly, it also delivers a superior cycling performance. And when used as the anode/cathode electrode for lithium-ion capacitors, a high energy density can be obtained. The present work offers an opportunity to utilize the pitch source in lithium energy storage with promising cycle life, high energy/power density, and low cost.