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71.
Min-zhi Chen Xiao-liang Wang Fang-fang Tao Qi Xue Ping-chuan 《高分子科学》2007,(1):107-111
The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only provide indirectly the information of the degree of entanglement in a relatively large scale (several to tens of nanometer). In this article, we report ^1H-NMR spectroscopy with dipolar filters under fast magic angle spinning for probing chain interpenetration of polymer glasses at the molecular level. 相似文献
72.
Maria Ochsenkühn-Petropulu Petros Tarantilis John Tsarouchis Klaus Ochsenkühn George Parissakis 《Mikrochimica acta》1998,129(3-4):233-238
Large area coatings (>10cm2) of the high temperature superconductor YBa2Cu3O7–x (x = 0.1 – 0.2) (YBCO) have been prepared by scale up an electrophoretic deposition technique using silver sheets and Si-wafers coated with Ag or Au as substrates. Several parameters, like the kind of the solvent, the applied voltage, the distance between the electrodes, the initial concentration of the suspension and the temperature during the electrophoresis were investigated in order to attain high deposition rates, as well as uniform YBCO coatings with the proper stoichiometry. To obtain a strongly adherent and dense coating a subsequent appropriate sintering and annealing procedure has been developed. The coatings obtained were characterized for their stoichiometry and superconducting properties by X-ray diffraction (XRD), Raman spectroscopy and magnetic measurements. The homogeneity and thickness of the films and the average grain size of the deposited particles have been investigated by optical and scanning electron microscopy (SEM). 相似文献
73.
Masao Kato Takao Shiraga Tatsumi Kimura Takashi Fukuda Hiro Matsuda Hachiro Nakanishi 《先进技术聚合物》2002,13(2):120-126
We synthesized some novel rigid NLO‐active maleimide copolymers bearing DR‐1 moieties ( PMPD , PHSD and PHND ). All copolymers exhibited high Tg's (190~197 °C), good solubilities for common solvents and excellent film‐forming properties. Dependence of film thickness on the d33 value for the poled copolymer films induced by corona poling was investigated and it was demonstrated that in less than thickness of 0.3 µm decrease of the thickness gives rise to remarkable increase in the d33 value. The poled copolymer films exhibited large d33 values (270 × 10?9 esu (film thickness 0.13 µm) for PMPD , 290 × 10?9 esu (0.12 µm) for PHSD and 350 × 10?9 esu (0.08 µm) for PHND ) as well as large r33 values (51.0 pmV?1 for PMPD and 60.4 pmV?1 for PHND ) which are significantly large compared to the value of LiNbO3 (31 pmV?1) as a typical EO material. The d33 values of the poled copolymers were kept constant even after standing 1000h at 80 °C, although a small decrease was observed at an initial stage. Further, the d33 values did not change up to ca. 123 °C upon heating at the rate of 10 °C/min in all cases. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
74.
We study asymptotic properties of discrete and continuous time generalized simulated annealing processesX(·) by considering a class of singular perturbed Markov chains which are closely related to the large deviation of perturbed diffusion processes. Convergence ofX(t) in probability to a setS
0 of desired states, e.g., the set of global minima, and in distribution to a probability concentrated onS
0 are studied. The corresponding two critical constants denoted byd and withd are given explicitly. When the cooling schedule is of the formc/logt, X(t) converges weakly forc>0. Whether the weak limit depends onX(0) or concentrates onS
0 is determined by the relation betweenc, d, and . Whenc>, the expression for the rate of convergence for each state is also derived. 相似文献
75.
