Linearization of column responses by correlation chromatography. Separation improvement and reduction of undesired adsorption effects

Summary Experiments and simulations prove that correlation chromatography can greatly reduce the disadvantage of a non-linear response of the chromatographic column. A factor that has been accepted as being an important source of error in correlation or multiplex chromatography, has been shown not to be. Separations affected, improve dramatically when correlation chromatography is used, and a substantial amount of correlation noise only arises when there is a large difference in separation between a conventional chromatogram and a correlogram.A model has been developed for simulating these nonlinearities. It is shown that, especially for correlation chromatography, the simulation results match the practical measurements very well.     

脉冲序列的快速搜索法及可信度分析

对于周期脉冲序列的信号分选识别，可采用序列搜索的时域方法[1，2]。本文将大周期内完全重复的脉冲序列分解为多个“单周期信号”．并把它们均定义为周期性信号．同时，提出了序列搜索的一种软件实现方法及密集视频脉冲信号分选的变步长、信步长快速搜索法．在此基础上，本文针对序列搜索分选法的可信度计算公式进行了推导和分析，证实了这种方法的可行性和有效性．     

应用粒子动态分析仪研究水力旋流器流场

利用粒子动态分析仪(PDA),对水力旋流器内固相颗粒流场做了全面的测定,得出水力旋流器内固相颗粒的流态、浓度及粒度分布,为进一步查清水力旋流器的工作机理提供了重要理论依据。     

Studies of the compositions of Pd(II) hydrolysis products

The characterization of the clusters formed on alkaline hydrolysis of [PdCl₄]^2– was performed using¹⁷O,²³Na,³⁵Cl,¹³³Cs NMR and UV spectroscopy. The chemical composition of the clusters was found to be [Pd(OH)₂] _n ·nNaCl. No mononuclear oxo- or hydroxocomplexes were detected. The spatial structure of the clusters is stabilized by alkali metal cations.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 675–679, April, 1993.     

Polarized Spacetime Foam

An approximate model of a spacetime foam is presented. It is supposed that in the spacetime foam each quantum handle is like to an electric dipole and therefore the spacetime foam is similar to a dielectric. If we neglect of linear sizes of the quantum handle then it can be described with an operator containing a Grassman number and either a scalar or a spinor field. For both fields the Lagrangian is presented. For the scalar field it is the dilaton gravity + electrodynamics and the dilaton field is a dielectric permeability. The spherically symmetric solution in this case give us the screening of a bare electric charge surrounded by a polarized spacetime foam and the energy of the electric field becomes finite one. In the case of the spinor field the spherically symmetric solution give us a ball of the polarized spacetime foam filled with the confined electric field. It is shown that the full energy of the electric field in the ball can be very big.     

瞬态非傅里叶导热效应判据的探讨

讨论了通用傅里叶导热定律的数学模型,推导了半无限大物体在第一类边界条件下的基于非傅里叶导热定律的双曲线型偏微分方程的解析解。通过分析非傅里叶导热定律在瞬态条件下温度分布的变化过程,提出了非傅里叶导热效应的瞬态判据以及非傅里叶导热的作用范围,对研究工程中瞬态导热问题(如激光处理,电子束处理等)有重要意义。     

Recursive partition and amalgamation with the exponential family: Theory and applications

The theory of tree-growing (RECPAM approach) is developed for outcome variables which are distributed as the canonical exponential family. The general RECPAM approach (consisting of three steps: recursive partition, pruning and amalgamation), is reviewed. This is seen as constructing a partition with maximal information content about a parameter to be predicted, followed by simplification by the elimination of ‘negligible’ information. The measure of information is defined for an exponential family outcome as a deviance difference, and appropriate modifications of pruning and amalgamation rules are discussed. It is further shown how the proposed approach makes it possible to develop tree-growing for situations usually treated by generalized linear models (GLIM). In particular, Poisson and logistic regression can be tree-structured. Moreover, censored survival data can be treated, as in GLIM, by observing a formal equivalence of the likelihood under random censoring and an appropriate Poisson model. Three examples are given of application to Poisson, binary and censored survival data.     

计算全息检测非球面干涉场的理论分析与实验结果

本文应用光学全息术及傅里叶光学的理论对计算全息图干涉检测非球面面形的光路及干涉场进行了理论分析,提出了其干涉场为不定域干涉的观点,并在实验中予以证实.     

Schwinger boson mapping of SO(8) fermion model

The Schwinger representation of the SO(8) fermion pair algebra in terms ofd and quasispin vector (u, s, v) bosons is used in deriving a microscopic boson coherent state having both particle-hole and pair excitations. The coherent state is the exact boson image of the HFB variational solution. We can study the shape phase transition and pairing behaviour of the nuclear ground states using the coherent states.     

An algebraic characterization ofB-convergent Runge-Kutta methods

Summary In the analysis of discretization methods for stiff intial value problems, stability questions have received most part of the attention in the past.B-stability and the equivalent criterion algebraic stability are well known concepts for Runge-Kutta methods applied to dissipative problems. However, for the derivation ofB-convergence results — error bounds which are not affected by stiffness — it is not sufficient in many cases to requireB-stability alone. In this paper, necessary and sufficient conditions forB-convergence are determined.This paper was written while J. Schneid was visiting the Centre for Mathematics and Computer Science with an Erwin-Schrödinger stipend from the Fonds zur Förderung der wissenschaftlichen Forschung