铌酸锂干法刻蚀的研究进展

概述了近年来国内外对铌酸锂(LN)晶体干法刻蚀技术的研究进展。根据刻蚀原理和特点,现有的LN干法刻蚀技术可分为等离子体刻蚀、激光微加工技术和Ti扩散电化学刻蚀。对各刻蚀方法及其研究进展进行了总结,分析了不同干法刻蚀方法之间的区别和联系,并对各方法中存在的问题进行了探讨。其中等离子体刻蚀技术由于其良好的图形转移特性,得到了最广泛的应用;激光微加工技术在制备光子晶体结构和微光栅结构中具有独特的优势;Ti扩散电化学刻蚀LN为制备大尺寸的LN基结构指明了新的方向。     

Tungsten‐Based Materials for Lithium‐Ion Batteries

Lithium‐ion batteries are widely used as reliable electrochemical energy storage devices due to their high energy density and excellent cycling performance. The search for anode materials with excellent electrochemical performances remains critical to the further development of lithium‐ion batteries. Tungsten‐based materials are receiving considerable attention as promising anode materials for lithium‐ion batteries owing to their high intrinsic density and rich framework diversity. This review describes the advances of exploratory research on tungsten‐based materials (tungsten oxide, tungsten sulfide, tungsten diselenide, and their composites) in lithium‐ion batteries, including synthesis methods, microstructures, and electrochemical performance. Some personal prospects for the further development of this field are also proposed.     

硅探测器加工中的离子注入工艺设计与控制

应用离子注入工艺可制备获得线性电流大、窗口死层薄的硅pin辐射探测器。首先简要介绍了离子注入工艺形成pn结的原理,重点根据技术要求进行了离子注入工艺设计和计算,分别得到了注入能量为40 keV和注入剂量为4×1014/cm2的两个重要控制参数。同时分析了在离子注入工艺中存在的影响因素和相应处理方法,对生产具有良好的指导作用。采用所设计的工艺参数制备获得的硅pin辐射探测器各项技术指标均满足要求,验证了离子注入工艺设计与参数控制的有效性。     

Atomic Insights into the Enhanced Surface Stability in High Voltage Cathode Materials by Ultrathin Coating

Surface properties of electrode materials play a critical role in the function of batteries. Therefore, surface modifications, such as coatings, have been widely used to improve battery performance. Understanding how these coatings function to improve battery performance is crucial for both scientific research and applications. In this study the electrochemical performance of coated and uncoated LiNi_0.5Mn_1.5O₄ (LNMO) electrodes is correlated with ensemble‐averaged soft X‐ray absorption spectroscopy (XAS) and spatially resolved scanning transmission electron microscopy‐electron energy loss spectroscopy (STEM‐EELS) to illustrate the mechanism of how ultrathin layer Al₂O₃ coatings improve the cycle life of LiNi_0.5Mn_1.5O₄. Mn²⁺ evolution on the surface is clearly observed in the uncoated sample, which results from the reaction between the electrolytic solution and the surfaces of LiNi_0.5Mn_1.5O₄ particles, and also possibly atomic structure reconstructions and oxygen loss from the surface region in LiNi_0.5Mn_1.5O₄. The coating effectively suppresses Mn²⁺ evolution and improves the battery performance by decelerating the impedance buildup from the surface passivation. This study demonstrates the importance of combining ensemble‐averaged techniques (e.g., XAS) with localized techniques (e.g., STEM‐EELS), as the latter may yield unrepresentative information due to the limited number of studied particles, and sheds light on the design of future coating processes and materials.     

