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81.
在加热妒内,由于高温及重力作用,板坯两端的悬臂将产生下桡变形。悬臂越长,下桡将越大,导致悬臂下桡部分与出口端墙相碰,影响出料而造成事故。本文对加热炉内板坯的下桡变形进行了分析计算。首先,建立了板坯的二维非稳态导热模型并用有限差分法计算了炉内板坯随时间的温度变化;然后建立了板坯悬臂粘塑性变形模型,用有限元法计算了高温条件下由重力引起的悬臂的下桡变形。由此理论模型计算出的板坯抽出温度与悬臂端下桡量与实测结果吻合良好,说明该理论模型及模型计算方法是正确的,可用于对装钢生产进行指导。 相似文献
82.
In this work, the melting behaviors of nonisothermally and isothermally melt‐crystallized poly(L ‐lactic acid) (PLLA) from the melt were investigated with differential scanning calorimetry (DSC) and temperature‐modulated differential scanning calorimetry (TMDSC). The isothermal melt crystallizations of PLLA at a temperature in the range of 100–110 °C for 120 min or at 110 °C for a time in the range of 10–180 min appeared to exhibit double melting peaks in the DSC heating curves of 10 °C/min. TMDSC analysis revealed that the melting–recrystallization mechanism dominated the formation of the double melting peaks in PLLA samples following melt crystallizations at 110 °C for a shorter time (≤30 min) or at a lower temperature (100, 103, or 105 °C) for 120 min, whereas the double lamellar thickness model dominated the formation of the double melting peaks in those PLLA samples crystallized at a higher temperature (108 or 110 °C) for 120 min or at 110 °C for a longer time (≥45 min). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 466–474, 2007 相似文献
83.
S. Mentus Dijana Jelić Veselinka Grudić 《Journal of Thermal Analysis and Calorimetry》2007,90(2):393-397
Thermal decomposition of lanthanum nitrate to lanthanum oxide was carried out by both temperature programmed heating (TPH)
and citrate-gel combustion. The temperature programmed heating was carried out under flow of oxidizing (air), neutral (nitrogen)
and reducing (25 vol.% hydrogen+argone mixture) gases, and the processes were controlled by simultaneous thermogravimetry
and differential thermal analysis. It was shown that hydrogen atmosphere helps to reduce temperatures of all decomposition
steps. The results of TPH were utilized to check the nature of residues in the products of lanthanum nitrate-to-oxide conversion
performed via citrate-gel combustion technique. 相似文献
84.
Govindarajan Sankar A. Sultan Nasar 《Journal of polymer science. Part A, Polymer chemistry》2007,45(8):1557-1570
A series of substituted N‐methylaniline‐blocked polyisocyanates based on 4,4′‐methylenebis(phenyl isocyanate) and poly(tetrahydrofuran) were prepared and characterized thoroughly with FTIR, 1H NMR, and 13C NMR spectroscopy methods. Compared with unsubstituted N‐methylaniline, a blocking agent with an electron‐releasing substituent at the para position took a shorter time, whereas those with an electron‐releasing substituent at the ortho position or an electron‐withdrawing substituent at the ortho and para positions took longer times for the blocking reaction. The thermal dissociation reactions of blocked polyisocyanates were carried out with an FTIR spectrophotometer attached to hot‐stage accessories under dynamic and isothermal conditions. The dynamic method was used to determine the deblocking temperature, and the isothermal method was used to calculate the deblocking kinetics and activation parameters. The cure times of blocked polyisocyanates with hydroxyl‐terminated polybutadiene were also determined. The deblocking temperatures, the results of cure‐time studies, and the kinetic parameters revealed that the thermal dissociation of the N‐methylaniline‐blocked polyisocyanates was retarded by electron‐donating substituents and facilitated by electron‐withdrawing substituents. The action of N‐methylanilines as blocking agents for isocyanate was explained by the formation of a four‐center, intramolecularly hydrogen‐bonded ring structure during the thermal dissociation of the blocked polyisocyanates. The formation of such a hydrogen‐bonded ring structure was confirmed and supported by variable‐temperature 1H NMR studies and entropy parameters, respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1557–1570, 2007 相似文献
85.
魏嵬 《数学的实践与认识》2007,37(16):76-83
为给转炉设计提供依据,需要计算炉液倾动的重心.利用数学方法将实际问题进行简化,通过分析炉液倾动过程中变量间的相互关系,来确定每个倾动角度对应情况下的液面位置.利用数学中三重积分的有关应用,进一步得出转炉在每个倾动角度为α∈(0,π2)时的重心计算方法及相关结论,在理论上为工程计算重心的方法提供参考. 相似文献
86.
《Magnetic resonance in chemistry : MRC》2003,41(9):660-670
Reduced forms of iso‐α‐acids (isohumulones), used in modern beer brewing were separated and characterized by 1H and 13C NMR spectroscopy. Components from mixtures of rho‐iso‐α‐acids, tetrahydro‐iso‐α‐acids, and hexahydro‐iso‐α‐acids were isolated using high‐performance liquid chromatography (HPLC) and analyzed by use of one‐ and two‐dimensional NMR experiments. The data presented assign the identities of the main peaks in the HPLC traces for the reduced iso‐α‐acids. Previous tentative assignments regarding the cis and trans configurations and the structures of the acyl residues of the reduced iso‐α‐acids were confirmed and extensive NMR assignments were made. Furthermore, the previously unknown stereochemistry in the C‐4 side‐chain of the rho‐ and hexahydro‐iso‐α‐acids was assigned. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
87.
本文介绍了宽低温STN-LCD加热装置的设计和制备方法,并对低温加热的实验结果进行了讨论和分析,相应的研究结果表明此法有利于拓宽STN液晶显示器的负温工作范围。 相似文献
88.
89.
本文描述了用膜吸收法测量激光等离子体辐射温度空间分布的原理和方法给出了柱形缝靶轴向辐射温度随空间位置变化的特征,对测量结果进行了分析讨论。 相似文献
90.
器件尺寸按比例缩小是实现超大规模集成电路的有效途径,但寄生和二级效应却将器件限在一定的水平,本文在对比分析常温与低温下小尺寸器件效应的基础上,重点研究了MOS器件亚阈特性对器件性能及按比例缩小的影响,并根据低温工作的特点,提出了MOS器件一种低温按比例缩小规则,该原则对低温器的优化设计,从而更大程度在提高电路与系统性能具有重要的指导意义。 相似文献