Optimization of a peroxyoxalate chemiluminescence detection system for the liquid chromatographic determination of fluorescent compounds

Summary A peroxyoxalate chemiluminescence detection system for liquid chromatography is described. The excitation of fluorophores is generated by the reaction of bis-(2,4,6-trichlorophenyl)oxalate or bis(2,4-dinitrophenyl)oxalate and hydrogen peroxide, which are added to the column effluent. The influence of the solvents and the concentrations of the reagents have been investigated. The influence of the flow cell volume on sensitivity and on band broadening have also been studied and a chemical band narrowing effect has been observed. Different types of apparatus have been compared for detection of the emitted light. The system has been used for the detection of the dansyl derivative of a drug with a secondary amine functional group in serum samples. The detection limits are in the 1–10pg range.     

NMR parameter contrast in abundant-spin images of solids

Solid state nuclear magnetic resonance imaging (NMRI) techniques have been steadily improving over the years. Today high-resolution images of rigid solids are now accomplished by many different means. For abundant nuclei, the combination of multiple-pulse line narrowing and pulsed field gradients have greatly improved both the resolution and sensitivity of the imaging experiment, but often at the expense of the chemical information in the material. In this paper we discuss means of incorporating NMR parameters in the imaging experiment to generate image contrast which provides information about local variations in the chemistry of the material.     

Line narrowing beyond natural linewidth in radiation matter interaction

A review of the various linear and nonlinear methods used to obtain resolution beyond natural linewidth is given. Based on the lecture given at the International Symposium on Theoretical Physics, Bangalore, November 1984.     

Temperature dependence of the linewidth of the first-order Raman spectra for MnF2 crystal

The first-order Raman spectra ofE _gandA _1g modes in MnF₂ crystal were measured at temperatures from 4.2 to 563 K, and the values of the linewidths obtained. The temperature dependence of the linewidths was analyzed by the phonon dispersion curves based on the rigid ion model, and the result showed that it was caused approximately by the cubic anharmonic term in crystal potential energy.     

在时域实验研究扩散诱导的Ramsey压窄

基于Duan-Lukin-Cirac-Zoller(DLCZ)方案,在时域上研究了扩散诱导的Ramsey压窄.以87Rb热原子系综为研究对象,观测到缓冲气体,激光束尺寸和镀石蜡Rb池均可以导致Ramsey压窄现象.实验结果和文献中重复相互作用模型预期的一致.     

Photo- and electroluminescence of nitrogen isoelectronic traps in GaAs1–xPx

The variation with temperature of the charge on the surface of NaCl single crystals has been measured directly by means of vibrating capacitor probe. The charge is negative at room temperature, in agreement with theory based on values of the free energy of vacancy formation, decreases with increase of temperature in two stages to a zero value at the isoelectric temperature, and then becomes positive. Values of isoelectric temperature obtained on surfaces are consistent with those obtained by experiments on charged dislocations, which suggests that surfaces could be used to obtain accurate values of the free energy of formation of cation and anion vacancies.     

Linewidth of electromagnetically induced transparency under motional averaging in a coated vapor cell

The linewidth of electromagnetically induced transparency(EIT) in a coated Rb vapor cell was studied under a magnetic field gradient.The nonlinear broadening of the EIT linewidth with the magnetic field gradient was observed.It was found that the motional averaging of the field gradient was more pronounced at higher laser intensities and larger beam sizes.In the same regime,there was a small linewidth decrease with the increasing magnetic field gradient.We have established a Monte-Carlo model,which gave results in good qualitative agreement with our experiment.Physics pictures for the above phenomena were also suggested.These results provide an understanding of the EIT linewidth behavior under motional averaging,and should be useful for applications in quantum optics and metrology based on coated vapor cells.     

考虑自热效应的重掺杂AlGaAs/GaAs HBT电流特性分析

重掺杂使导带、价带带边同时发生了收缩,从而产生能带变窄效应(BGN)。对于因重掺杂NPN突变A1GaAs／GaAs HBT,而引起BGN导带和价带突变界面势垒形状及高度都发生改变结果,以致对电流输出特性产生重要的影响。本文基于Jain—Roulston禁带收缩模型及热场发射——扩散载流子输运机制,对考虑自热效应下的重掺杂AlGaAs／GaAs HBT电流特性进行了深入的研究。通过与其它计算程序常用的几种BGN模型比较得出：为了更好描述电流传输,利用Jain—Roulston的BGN模型,考虑导带、价带突变量的改变依赖于实际掺杂浓度值是必要的。     

半导体激光器参量估计的改进算法

为了精确估计带外腔半导体激光器的线宽展宽因数,采用了光反馈自混合技术和梯度最优算法,可以达到数据-理论的最佳拟合,同时提出了改进的梯度迭代公式,并在参量迭代时引入可变步长,取得了仿真和实验数据.该算法不仅测量精度较高,而且抗噪声性能较好.仿真结果表明,当信噪比大于20dB时,线宽展宽因数的相对标准差小于2.55%.实验数据处理结果表明,线宽展宽因数的相对标准差小于5.1%,对半导体激光器的应用是有帮助的.     

一种窄线宽的高重复频率窄脉宽主动调Q光纤激光器

提出并演示了一种基于声光调制器(AOM)主动调Q的环形腔双包层光纤激光器获得窄线宽、窄脉宽和高重复频率激光脉冲的方法。通过在腔内采用以双包层增益光纤作为输入尾纤的泵浦剥离器来缩短腔长,可以降低增益光纤正向放大自发辐射(ASE)的反射,抑制其ASE的增益自饱和效应,使腔内有效增益增大,窄线宽调Q脉冲可在环形腔中快速建立,从而不仅可使调Q脉冲脉宽变窄,还允许其重复频率大幅提升。在7 W泵浦功率下,所提出的调Q光纤激光器获得了线宽和脉宽分别窄至0.16 nm和10.4 ns、重复频率高达150 kHz的调Q激光脉冲。