基于状态的测控设备维护决策方法

为解决定期预防性维护存在的弊端,提出了基于状态的测控设备维护决策方法,并参照OSA-CBM标准,构建了适用于测控系统的维护决策系统。通过对状态监测、故障诊断、性能评估、状态预测等关键技术的研究表明,该方法切实可行,可进一步提升测控设备维护管理水平。     

离子注入和脉冲激光退火制备碲超饱和掺杂单晶硅pn结

Pn junctions based on single crystalline tellurium supersaturated silicon were formed by ion implantation followed by pulsed laser melting（PLM）.P type silicon wafers were implanted with 245 keV ¹²⁶Te⁺ to a dose of 2×10¹⁵ ions/cm²,after a PLM process（248 nm,laser fluence of 0.30 and 0.35 J/cm²,1-5 pulses,duration 30 ns）,an n⁺ type single crystalline tellurium supersaturated silicon layer with high carrier density(highest concentration 4.10×10¹⁹ cm^-3,three orders of magnitude larger than the solid solution limit) was formed,it shows high broadband optical absorption from 400 to 2500 nm.Current-voltage measurements were performed on these diodes under dark and one standard sun（AM 1.5）,and good rectification characteristics were observed.For present results,the samples with 4-5 pulses PLM are best.     

一种新的图像去噪混合滤波方法

为了去除图像中混入的脉冲噪声和高斯噪声,提出了一种基于自适应中值滤波和模糊加权均值滤波的混合滤波方法.该方法首先进行噪声检测把受高斯型噪声污染的像素和受脉冲型噪声污染的像素区别开来,然后对受高斯噪声污染的像素采用模糊加权均值滤波算法,而对受脉冲噪声污染的像素则采用改进的中值滤波算法进行去噪.仿真结果证明,该方法更具有实用性和有效性.     

一种用于核辐射监测信号的多微处理系统

介绍了4兆伏静电正离子加速器的监测防护系统,该系统由多个微处理器与主控机分布式分布,组成高速多通道辐射信号采集控制系统,可以对多点核辐射的能量、强度、剂量率,剂量及剂量当量进行监测.系统的核电路部分采用最新的芯片产品,合理的硬件安排,优化的软件编程,在仅更换不同的探头后,便可探测分析γ,X及快中子辐射.在参数稍做调整之后,就可以广泛应用于类似条件的其他场所的辐射监测.     

Fluorescence studies and semiempirical calculations on alkali ion indicators

Two newly synthesized cryptands act as sensitive Na⁺- and K⁺-selective indicators for cation concentrations above 20 M. The fluorescence properties change markedly upon cation binding. In addition, the free ligands exhibit a pronounced sensitivity to pH, which is considerably lower for the cation complexes. Time resolved fluorescence is characterized by a decay time of about 5 ns that is attributed to the diprotonated protolytic state of the uncomplexed ligands. Semiempirical calculations show the systematic influence of the nitrogen lone pairs or the N–H bond on the stability of the system. The cause of the strong fluorescence intensity increase observed upon protonation of the fluorescent cryptands may be attributed to an increase in the S₁–T _x energy gap as a consequence of bridgehead nitrogen protonation.This is a peer-reviewed conference proceeding article from the Third Conference on Methods and Applications of Fluorescence Spectroscopy, Prague, Czech Republic, October 18–21, 1993.     

非等电子Sb替换Cu和Te后黄铜矿结构半导体Cu_3Ga_5Te_9的热电性能

热电材料是一类能够实现热与电相互转换的功能材料,在制冷和发电领域极具应用潜力.本文采用金属Sb元素非等电子替换Cu3Ga5Te9化学式中的Cu和Te,观察到材料Seebeck系数和电导率提升的现象.这些电学性能的改善与载流子浓度和有效质量的增大及迁移率基本维持不变有关.载流子浓度的提高是由于Sb原子占位在Te晶格位置后费米能级进入到价带所产生的空穴掺杂效应所致,同时也与Cu含量减少后铜空位(V-1Cu)浓度增大相关联.另外,非等电子替换后,阴离子(Te2-)移位导致了晶格结构缺陷参数u和η的改变,其改变量fiu和fiη与材料晶格热导率(κL)的变化密切相关.在766 K时,适量的Sb替换量使材料的最大热电优值(ZT)达到0.6,比Cu3Ga5Te9提高了近25%.因此,通过选择替换元素、被替换元素及替换量有效地调控了材料的电学及热学性能,在黄铜矿结构半导体中实现了非等电子元素替换改善热电性能的思想.