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11.
计算机模拟仿真射频磁控溅射实验制备薄膜及离于电池电极,研究了在特定实验条件下薄膜的生长过程,并分析了影响薄膜生长的部分因素。 相似文献
12.
Materials from the Mn(0.5−x)CaxTi2(PO4)3 (0≤x≤0.50) solid solution were obtained by solid-state reaction in air at 1000 °C. Selected compositions were investigated by powder X-ray diffraction analysis, 31P nuclear magnetic resonance (NMR) spectroscopy and electrochemical lithium intercalation. The structure of all samples determined by Rietveld analysis is of the Nasicon type with the R
space group. Mn2+/Ca2+ ions occupy only the M1 sites in the Ti2(PO4)3 framework. The divalent cations are ordered in one of two M1 sites, except for the Mn0.50Ti2(PO4)3 phase, where a small departure from the ideal order is observed by XRD and 31P MAS NMR. The electrochemical behaviour of Mn0.50Ti2(PO4)3 and Mn(0.5−x)CaxTi2(PO4)3 phases was characterised in Li cells. Two Li ions can be inserted without altering the Ti2(PO4)3 framework. In the 0≤y≤2 range, the OCV curves of Li//LiyMn0.50Ti2(PO4)3 cells show two main potential plateaus at 2.90 and 2.50–2.30 V. Comparison between the OCV curves of Li//Li(1+y)Ti2(PO4)3 and Li//LiyMn0.50Ti2(PO4)3 shows that the intercalation occurs first in the unoccupied M1 site of Mn0.50Ti2(PO4)3 at 2.90 V and then, for compositions y>0.50, at the M2 site (2.50–2.30 V voltage range). The effect of calcium substitution in Mn0.50Ti2(PO4)3 on the lithium intercalation is also discussed from a structural and kinetic viewpoint. In all systems, the lithium intercalation is associated with a redistribution of the divalent cation over all M1 sites. In the case of Mn0.50Ti2(PO4)3, the stability of Mn2+ either in an octahedral or tetrahedral environment facilitates cationic migration. 相似文献
13.
通信用VRLA蓄电池可靠性指标及计算探讨 总被引:1,自引:0,他引:1
在说明通信局(站)电源系统对VRLA蓄电池组可靠性要求的基础上,阐述了为了达到电信设备的电压、电流需求,通过串联或串并联构成电池组的单体VRLA蓄电池应达到的可靠性指标。在确定单体VRLA蓄电池应达到的可靠性指标。在确定单体VRLA蓄电池可靠性参数时,可通过现场使用调查或加速寿命试验的办法来求得。在单体VRLA蓄电池可靠性指标过低的情况下,可通过多种冗余连接方式来提高电池组的可靠性。 相似文献
14.
Reduced charge montmorillonites (RCM) were prepared by the thermal treatment of lithiumsaturated montmorillonite. Samples prepared by mild thermal treatment with lithium contained more water sorbed than the original montmorrilonite. When RCMs were prepared, part of the lithium cations reacted with hydroxyl groups in the octahedral sheet and released protons, which reacted with the structure. Acid treatment probably enhanced the surface area. which was reflected in the amount of water sorbed. Deprotonation of hydroxyl groups was proved by the measurements of the ignition loss. The heating of lithium saturated montmorillonite at higher temperatures brough about the collapse of the interlayers and a decrease in the amount of water sorbed. 相似文献
15.
常延勋 《电信工程技术与标准化》2002,(2):38-40
该针对阀控密封铅酸蓄电池的特性和使用环境,较全面的论述了接入网点蓄电池的选型要求与维护方式。 相似文献
16.
本文首先扼要介绍锂离子电池保护电路的功能,然后分别介绍过充电保护,过放电保护,过电流保护,最后列举几种保护性半导体IC的性能及应用电路的结构。 相似文献
17.
18.
电解铜箔产业发展趋势 总被引:4,自引:0,他引:4
随着技术的进步,电解铜箔在厚度上迅速向薄、超薄方向发展,THE、RCC、CAC等特殊性能铜箔需求比例快速 增加,以锂离子电池为代表的新应用领域正在形成。 相似文献
19.
A. Deptuła T. Olczak W. Łada B. Sartowska A.G. Chmielewski C. Alvani P.L. Carconi A. Di Bartolomeo F. Pierdominici S. Casadio 《Journal of Sol-Gel Science and Technology》2003,26(1-3):207-212
Microspheres of Li2TiO3 were fabricated by a classical, inorganic sol-gel process from commercially available TiCl4. Elaborated process consists of the following main steps: (1) dissolving of TiCl4 in concentrated aqueous HCl and addition of LiOH; (2) formation of sol emulsion in 2-ethylhexanol-1 containing the surfactant SPAN-80 (EH); (3) gelation of emulsion drops by extraction of water with partially dehydrated EH; (4) impregnation of gel to Li:Ti molar ratio MR = 2; (5) thermal treatment at 1200°C in order to receive chloride free product. This temperature can be significantly lowered (to 750°C) by dechlorination starting solution TiCl4 by chemical treatment of the with nitric acid to form of nitrate-stabilized titania sols. Tritium release from sol-gel made Li2TiO3 microspheres were found very close to that observed for other traditional materials, however for the first sample process starts slightly earlier. 相似文献
20.