High efficiency of Mn–Ce‐modified TiO2 catalysts for the low‐temperature oxidation of Hg0 under a reducing atmosphere

Manganese‐ and cerium oxide‐modified titania catalysts were prepared by the deposition precipitation for the removal of elemental mercury (Hg⁰) from simulated yellow phosphorus off‐gas at low temperature. In addition, these catalysts were characterized by X‐ray diffraction, Brunauer–Emmett–Teller measurements, X‐ray photoelectron spectroscopy and field‐emission scanning electron microscope to determine the surface morphology of the obtained compounds and explore their formation mechanism. The results revealed that a Mn–Ce loading and reaction temperature of 10% and 150 °C, respectively, as well as a Mn/Ce molar ratio of 2:1, led to an optimal efficiency for the oxidation of elemental mercury. Furthermore, the effects of flue gas components were investigated. The presence of O₂ clearly promoted the oxidation of Hg⁰. A CO atmosphere did not affect the Hg⁰ oxidation, when compared with N₂, whereas the presence of H₂S and water vapor inhibited the oxidation process. Furthermore, the X‐ray photoelectron spectroscopy spectra of Hg 4f revealed that the elemental mercury adsorbed by the catalyst is present as HgO. Finally, the Hg⁰ catalytic oxidation mechanism was discussed on the basis of the experimental results and characterization analysis.     

Pitch-Based Laminated Carbon Formed by Pressure Driving at Low Temperature as High-Capacity Anodes for Lithium Energy Storage Systems

Pitch has been used to prepare electrodes by high-temperature heat treatments for supercapacitors, lithium-ion batteries, on account of its rich aromatic ring structure. Here, the toluene-soluble component of pitch is used to prepare a kind of laminated carbon. This was realized by a template-free synthesis at low temperature with the addition of pressure. The toluene-soluble component has a small molecular weight, which makes the thermal deformation ability stronger and then enhances the orientation of the carbon layer with the help of pressure. The prepared anode exhibits a splendid electrochemical performance compared with the traditional graphite anode. A high stable capacity of approximately 550 mAh g⁻¹ at 50 mA g⁻¹, which is much higher than graphite (372 mAh g⁻¹), is obtained. Also, when the current density is up to 2 A g⁻¹, the capacity is about 150 mAh g⁻¹. Surprisingly, it also delivers a superior cycling performance. And when used as the anode/cathode electrode for lithium-ion capacitors, a high energy density can be obtained. The present work offers an opportunity to utilize the pitch source in lithium energy storage with promising cycle life, high energy/power density, and low cost.     

Substrate noise isolation improvement in a single-well standard CMOS process

This work describes a fully CMOS compatible methodology, which makes available a pseudo deep n-well in single-well standard CMOS process. The proposed method is based on mask manipulation to accommodate the field implant p-type region into the n-well, and does not require any additional masks or modification in the CMOS process flow. According to the experimental results, the floating NMOS made available by the methodology shows a reduction in the threshold voltage, which implies a slight improvement in its performance, when compared with its standard NMOS counterpart. It was also experimentally demonstrated up to 3 GHz, that the guard-ring field implant/pseudo deep n-well proposed structure improves substrate noise isolation when compared to the classical p+ guard-ring, with a maximum improvement above 20 dB for low frequencies and a minimum of 4 dB at 3 GHz.     

Microstructure change in deuterium implanted CLAM steel induced by electron irradiation

As Reduced Activation Ferritic/Martensitic (RAFM) steel is considered the primary candidate for use as a structural material in fusion power reactors,many countries are developing different kinds of RAFM.China is developing new CLAM (China Low Activation Martensitic) steel.The study investigates microstructural changes in CLAM steel implanted with deuterium ions induced by 1250 keV electron irradiation from R.T.to 873 K,and observes both the growth and shrinkage of the defect clusters produced by deuterium ...     

Multi-scale noise estimation for image splicing forgery detection

Noise discrepancies in multiple scales are utilized as indicators for image splicing forgery detection in this paper. Specifically, the test image is initially segmented into superpixels of multiple scales. In each individual scale, noise level function, which reflects the relation between noise level and brightness of each segment, is computed. Those segments not constrained by the noise level function are regarded as suspicious regions. In the final step, pixels appears in suspicious regions of each scale, after necessary morphological processing, are marked as spliced region(s). The Optimal Parameter Combination Searching (OPCS) Algorithm is proposed to determine the optimal parameters during the process. Two datasets are created for training the optimal parameters and to evaluate the proposed scheme, respectively. The experimental results show that the proposed scheme is effective, especially for the multi-objects splicing. In addition, the proposed scheme is proven to be superior to the existing state-of-the-art method.     

