Study of Sorption of 2,4‐D on Outer Peristaltic Part of Waste Tire Rubber Granules

From this study it was evident that outer peristaltic parts of waste tire granules gave the highest removal. Film and pore diffusions are the major factors controlling rates of sorption from solution by porous adsorbents. For sorption of 2,4‐D on waste tire rubber granules, the sorption rate coefficient of second‐order kinetic equation was utilized indirectly to determine the rate‐limiting step. The diffusion coefficient lies in the scale of 10^?8 cm²/s, and the pore diffusion coefficient is in the range of 10^?9–10^?10 cm²/s. So both film and pore diffusion are rate limiting. Considering external mass transfer from fluid to particle, using the effect of initial concentration, and using the effect of adsorbent size, no conclusion was reached regarding rate‐controlling steps. It is apparent from the study that external mass transfer (film diffusion) as well as intra‐particle diffusion (pore diffusion) play significant roles in the sorption process for 2,4‐D removal from water onto rubber granules.     

正整数的一类三分拆的应用

利用正整数n的一类特殊的3分拆n=n1+n2+n3,n1>n2>n3≥1,且n2+n3>n1的Ferrers图将不定方程4x1+3x2+2x3=n(n≥9)的正整数解与这种分拆联系起来,从而得到了该不定方程的正整数解数公式;同时也给出了正整数n的一类4分拆的计数公式.此外,还给出了周长为n的整边三角形的计数公式的一个简单证明.     

Regioselectivity Study on Propylene Polymerization Catalyzed by Neutral Salicyladiminato Pd（Ⅱ） Model Complex with DFT Method

Many attempts have been made to control the regioselectivity for olefin polymerization by varying the structures of ligands in catalysts. The regioselectivity of propylene polymerization was investigated by replacing a nitrogen atom in the Pd(Ⅱ) diimine catalyst with an oxygen atom from density functional theory method at the B3LYP/LANL2DZ level. The results show that the 1,2-insertion becomes a rival mechanism to the 2,1-insertion when the nitrogen atom is replaced by the oxygen atom leading to an asymmetric environment in the catalyst, and that the steric effect in the asymmetrical catalyst plays an important part in the polymerization. The insertion barrier from 2-O is much higher than that from 2-N. A pyramid transition state was characterized for the catalyst to convert 2-O back to 2-N through internal rotation. The propylene prefers to coordinate at the opposite side of O in the catalyst. This is the driving force for the internal rotation.The results are significant for isotactic and syndiotactic polymerization.     

Modal part analysis of slosh of the liquid in a cylindrical container in the case of small bond number

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有损压缩JPEG在载频条纹图分析中的应用研究

探讨了基于JPEG的有损压缩方法在载频条纹图分析中的应用前景。简介了当今流行的JPEG有损压缩技术和傅里叶变换轮廓术。使用专业软件对傅里叶变换轮廓术中拍摄的载频条纹图进行各种压缩比的压缩,解压后再解调出相位,与未经压缩的原图解调出的相位进行比较。将其相位误差与相位移法解调出的相位误差进行了对比,指出相对于相位移法而言,傅里叶变换轮廓术具有滤波的作用,对其拍摄的载频条纹图,应用JPEG压缩算法是可能的,解调出来的相位误差更小。     

进化神经网络在激光熔覆成形中的应用研究

在激光熔覆成形金属制件工艺中,熔覆层稀释率大小对成形制件的性能以及后续工序的处理有至关重要的影响。设计了基于进化神经网络的学习算法,建立了熔覆层稀释率随工艺参数变化的预测模型,该模型结合了基因遗传算法的全局搜索能力和BP神经网络良好的局部性质。实验和模拟结果表明,基于进化计算的神经网络不仅可以克服单纯使用BP神经网络易陷入局部极小值等问题,而且预测精度较高,具有一定的实用价值。     

Spherical functions and invariant differential operators on complex Grassmann manifolds

Proofs are given of two theorems of Berezin and Karpelevič, which as far as we know never have been proved correctly. By using eigenfunctions of the Laplace-Beltrami operator it is shown that the spherical functions on a complex Grassmann manifold are given by a determinant of certain hypergeometric functions. By application of this result, it is proved that a certain system of operators, fow which explicit expressions are given, generates the algebra of radial parts of invariant differential operators.     

A modeling concept of a mechanical system having a piecewise linear spring property for its diagnosis

Machine condition monitoring and fault diagnosis of rotating machinery are very important because of the wide use of rotating machinery in industry. Couplings and gears are used in many mechanical systems to connect elements and transmit power. The system is usually modeled as a single-degree-of-freedom system with a piecewise linear spring property, where the mass of main machine is only considered. In the present study, the dynamic behavior of a system with an unsymmetrical nonlinearity and a significant mass of the connecting part was investigated both experimentally and by numerical simulation. In the experiment, a 1/3 sub-harmonic oscillation was observed, but this oscillation was not found in the simulation using a single-degree-of-freedom system, in which the mass of the connecting part was ignored. However, when a two-degrees-of-freedom system was used that considered both the mass of the connecting part and the impact property, the 1/3 sub-harmonic oscillation was observed. Thus it is recognized that an adequate mathematical model for diagnosis in the early stage of abnormality must be selected on the basis of the mass ratio between the connecting part and the main body.     

基于C语言函数参数传递规律的探讨

函数是C语言的基本单位,函数的参数传递采用单向的值传递方式。当指针作为函数参数时,进行的是地址传递,地址传递依然是单向的值传递方式,并不是双向的传递方式。使用局部变量的有关知识,用图示法分析探讨函数的各种参数传递形式,通过探讨,总结了函数的参数传递规律。图示分析方法是一种全新的分析工具,有一定的推广价值。     

基于效用的备品备件优化库存控制法

 在(s,Q) 的故障替换概率分布模型基础上,提出了基于最小补充周期效用的优化补充周期定义算法和基于最小订货周期效用的优化订购周期定义算法,在保持了(s,Q)机制强调费用节省和可用性优点的同时,克服了它对资金积压、技术折旧损失和缺货损失、冗余库存维护损失缺乏调控能力的缺点.仿真结果很好验证了本机制的优点.