Statistical thermodynamics evaluation of polymer–polymer miscibility

The Simha and Somcynsky (S–S) statistical thermodynamics theory was used to compute the solubility parameters as a function of temperature and pressure [δ = δ(T, P)], for a series of polymer melts. The characteristic scaling parameters required for this task, P*, T*, and V*, were extracted from the pressure–temperature–volume (PVT) data. To determine the potential polymer–polymer miscibility, the dependence of δ versus T (at ambient pressure) was computed for 17 polymers. Close proximity of the δ versus T curves for four miscible polymer pairs: PPE/PS, PS/PVME, and PC/PMMA signaled the usefulness of this approach. It is noteworthy, that the tabulated solubility parameters (derived from the solution data under ambient conditions) propounded the immiscibility of the PVC/PVAc pair. The computed values of δ also suggested miscibility for polymer pairs of unknown miscibility, namely PPE/PVC, PPE/PVAc, and PET/PSF. In recognizing the limitations of the solubility parameter approach (the omission of several thermodynamic contributions), these preliminary results are auspicious because they indicate a new route for estimating the miscibility of any polymeric material at a given temperature and pressure. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2909–2915, 2004     

晶格失配对异质外延超薄膜生长中成核特性的影响

利用动力学蒙特卡罗方法模拟了异质外延超薄膜生长中的成核过程.研究了薄膜与衬底的晶格失配对超薄膜生长中成核密度、平均核尺寸、标度关系及生长模式的影响.结果发现产生压（张）应变的晶格负（正）失配使生长过程更早（迟）从成核区进入过渡区，失配越大，这一效应越明显.在相同的沉积条件下，负失配导致超薄膜形成较低的成核密度与较大的平均核尺寸，而正失配则相反.成核密度满足标度关系Ns≈(F/D)χ，随着失配度从-0.04增加到0.02，标度系数χ从0.37逐渐减小到0.33，对应超薄膜生长过程从包含二聚体扩散模式转变到无 关键词： 薄膜生长 成核 晶格失配 蒙特卡罗模拟     

介绍两种画中画插入播出器

介绍画中画插入播出器的工作原理及设计思想，并给出了实际的电原理图。     

自动线性跟踪Butterworth有源滤波器研究

滤波是通信、测试、数据采集和实时控制等领域至关重要的环节。通常的模拟滤波器，由于截止频率固定，在某些宽频率动态范围且有实时性要求的应用场合，往往达不到预期的滤波效果，有时甚至影响整个系统的正常运行。本文从有源滤波器的机理分析入手，提出了一种由单片机参与的滤波系统，它能自动跟踪输入信号频率，线性地选择合适的滤波器截止频率，弥补了原有滤波器的不足。     

负动量压缩因子的环形对撞机磁聚焦结构的研究

探讨了设计负动量压缩因子(α_p<0)的正负电子对撞机储存环磁聚焦结构的可行性及方法.作为应用实例,说明了设计α_p<0的τ–粲工厂磁聚焦结构的可能性.     

新型微波有源滤波器综合方法

本文给出了一种新颖的微波有源滤波器的拓扑结构及综合方法，并对有源滤波电路进行了计算机模拟，结果表明本文给出的微波有源滤波器电路具有优良的的窄带滤波特性，通带内正向增益大于１０ｄＢ，带外抑制大于３０ｄＢ。     

Ground-state complex formation of perylene with pyromellitic dianhydride studied by static fluorescence quenching

The association of complex formation with static quenching in CT systems was investigated. Evaluation of the data made evident that the inner filter effect must be allowed for. Time-resolved and temperature-dependent stationary measurements of fluorescence led to the separation of dynamic and static quenching components. The static quenching constant is discussed with respect to the equilibrium constant of complex formation determined by absorption spectroscopy.     

声表面波滤波器的匹配电路设计

介绍了通过测试仪器采集的声表面波（SAW）滤波器的Sij(i,j=1,2）参数来优化匹配电路的方法。首先将采集的Sij(i,j=1,2）参数转换为SAW滤波器Yij(i,j=1,2）参数，然后建立新的S12（或S21）参数与匹配电路的依赖关系，通过优化匹配电路元件值，而使滤波器的插入损耗和通带波动满足目标值，该方法的主要优点是考虑整个通带特性，而不是考虑通带内的某一点（如中心频率）。     

合成孔径雷达干扰技术的研究

合成孔径雷达（Synthetic Aperture Radar）是一种新型高辨力成像雷达。其在距离上利用发射的线性调频（LFM）的脉冲压缩信号来获取距离上的高分辨力，在方位上利用接收脉冲之间的多普勒信息获得方位上的高分辨力。本文在简单分析合成孔径雷达工作原理基础上，针对合成孔径雷达的特点与弱点，讨论了几种干扰样式。