基于数据流方法的大规模网络异常发现 总被引:6,自引:0,他引:6
随着网络规模和速度的增加,大规模网络异常发现要求检测算法能够在无保留状态或者少保留状态下对G比特级的海量网络业务量数据进行实时在线分析。针对在高速骨干网上进行大规模网络异常发现的特点和要求,提出了一种基于数据流的大规模网络异常发现的方法,第一次将数据流模型用于大规模网络的异常发现。主要包括以下创新点:设计了一种面向异常发现的网络流量概要数据结构和突发高频事件检测算法;提出了一种基于安全监测策略定制的预查询方法来进行多数据流的关联监测并且对数据流查询进行了优化;在真实数据分析的基础上,对网络业务量进行了数据约减,使得监测部分特殊类型的数据流能最大程度地获得整体网络业务量的变化特征以提高异常发现的效率。通过真实网络环境下的实验和性能评价验证了数据流方法的有效性。 相似文献
76.
77.
The numerical simulation of turbulence is one of the most challenging tasks in the field of the modern computational science. At present, the most advanced approach is the large eddy simulation (LES) technique wherein a formal separation between resolved (large) and unresolved (small) scales of the motion is in effect by means of a filtering operation applied onto the governing equations. However, LES requires very sophisticated numerical discretizations in terms of both accuracy and efficiency. Often, the modelling of the unresolved subgrid scale terms adds further computational complexities. This paper illustrates the suitability in using software packages for symbolic computation (in the present case, Maple© for helping in the production of subroutines for a new multidimensional, high‐order accurate finite volume‐based LES code. Specifically, it will be detailed how producing, rapidly and efficiently, the routines for computing convective, diffusive as well as subgrid scale modelling fluxes. It is particularly detailed how exploiting the package for differential calculus and linear algebra for the analytical integration of the flux polynomials over the finite volume faces. The structure of the LES code is illustrated, and an accuracy analysis of the local truncation errors is performed comparing the third‐order accurate multidimensional upwind and the classical second‐order centred reconstruction in the wavenumbers space. Then, some numerical results for the turbulent plane channel and some brief points concerning the parallelization issue are addressed. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
78.
The accuracy of boundary conditions for computational aeroacoustics is a well‐known challenge, due in part to the necessity of truncating the flow domain and replacing the analytical boundary conditions at infinity with numerical boundary conditions. In particular, the inflow boundary condition involving turbulent velocity or scalar fields is likely to introduce spurious waves into the domain, therefore degrading the flow behavior and deteriorating the physical acoustic waves. In this work, a method to generate low‐noise, divergence‐free, synthetic turbulence for inflow boundary conditions is proposed. It relies on the classical view of turbulence as a superposition of random eddies convected with the mean flow. Within the proposed model, the vector potential and the requirement that the individual eddies must satisfy the linearized momentum equations about the mean flow are used. The model is tested using isolated eddies convected through the inflow boundary and an experimental benchmark data for spatially decaying isotropic turbulence. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
79.
K. Przewlocki L. Petryka Z. Stḙgowski 《Isotopes in environmental and health studies》2013,49(9):439-444
One of the most difficult operations for control and identification in copper ore concentration process is grain classification in hydrocyclone batteries. In the paper radiotracer investigations of the classification process immediately give values of hydrocyclones parameters with higher accuracy than obtained from conventional methods. Presented paper includes the results of the investigation which was carried out in “Lubin” Copper Mine in Poland. 相似文献
80.
Giancarlo De Santis Luigi Fabbrizzi Maurizio Licchelli Piersandro Pallavicini Angelo Perotti Antonio Poggi 《Supramolecular chemistry》2013,25(2):115-125
Abstract The new ferrocene-containing water-soluble ligands 1 and 2 were synthesized and their protonation and complexation properties toward NiII and CuII studied as a function of pH, by means of potentiometric titration experiments. Electrochemical measurements were performed in aqueous solution on pure 1 and 2 and in the presence of NiII and CuII cations, in the pH range 2–12, allowing us to determine the redox potential values relative to the ferrocene oxidation in the free ligands and in their NiII and CuII complexes. 1 and 2 behave as redox switchable ligands, the former enhancing, the latter decreasing its binding ability upon oxidation of the appended ferrocene function. Besides, the CuII complex of ligand 1 and the NiII complex of ligand 2 behave as two-centre two-electron redox systems, the complexed metal cation being subject to further oxidation to MIII. 相似文献