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31.
32.
T. Rietmann S. Sohn M. Schröder D. Lipinsky H.F. Arlinghaus 《Applied Surface Science》2006,252(19):6640-6643
In order to improve quantification of high mass ions, the influence of cluster composition on detection efficiencies has been studied using a TOF-SIMS IV with the extended capability of postaccelerating ions up to 20 keV. In this experimental study, we focus on the comparison of detection efficiencies for three types of negatively charged secondary cluster ions: gold-alkanethiolate-clusters (AuxMy), gold-sulfur-clusters (AuxSy) and gold-clusters (Aux). The clusters were sputtered from self-assembled monolayers of hexadecanethiols on gold substrates using 10 keV Ar+ primary ions. The detection efficiencies were derived on the basis of a function for the secondary electron yield and a fourth-order approximated Poisson probability distribution for electron propagation and amplification within the microchannel plate.In addition to the well-known dependence of detection efficiencies on ion mass and energy, which has already been studied for positively charged ions, we were able to show a similar behaviour for the investigated negatively charged secondary ions. We have observed major variations among the three types of clusters at similar mass and energy as predicted in a theoretical approach. The observed differences are due to the different composition of the investigated clusters which has a major influence on the kinetic ion induced electron emission within the microchannel plate. For the first time it was possible to experimentally verify these predictions for detection efficiencies. 相似文献
33.
The stress-strain state of multilayered plates on an undeformable foundation is investigated. The design diagram of a transversely
loaded plate is formed by supplementing it with a symmetric one about the contact surface of the foundation. The double-thickness
plate obtained becomes loaded bilaterally and symmetrically about its midsurface. In such a way, only unflexural deformations
can be modeled, which reduces the number of unknowns and the general order of differentiation of the resolving system of equations.
The refined continual model developed takes into account the deformations of transverse shear and transverse compression in
high iterative approximations. The cases of a rigid contact between the foundation and the plate and frictionless slip of
the plate over the foundation are considered. Calculations confirm the efficiency of such an approach, which allows one to
obtain solutions qualitatively and quantitatively close to three-dimensional ones.
__________
Translated from Mekhanika Kompozitnykh Materialov, Vol. 42, No. 5, pp. 643–654, September–October, 2006. 相似文献
34.
35.
Jean-Marie Lehn 《Journal of Chemical Sciences》1994,106(5):915-922
The article discusses molecular recognition and overviews the key concepts -storage and retrieval of chemical information
by molecular structures, supramolecular reagents and catalysts, molecular transport, semiochemistry and self assembly. The
prospects of controlling supramolecular architecture through engineered molecular recognition and design of ‘programmed systems’
controlled by molecular information are also discussed. 相似文献
36.
提出了一种相似度的新定义,使双极WAT模型的实现更加简洁明了。增加一个阈值使系统能判别非存储模式或因其信息量过低而无法鉴定的输入模式,阈值的大小与要求的容错能力有关。双极相似度及阈值通过光学方法实现。阈值的光学实现使系统仍具有照明不变性。通过电路实现取及WTA网络的迭代运算。 相似文献
37.
在非AWGN环境下,针对CW,AM,FM,OOK,PSK,QPSK,16QAM,FSK,MSK,SSB十种混合调制信号,对调制类型特征提取方法和自动识别算法进行了分析、综合、设计和计算机仿真。提出了梯层电平分析方法、频率瞬时信号分析、剔除载波的归一化能量分析、平方后信号的频谱分析、四次方后的信号频谱分析等方法。当SNR=10dB时,计算机仿真结果是正确识别率不低于95%,自动识别的平均处理时间为不超过10s。 相似文献
38.
The self-organizing map (a neural network) was applied to the spectral pattern recognition of voice quality in 34 subjects: 15 patients operated on because of insufficient glottal closure and 19 subjects not treated for voice disorders. The voice samples, segments of sustained /a/, were perceptually rated by six experts. A self-organized acoustic feature map was first computed from tokens of /a/ and then used for the analysis of the samples. The locations of the samples on the map were determined and the distances from a normal reference were compared with the perceptual ratings. The map locations corresponded to the degree of audible disorder: the samples judged as normal were overlapping or close to the normal reference, whereas the samples judged as dysphonie were located further away from it. The comparison of pre- and postoperative samples of the patients showed that the perceived improvement of voice quality was also detected by the map. 相似文献
39.
基于宽带毫米波工作体制的雷达目标识别方法探讨 总被引:1,自引:0,他引:1
对基于宽带毫米波工作体制的雷达目标特征获取和识别方法进行了综合分析和探讨.表明:在毫米波照射下,雷达目标可模型化为由多个散射中心组成的扩展目标;只要发射信号有足够的带宽,就可以从回波信号中获得各散射中心的空间分布、类型等特征;仿真结果说明,这种方法对高频区复杂目标的识别是有效的. 相似文献
40.