Noise Feedback Coding Revisited： Refurbished Legacy Codecs and New Coding Models

Noise feedback coding(NFC) has attracted renewed interest with the recent standardization of backward-compatible enhancements for ITU-T G.711 and G.722.It has also been revisited with the emergence of proprietary speech codecs,such as BV16,BV32,and SILK,that have structures different from CELP coding.In this article,we review NFC and describe a novel coding technique that optimally shapes coding noise in embedded pulse-code modulation(PCM) and embedded adaptive differential PCM(ADPCM).We describe how this new technique was incorporated into the recent ITU-T G.711.1,G.711 App.III,and G.722 Annex B(G.722B) speech-coding standards.     

Signal noise perturbation on automotive mixed-mode semiconductor device generated by graded substrate defect

The semiconductor technologies evolution allows greatly reducing noise impact on products and many structures have been created to reduce its effect. However, this paper presents the apparition of a noise issue during the production of a mixed-mode device dedicated to automotive applications. The research investigations concerned the fact that failure was not detected at test level but at customer level; therefore, it was determinant to understand the root cause of this failure mode to drive corrective actions in order to secure customer. The challenge was to analyse noise in Failure Analysis (FA) without fault spatial localization results. Indeed, Light Emission Microscopy (EMMI) and Thermal Laser Stimulation (ex: Soft Defect Localization – SDL) were unable to provide any defective area in the product. The lack of failing device identification led us to combine electrical and design analyses in order to define hypothesis on the failure origin. It was then possible to drive physical investigations through different approaches, using physical cross-section, Secondary Ion Mass Spectrometry (SIMS) and Scanning Capacitance Microscopy (SCM) techniques. Finally, the obtained complementary results will be discussed and an explanation of the failure mechanism will be presented as the root cause issue, allowing defining the defective step in production process.     

A wireless multi-channel implantable neural recording microsystem based on optimized analog TDM-FDM combination

Crosstalk noise (CT) is a limiting factor to increase the number of channels in analog Time-Division-Multiplexing (TDM)-based Wireless Neural Recording microsystems (WNRs). This paper proposes a novel approach to mitigate and decrease the effect of the CT by combining TDM with Frequency-Division-Multiplexing (FDM). In particular, we evaluate some possible configurations of the TDM-FDM combination and present a system that has less CT than other configurations. A 12-channel WNR based on the proposed system is designed in both system and circuit-level. In this system, channels are first divided into three 4-channel groups and after multiplexing in time domain, they are combined together with FDM method. While the group containing the marker pulse is located in the base-band, the second and third group are shifted to the frequency domain by employing quadrature modulation. The circuit-level of the system is designed and simulated by using 0.18 μm CMOS technology. The designed circuit consumes a power of 1.4 mW at a supply voltage of 1.8 V. The performance of the proposed system is also compared with simple TDM-based WNR. Simulations shows that in the proposed system the CT is considerably decreased.     

Pinacol Coupling of Aromatic Aldehydes and Ketones in Ethyl Acetate Mediated by TiCl4‐Mg

Titanium tetrachloride in ethyl acetate can be reduced by Mg powder to the corresponding low‐valent titanium complexes, which can reduce some aromatic aldehydes and ketones to the corresponding pinacols in 38–85% yields within 15–60 min at rt with stirring.     

A 3D-DCT video encoder using advanced coding techniques for low power mobile device

The three-dimensional discrete cosine transform (3D-DCT) has been researched as an alternative to existing dominant video standards based on motion estimation and compensation. Since it does not need to search macro block for inter/intra prediction, 3D-DCT has great advantages for complexity. However, it has not been developed well because of poor video quality while video standards such as H.263(+) and HEVC have been blooming. In this paper, we propose a new 3D-DCT video coding as a new video solution for low power mobile technologies such as Internet of Things (IoT) and Drone. We focus on overcoming drawbacks reported in previous research. We build a complete 3D-DCT video coding system by adopting existing advanced techniques and devising new coding algorithms to improve overall performance of 3D-DCT. Experimental results show proposed 3D-DCT outperforms H.264 low power profiles while offering less complexity. From GBD-PSNR, proposed 3D-DCT provides better performance by average 4.6 dB.