历史订单信息对牛鞭效应的影响分析

客户需求信息的失真是导致牛鞭效应存在的原因,基于零售商的历史订单数据对其需求进行预测可以部分消除牛鞭效应。论文基于零售商-分销商二级供应链视角,分析了在零售商的需求为线性自回归模式的二级供应链中,分销商利用零售商历史订单数据和现有订单数据进行需求预测时自身库存成本的变更以及整个供应链的牛鞭效应的缓解程度。结果表明:分销商利用历史订单数据进行库存的决策可以显著地降低自己的平均库存和需求的波动,这种降低程度在零售商的订货提前期较大的情况下比较明显,但是零售商的需求预测相关系数对它影响不大。     

Chemical vapor transport and solid-state exchange synthesis of new copper selenite bromides

A new dimorphic copper selenite bromide, Cu₅(SeO₃)₄Br₂ was obtained via chemical transport reactions. α-Cu₅(SeO₃)₄Br₂, monoclinic (1m) and β-Cu₅(SeO₃)₄Br₂, triclinic (1a) polymorphs were produced simultaneously upon reaction of amorphous, partially dehydrated copper selenite and copper bromide. 1m is similar to Cu₅(SeO₃)₄Cl₂, whereas 1a is distantly related to Ni₅(SeO₃)₄Br₂ and Co₅(SeO₃)₄Br₂. Attempts to reproduce synthesis of 1a via exchange reaction between Na₂SeO₃ and CuBr₂ resulted in a new Na₂[Cu₇O₂](SeO₃)₄Br₄ (2). Current study demonstrates for the first time, that both chemical vapor and exchange reactions can be employed in preparation of new selenite halides.     

Sodium and Manganese Stoichiometry of P2‐Type Na2/3MnO2

To realize a reversible solid‐state Mn^III/IV redox couple in layered oxides, co‐operative Jahn–Teller distortion (CJTD) of six‐coordinate Mn^III (t_2g³–e_g¹) is a key factor in terms of structural and physical properties. We develop a single‐phase synthesis route for two polymorphs, namely distorted and undistorted P2‐type Na_2/3MnO₂ having different Mn stoichiometry, and investigate how the structural and stoichiometric difference influences electrochemical reaction. The distorted Na_2/3MnO₂ delivers 216 mAh g^?1 as a 3 V class positive electrode, reaching 590 Wh (kg oxide)^?1 with excellent cycle stability in a non‐aqueous Na cell and demonstrates better electrochemical behavior compared to undistorted Na_2/3MnO₂. Furthermore, reversible phase transitions correlated with CJTD are found upon (de)sodiation for distorted Na_2/3MnO₂, providing a new insight into utilization of the Mn^III/IV redox couple for positive electrodes of Na‐ion batteries.     

Theoretical Studies on Electronic Structures and Spectra for C80^n （D5d,C2v） Singlet

1INTRODUCTIONC80iscalledthemissingfullereneduetoitsinstabilityinkineticsandlowerLUMO-HOMOenergygap[1],aswellasthelowerabundanceintheexperimentandthedifficultyinsynthesis[1~5].However,thestableexistenceofcomplexLa2@-C80[2]stimulatestheresearchinterestinionsofC80.Zhang[3]performedtheoreticalstudiesonthestabi-lityandNMRspectraforC80isomers.Nakao[4]cal-culatedtheLUMO-HOMOenergygapofC80byusingabinitiomolecularorbital.Hennrich[5]syn-thesizedC80(D5)fromfullerenesootextractionbydHPLC.…     

[Pd(en)2Pd(en)2X2]4+n(X=Cl,Br,I)链的畸变研究

对一维卤桥过渡金属化合物〔Ｐｄ（ｅｎ）２Ｐｄ（ｅｎ）２Ｘ２〕ｎ＾４＋（Ｘ＝Ｃｌ,Ｂｒ,Ｉ）应用量子化学从头算及ＥＨＴ能带计算进行了研究,发现Ｐｅｉｅｒｌｓ畸变的产生及程度取决于填充轨道能量的降低与核间及电子间相互作用。     

富勒烯离子Jahn-Teller畸变和光谱研究进展

M_xC₆₀ (M= K、Cs、Rb) 具有的超导性启发人们对C₆₀^n- 和C₇₀^n- 展开了深入研究。本文综述了富勒烯离子C₆₀^n±、C₇₀^n±、C₇₆^n±、C₇₈^n±及C₈₀^n±的结构畸变和光谱研究进展,介绍了国内外近十几年来众多研究小组的有关工作,从实验检测到理论计算, 从结构探讨到谱学性质研究, 并结合作者在此方面的理论研究成果,进一步探索富勒烯离子Jahn-Teller 畸变的特点和产生原因以及其电子光谱的规律性。     

Spirals on Si(1 1 1) at sublimation and growth: REM and LODREM observations

Using recently proposed improvements of reflection electron microsopy (REM) we study, in perfectly controlled thermodynamics conditions, spiral and spirals shapes on Si(1 1 1) surface. It is shown that the new method named low distortion reflection electron microscopy (LODREM) is a powerful instrument, resolving in much more details (compared with REM) growth or evaporation spirals at the crystal surface. More precisely, we examine the distance between two successive steps of a spiral at growth (or evaporation) with respect to the supersaturation (or undersaturation). It is found that this distance scales with an exponent close to −1/2. This result, which deviates from the BCF theory, originates from a non-local behavior with a slow kinetic of attachment of the adatoms at the steps.     

数字CATV系统中激光器削波对QAM信号影响的研究

目前的CATV网络不仅要传输一般的模拟信号,而且要能够传输QAM调制的数字信号。重点分析了数字CATV网络中数字频道和模拟频道的相互影响以及QAM调制的原理,讨论了在发射机端激光器削波对数字信号的影响,并给出了仿真结果。分析结果表明,QAM信号的误码率和QAM信号的光调制度、削波失真系数以及削波失真与高斯噪声之间的比例等都有密切的关系,激光器削波将严重恶化数字QAM信号的误码率。     

液晶E7的动力学模式的激光散射研究

向列液晶的动力学行为展示为两个动力学模式 ,即展曲和扭曲变形模式。用激光散射法测定了向列液晶E7的动力学变形模式 ,结果表明 ,在适宜的散射角范围内及不同的温度下可同时观察测定到展曲和扭曲变形模式 ,且通过频率和波矢的关系曲线可求出各粘弹性系数。