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41.
42.
Dheeraj K. SinghSunil K. Srivastava Prachi RaghuvanshRanjan K. Singh B.P. Asthana 《Vibrational Spectroscopy》2011,56(1):34-41
The Raman spectra of neat (C2H5)2CO (pentanone) and its binary mixtures with hydrogen donor solvent (CH3OH), [(C2H5)2CO + CH3OH] having different mole fractions of the reference system, (C2H5)2CO in the range 0.1-0.9 at a regular interval of 0.1 were recorded in the CO stretching region. In neat liquid, the Raman peak appears asymmetric. The asymmetric nature of the peak has been attributed to the CO stretching mode of the two conformers of (C2H5)2CO having C2 and C2v point groups and the corresponding bands at ∼1711 and ∼1718 cm−1, respectively. A careful analysis of the Iiso (isotropic component of the Raman scattered intensity) at different concentrations reveals that upon dilution with methanol, at mole fraction C = 0.6, an additional peak in the CO stretching region is observed at ∼1703 cm−1 which is attributed to the hydrogen bonding with methanol. A peculiar feature in this study is that upon dilution, the peak at ∼1718 cm−1 shows a minimum at C = 0.6, but on further dilution it shows a blue shift. However, the other peak at ∼1711 cm−1 shows a continuous red shift with dilution as well as a maximum at C = 0.7 in the linewidth vs. concentration plot, which is essentially due to competition between motional narrowing and diffusion phenomena. A significant amount of narrowing in the Raman band at ∼1718 cm−1 can be understood in terms of caging effect of the reference molecule by the solvent molecules at high dilution. A density functional theoretic (DFT) calculation on optimized geometries and vibrational frequencies of two conformers of neat (C2H5)2CO in C2 ad C2v forms and the complexes with one and two CH3OH molecules with both the conformers was performed. The experimental results and theoretical calculations together indicate a co-existence of two conformers as well as hydrogen bonded complex with methanol in the binary mixture, [(C2H5)2CO + CH3OH] at intermediate concentrations. 相似文献
43.
激光器调谐过程中的动态线宽是非常重要的参数, 然而, 当前各种测量方法得到的都是激光器稳定状态下的静态线宽. 本文提出一种对干涉拍信号进行基于局部均值分解的时频分析进而获取激光动态线宽的方法, 通过仿真信号验证了这种时频分析方法提取瞬时相位噪声的有效性; 构建实验系统, 利用10cm路径差产生约0.5ns的超短时延, 提取相位噪声的时频分布, 首次得到了分布反馈半导体激光器在脉冲工作模式下的动态线宽.
关键词:
超短时延
动态线宽
局部均值分解
时频分布 相似文献
44.
在Ar+O22气氛中,采用射频反应溅射Cd-In靶制备CdIn22O44 薄膜.制得的薄膜经x射线衍射(XRD)检测为CdIn22O44和CdO相组成的多晶.从理论上分析了热 处理前后氧空位、掺杂点缺陷和富氧电子陷阱在影响膜的载流子浓度和电子散射中所起的重要作用.同时,对样品 进行Hall效应、Seebeck效应测试并得出不同载流子浓度下的迁移率、有效质量、弛豫时间以及它们之间的相互关系,特别强调 相似文献
45.
K. Sasaki O. Takahashi N. Takada M. Nagatsu T. Tsukishima T. Okada S. Okajima Y. Tsunawaki S. Sudo K. N. Sato et al. 《International Journal of Infrared and Millimeter Waves》1995,16(12):2133-2146
Spectrally narrow, pulsed outputs consisting of almost a single mode have been obtained from an optically-pumped high-power (200kW) D2O laser by adopting the injection seeding method, where single-mode radiation (seed pulse) from a low-power, compact D2O laser has been injected into the main D2O laser. Spectrally narrow outputs with high power having spectral widths as narrow as 5 MHz have been obtained, when the seed pulses with frequency tuned to one longitudinal mode of the main D2O laser have been injected at a time sufficiently before the lasing of the main laser took place. The experimental results have been compared with those of numerical simulation modified to include the injection field with varying injection times. 相似文献
46.
介绍了利用双光栅外腔结构对650 nm半导体激光器输出激光进行选模、线宽压窄及波长调谐的 研究。获得了最窄线宽<0.01 nm的单纵模激光输出,实现了波长调谐范围约8.4 nm。 相似文献
47.
48.
M. Maghrebi Melliti R. Chtourou J. Block V. Thierry-Mieg 《Physica E: Low-dimensional Systems and Nanostructures》2005,30(1-2):17-20
Polariton linewidths have been measured in a series of microcavities with different excitonic and cavity inhomogeneous broadening in the weak-disorder regime. We show experimentally that the behaviour of the polariton linewidths as a function of the detuning depends on the asymmetric line shape of an inhomogeneously broadened exciton line and particularly the disorder effect can be modulated and cancelled around resonance. When the disorder contribution is minimal, the behaviour of the cavity polariton linewidths tends to one of the homogeneous broadening system. 相似文献
49.
G. J. de Jong N. Lammers F. J. Spruit U. A. Th. Brinkman R. W. Frei 《Chromatographia》1984,18(3):129-133
Summary A peroxyoxalate chemiluminescence detection system for liquid chromatography is described. The excitation of fluorophores is generated by the reaction of bis-(2,4,6-trichlorophenyl)oxalate or bis(2,4-dinitrophenyl)oxalate and hydrogen peroxide, which are added to the column effluent. The influence of the solvents and the concentrations of the reagents have been investigated. The influence of the flow cell volume on sensitivity and on band broadening have also been studied and a chemical band narrowing effect has been observed. Different types of apparatus have been compared for detection of the emitted light. The system has been used for the detection of the dansyl derivative of a drug with a secondary amine functional group in serum samples. The detection limits are in the 1–10pg range. 相似文献
50.
Solid state nuclear magnetic resonance imaging (NMRI) techniques have been steadily improving over the years. Today high-resolution images of rigid solids are now accomplished by many different means. For abundant nuclei, the combination of multiple-pulse line narrowing and pulsed field gradients have greatly improved both the resolution and sensitivity of the imaging experiment, but often at the expense of the chemical information in the material. In this paper we discuss means of incorporating NMR parameters in the imaging experiment to generate image contrast which provides information about local variations in the chemistry of the material. 相似文献