全文获取类型
收费全文 | 16243篇 |
免费 | 3507篇 |
国内免费 | 1597篇 |
专业分类
化学 | 2705篇 |
晶体学 | 172篇 |
力学 | 1388篇 |
综合类 | 155篇 |
数学 | 2154篇 |
物理学 | 9567篇 |
无线电 | 5206篇 |
出版年
2024年 | 32篇 |
2023年 | 190篇 |
2022年 | 332篇 |
2021年 | 412篇 |
2020年 | 521篇 |
2019年 | 414篇 |
2018年 | 393篇 |
2017年 | 579篇 |
2016年 | 649篇 |
2015年 | 650篇 |
2014年 | 1022篇 |
2013年 | 1144篇 |
2012年 | 1108篇 |
2011年 | 1155篇 |
2010年 | 1037篇 |
2009年 | 1074篇 |
2008年 | 1092篇 |
2007年 | 1060篇 |
2006年 | 1054篇 |
2005年 | 900篇 |
2004年 | 943篇 |
2003年 | 814篇 |
2002年 | 697篇 |
2001年 | 584篇 |
2000年 | 552篇 |
1999年 | 454篇 |
1998年 | 415篇 |
1997年 | 330篇 |
1996年 | 292篇 |
1995年 | 215篇 |
1994年 | 213篇 |
1993年 | 158篇 |
1992年 | 135篇 |
1991年 | 115篇 |
1990年 | 111篇 |
1989年 | 106篇 |
1988年 | 76篇 |
1987年 | 48篇 |
1986年 | 56篇 |
1985年 | 41篇 |
1984年 | 29篇 |
1983年 | 13篇 |
1982年 | 25篇 |
1981年 | 22篇 |
1980年 | 17篇 |
1979年 | 14篇 |
1978年 | 14篇 |
1977年 | 8篇 |
1976年 | 7篇 |
1975年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
261.
在机动车磁卡收费系统中,红外车辆分离子系统是一种重要设备,它是由平行等距红外线族构成的平面检测系统,其性能直接影响收费系统的正常运转。本文介绍该子系统的设计并对系统性能进行分析,得出:子系统采取相关检测技术后,不仅能有效地抑制外界干扰、噪声,还具有抗相邻红外信号干扰能力。 相似文献
262.
Adolfo M. Nemirovsky Maurício D. Coutinho-Filho 《Journal of statistical physics》1988,53(5-6):1139-1153
A field-theoretic representation is presented to count the number of configurations of a single self-avoiding walk on a hypercubic lattice ind dimensions with periodic boundary conditions. We evaluate the connectivity constant as a function of the fractionf of sites occupied by the polymer chain. The meanfield approximation is exact in the limit of infinite dimensions, and corrections to it in powers ofd
–1 can be systematically evaluated. The connectivity constant and the site entropy calculated throughout second order compare well with known results in two and three dimensions. We also find that the entropy per site develops a maximum atf1–(2d)–1. Ford=2 (d=3), this maximum occurs atf~0.80 (f~0.86) and its value is about 50% (30%) higher than the entropy per site of a Hamiltonian walk (f=1). 相似文献
263.
Mária Hvastijová Jiří Kohout Helmut Köhler 《Monatshefte für Chemie / Chemical Monthly》1992,123(6-7):493-500
Summary New dicyanamide complexes of the typeM[N(CN)2]2
L
2 (M=Cu or Ni;L=2-, 3-, 4-aminopyridine, 2-amino-5-nitropyridine) and Co[N(CN)2]2 (2-amino-5-nitropyridine)2 were prepared and studied by spectroscopic methods as well as by room-temperature magnetic moments. The results show that the Cu(II) complexes have elongated pseudooctahedral structures while the Ni(II) and Co(II) complexes are octahedral. In most cases the N(CN)2 groups are in bridging function and through their cyanide nitrogens, or-more rarely-amide and cyanide nitrogens connect the basic structure units into polymeric conglomerates. In the Cu(II) systems exchange coupling is seen from the eff value or ESR spectrum.
Professor Viktor Gutmann zum 70. Geburtstag gewidmet 相似文献
264.
