Anisotropic ESR parameters of Cu(II) complexes in solutions and dynamics of solvent coordination: use of “minimum linewidths”

The “minimum linewidths” seen in the ESR linewidths against temperature plots, the dependence of line widths on the⁶³Cu nuclear magnetic quantum numbers and the Hubbard relation provide sufficient number of equations to determine the anisotropic ESR parameters in the case of axially symmetric Cu(II) complexes even when unresolved hyperfine structures make contributions to linewidths. After testing the method by reanalysing the literature data on Cu(II) bis-acetylacetonate, it has been used to obtain the anisotropic ESR parameters in the case of bis-salicylaldehydate of Cu(II). Linewidth contributions from unresolved hyperfine structures associated with the¹H of coordinating CHCl₃ inferred in these studies, were confirmed by comparing the widths in CHCl₃ and CDCl₃ under ideal conditions. The temperature dependence of this contribution and the estimate of rate constant at room temperature (∼ 10¹⁰ s⁻¹) suggest that the coordinating solvent exchange is diffusion controlled.     

Experimental Study on One-mirror-inclined Three-mirror-cavity Photodetectors

Research on the one-mirror-inclined three-mirror-cavity (OMITMiC) photodetectors in the laboratory is reported. In the structure of photodetectors, it is the inclined-mirror that makes the filtering cavity and the absorption cavity decoupled, thus narrow spectral response linewidth, wavelength-tunable and high quantum efficiency can be achieved simultaneously. On the basis of the theoretical analysis and experimental verification on the principle with separated optical components, the vertical taper structure, the key part in the whole integrated device was realized, by dynamic etch mask technique. Moreover, the first integrated device of this type was fabricated. A spectral linewidth less than 6 nm and a quantum efficiency of 52.6% have been achieved experimentally.     

双模激光线宽及其时谱的实验观测

本根据双模激光时间相干度ｇ（ｔ）与激光线宽△ｕｐ的关系提出了一种观测激光宽及其时谱的简单方法－ｇ（ｔ）时谱法，章以双模Ｈｅ－Ｎｅ激光器为例，介绍了本方法的测量原理，给出了相应的实验结果，得到了双模Ｈｅ－Ｎｅ激光线宽△ｕｐ随开机时间变化的时谱曲线。     

光谱线宽对可调谐激光调制吸收光谱技术测量CO2浓度的影响

在利用可调谐激光调制吸收光谱技术进行测量时,气体参量改变将导致线宽变化,从而影响二次谐波信号峰值的大小.针对于Lorentz线型,给出了线宽变化对二次谐波峰值影响的理论分析及利用二次谐波信号峰谷比值进行修正的方法.在10 cm的吸收池内利用1578.22 nm处的吸收谱线对CO2进行了测晕,在不同调制幅度下验证了不同工况中线宽对二次谐波信号的影响.结果表明,利用二次谐波峰谷比值确定调制系数进行修正可有效地减小由于工况改变时线宽变化对测量带来的影响,当压力由1.0×105Pa变化至1.5×105Pa时,修正前后的测量相对误差分别为34.3%与1.8%;当气体体积分数在20%～100%变化时,修正前后的平均误差分别为12.8%与1.8%.     

用于拍瓦级激光系统的三维光参量啁啾脉冲放大的数值模拟

建立了光参量啁啾脉冲传输放大(OPCPA)的物理模型,采用分步傅里叶算法编写了三维OPA+CPA数值模拟程序,利用该程序可以研究OPCPA系统中的能量放大、增益窄化、自相位调制、空间自聚焦以及脉冲的时间信噪比等问题,对OPCPA系统进行优化设计。利用该程序对神光II第九路拍瓦升级系统(SG-II-U-PW)进行了数值模拟研究,计算结果表明,第九路光路无需作太大改动即可满足拍瓦升级指标,并提出了第九路主放大链的两种运行方案。三维OPA+CPA模拟程序经过简单修改后也可以对飞秒(fs)OPCPA系统、以及未来峰值功率为exawatt级(1018W)的激光系统进行优化设计。     

啁啾脉冲激光放大器输出光束时间特性的理论和数值模拟

利用分布傅里叶变换对描述啁啾脉冲放大的非线性薛定谔方程进行求解 ,研究了在钕玻璃和钛宝石这两种增益介质中 ,自相位调制、增益变窄和增益饱和这三种非线性效应对放大啁啾脉冲输出特性的影响 ,具体给出了在不同放大介质中 ,它们对放大脉冲的影响程度和影响结果。重点阐明了自相位调制对放大啁啾脉冲的影响 ,及其与另外两种非线性效应的内在联系     

扬氏光纤干涉仪测量激光谱线线宽

本文介绍了一个用二根单模光纤组成的扬氏干涉仪来测量连续或脉冲激光谱线宽度的方法,实测了几种激光的线宽及铜蒸气激光在一个脉冲时间内光谱线宽的时间过程。     

Investigation of ferromagnetic resonance and damping properties of CoFeB

In this study, the influences of thin film thickness and post-annealing process on the magnetic properties of CoFeB thin films were investigated. The angular dependency and linewidth of the ferromagnetic resonance signal were used to explore the magnetic behavior of sputtered single-layer and trilayer thin film stacks of CoFeB. A micromagnetic simulation model was employed based on the metropolis algorithm comprising the demagnetizing field and in-plane induced uniaxial anisotropy terms with all relevant contributions. Our results reveal that the direction of magnetization changes from in-plane to out-of-plane as a result of the annealing process and induces a perpendicular magnetic anisotropy in the 1-nm thick CoFeB thin film. The ferromagnetic resonance (FMR) linewidth can be defined well by the intrinsic Gilbert damping effect and the magnetic inhomogeneity contribution in both as-grown and annealed samples. The difference between the linewidths of the single and trilayer film is mainly caused by the spin pumping effect on damping which is associated with the interface layers.     

光纤光栅外腔半导体激光器的线宽特性研究

通过构建外腔半导体激光器的等效腔模型,并在修正的肖洛-汤斯线宽公式中引入外腔压窄因子,系统模拟了光纤光栅外腔半导体激光器的电流阈值特性和线宽特性.以等效腔模型为基础,综合考虑外腔压窄因子,利用修正后的肖恩-汤斯公式,使用Matlab对外腔激光器的阈值和线宽特性进行了系统的模拟.模拟结果表明:通过增加外腔反射率,可有效增加光子寿命并降低阈值载流子浓度,进而获得较低的阈值电流,对于0.81的外腔等效反射率,阈值电流低至3.83 mA;通过增加外腔反射率、耦合效率和外腔长度,可显著压窄线宽至千赫兹量级;此外,合理限制增益芯片尺寸也会压窄线宽.激光器工作电流为60 mA时,当外腔光栅反射率由0.1提高至0.9可使阈值电流由9.04 mA降低至4.01 mA,线宽由95.27 kHz降低至1.34 kHz;当外腔长度由2 cm增加至6 cm时,激光器线宽由3.20 kHz降低至0.36 kHz.     

Esr-spectrum of amorphous silicon

The ESR-linewidth of a-Si consists of a temperature-independent part ΔH_pp(O) and a temperature-dependent contribution 5Hpp(T), the latter being closely related to the hopping conductivity. δH_pp(O) is to a large part determined by a g-value spectrum as can be concluded from measurements at different magnetic fields H_o. Additionally in some cases exchange interaction is involved. Annealing of glow-discharge a-Si and the influence of hydrogen effusion on the ESR-spectrum is investigated. In the case of boron-doped a-Si a new line with g = 2.0038 can be resolved which is ascribed to a center with a dangling bond on a silicon atom with one Si-H bond.