An intrinsic principle of least action is presented for the intrinsic dynamism of chemical reactions. Then, as the stationary trajectory, a meta-IRC (intrinsic reaction coordinate) draws a geodesic curve in a rigged Riemannian space. This establishes a geodesic law for the intrinsic dynamism. Moreover, a diagrammatic perturbation theory is formulated for the intrinsic dynamism, and a dynamical interaction between a chemically reacting system and a background system is investigated. Then, the structural stability of the system is discussed using a new concept of the dynamical potential field. An example is given in order to elucidate the present theory.Dedicated to Prof. Hermann Hartmann on the occasion of his 65th birthday. 相似文献
265.
几种改进的CoMFA方法比较研究血小板活化因子拮抗剂 总被引:6,自引:1,他引:6
由于传统的比较分子场分析(CoMFA)方法本身存在一些缺陷,使得分子的叠合 规则以及叠合分子的空间取向和空间位置等因素对q~2的影响很大,因此相继提出 了几种改进的CoMFA方法。为了优化CoMFA结果,应用传统的CoMFA方法和交叉验证 的R~2引导的区域选择法(q~2-GRS)、全取向搜索法(AOS)、全空间搜索法(APS) 以及比较分子相似性指数(CoMSIA)等四种改进的CoMFA方法,对18个pinusolide类 衍生物这类新发现的血小板活化因子(PAF)拮抗剂进行了比较研究。结果表明四 种改进的CoMFA方法得到的q~2值均比传统CoMFA的高。q~2-GRS方法得到的q~2值有 所提高,但综合结果并不理想,AOS与APS得到的q~2较为理想,而在CoMSIA中, q~2几乎不受空间取向或空间位置的影响。同时我们引人基于样本的偏最小二乘法 (SAMPLS)取代原AOS/APS程序中的传统PLS进行统计分析,明显提高了其运行速 度。最后,根据q~2最高的CoMFA模型和CoMSIA模型设计了几个预测活性更高的 pinusolide类似物。 相似文献
266.
The vibrational wavenumbers and the fundamental modes of 2,2′-biquinoline were obtained by density functional theory (DFT) with the B3LYP functional using the 6-31G(d,p) basis set. The calculated wavenumbers were scaled by a single factor of 0.965 to correct them for vibrational anharmonicity, but the force constants were overestimated. Normal coordinate analysis of the molecule was also carried out by using the force field of the quinoline molecule and the force field parameters of quinoline are shown to be transferable to 2,2′-biquinoline. The potential energy distribution associated with the normal modes is also given. The theoretical wavenumbers are found to be in good agreement with the experimental data. 相似文献
267.
A. V. Larin D. N. Trubnikov D. P. Vercauteren 《International journal of quantum chemistry》2003,92(1):71-84
Three hydrated aluminosilicate frameworks—LiABW, NaNAT, and BaEDI—are partly optimized with the periodic Hartree–Fock CRYSTAL95 code. In particular, we optimized the positions of the adsorbed water molecules including the positions of the framework cations (ABW, NAT) or part of the framework atomic positions (ABW). This allowed us to compare cation–water clusters in the gas and adsorbed states and discuss the influence of hydrogen bonding to the framework oxygen atoms or to the neighbor water molecules on the atomic properties (quadrupole coupling constant, anisotropy of electric field gradient) of the adsorbed water molecules. The LiBIK structure obtained from X‐ray diffraction is also considered to illustrate the hydrogen bonds occurring between adsorbed water molecules. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem, 2003 相似文献
268.
269.
G. R. Kosmambetova P. E. Strizhak É. M. Moroz T. E. Konstantinova A. V. Gural’skii V. P. Kol’ko V. I. Gritsenko I. A. Danilenko O. A. Gorban 《Theoretical and Experimental Chemistry》2007,43(2):102-107
The morphological and catalytic properties of samples of nanomeric zirconium dioxide, stabilized with yttrium oxide, manufactured
via the effect of a UHF field during the process of drying precipitated zirconium hydroxide and calcination at temperatures
from 300 to 1000 °C, were studied. It was shown that the highest activity in the oxidation of CO occurred with 40 nm particles
of zirconium dioxide prepared at 1000 °C.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 2, pp. 96–101, March–April, 2007. 相似文献
270.