Fisher分布下基于白化滤波的极化SAR图像CFAR检测方法

在已有的极化合成孔径雷达（SAR）图像恒虚警（CFAR）检测方法中,存在着高分辨下杂波模型适用性差的难题.为此提出了一种Fisher分布下具有虚警概率解析表达形式的CFAR检测方法.首先,在乘积模型框架下,引入Fisher纹理变量,推导出了极化白化滤波（PWF）检测量的概率密度函数（PDF）.然后,对PDF积分得到了虚警概率关于检测门限的解析表达形式,并设计了相应的CFAR检测算法流程.最后,通过机载合成孔径雷达（AIRSAR）实测数据比较了新方法和双参数恒虚警（2P-CFAR）算法及已有的基于K分布、G₀分布、Wishart分布的CFAR检测方法的检测性能.结果表明新方法能有效检测出目标,且鲁棒性较强,相比于其他检测方法,品质因数平均高出32.66%.     

中频相参数字接收机的相位补偿误差分析

中频相参雷达是一种通过在中频上的频率跟踪和相位补偿使不相参的回波具备相参性的雷达系统,这种雷达成本低、功率大,但是测速偏差和地物抑制能力相较全相参系统偏低,在实际使用中难以满足用户的需求。鉴于此,通过对中频相参数字接收机的频率跟踪和相位补偿功能的原理分析,推导出中频相参数字接收机经过相位补偿后,得到的回波的发射初始相位并不能修正到零,实际上存在两部分误差：第一部分与中频相参数字接收机内部数字控制振荡器（NCO）的频率、回波与样本脉冲之间的延时关系成正比,只要对NCO频率进行调整,此误差在脉间和距离上就是变化的;而第二部分是测频处理算法带来的误差。在发射样本信号频率变化不大的情况下,第一部分相位补偿误差在脉间的变化对多普勒速度处理的偏差、信号功率谱的展宽以及信噪比的下降起主导作用。在以上推论的基础上,改进了中频相参数字接收机的频率跟踪策略,有效改善了测速精度和地物抑制能力。     

Khatri-Rao积变换下的离格信号DOA估计

当存在离格信号时,基于稀疏表示的波达角(DOA)估计算法性能损失严重.为解决这个问题,在对接收数据协方差矩阵进行Khatri-Rao积变换的基础上,推导了离格信号网格偏离量与紧邻信号原子系数之间的关系,提出了一种单一离格信号DOA估计方法.为提高对邻近离格信号DOA的估计性能,利用矩阵的广义逆性质提出了基于多原子系数的联合估计方法.仿真实验表明,单一离格信号DOA估计方法在低信噪比下有较好的性能,联合估计方法在高信噪比条件下对邻近离格信号DOA有较高的估计精度,同时所提算法估计性能几乎不受网格划分间距的影响,可以通过增大网格间距降低算法运算量.相关研究对阵列天线DOA估计具有一定的参考价值.     

User scheduling based on angles with block diagonalization in MU‐MIMO broadcast

This paper investigates user selection scheme in the multiuser multiple‐input multiple‐output (MU‐MIMO) broadcast (BC) scene with block diagonalization precoding. Block diagonalization is a suboptimal but practical linear precoding method, which can eliminate the multiuser interference by turning the MU‐MIMO BC channel into parallel MIMO channels. With this precoding method, we propose the best user from the user subset to maximize the total throughput in the MU‐MIMO BC system. The angles between subspaces used in this paper are induced from n ‐inner product, an extension from norm space to the n ‐dimensional space, which characterizes the orthogonality between subspaces. One of the algorithms achieves good performance by comparing the capacity greedily, the other one attains high capacity by reducing the cardinality of the user subset to improve the orthogonality between the user channels, which could be seen as a complexity reduction algorithm with respect to the former one. Indeed, they are all based on the angles between subspaces. Analysis shows that both of the proposed algorithms have lower complexity and better performance than the classical algorithms. The numerical results also confirm our analysis.     

Bandwidth of the strong product of two connected graphs

The bandwidth B(G) of a graph G is the minimum of the quantity max{|f(x)-f(y)|:xy∈E(G)} taken over all proper numberings f of G. The strong product of two graphs G and H, written as G(S_P)H, is the graph with vertex set V(G)×V(H) and with (u₁,v₁) adjacent to (u₂,v₂) if one of the following holds: (a) u₁ and v₁ are adjacent to u₂ and v₂ in G and H, respectively, (b) u₁ is adjacent to u₂ in G and v₁=v₂, or (c) u₁=u₂ and v₁ is adjacent to v₂ in H. In this paper, we investigate the bandwidth of the strong product of two connected graphs. Let G be a connected graph. We denote the diameter of G by D(G). Let d be a positive integer and let x,y be two vertices of G. Let denote the set of vertices v so that the distance between x and v in G is at most d. We define δ_d(G) as the minimum value of over all vertices x of G. Let denote the set of vertices z such that the distance between x and z in G is at most d-1 and z is adjacent to y. We denote the larger of and by . We define η(G)=1 if G is complete and η(G) as the minimum of over all pair of vertices x,y of G otherwise. Let G and H be two connected graphs. Among other results, we prove that if δ_D(H)(G)?B(G)D(H)+1 and B(H)=⌈(|V(H)|+η(H)-2)/D(H)⌉, then B(G(S_P)H)=B(G)|V(H)|+B(H). Moreover, we show that this result determines the bandwidth of the strong product of some classes of graphs. Furthermore, we study the bandwidth of the strong product of power of paths with complete bipartite graphs.     

Convolution properties for certain classes of multivalent functions

Recently N.E. Cho, O.S. Kwon and H.M. Srivastava [Nak Eun Cho, Oh Sang Kwon, H.M. Srivastava, Inclusion relationships and argument properties for certain subclasses of multivalent functions associated with a family of linear operators, J. Math. Anal. Appl. 292 (2004) 470-483] have introduced the class of multivalent analytic functions and have given a number of results. This class has been defined by means of a special linear operator associated with the Gaussian hypergeometric function. In this paper we have extended some of the previous results and have given other properties of this class. We have made use of differential subordinations and properties of convolution in geometric function theory.     

(−)-Quinic acid: a versatile precursor for the synthesis of analogues of 2-crotonyloxymethyl-(4R,5R,6R)-4,5,6-trihydroxycyclohex-2-enone (COTC) which possess anti-tumour properties

Syntheses of three novel analogues of the Streptomyces metabolite COTC are described, using the versatile chiral pool starting material, (−)-quinic acid. The results of bioassays of the target compounds against two lung cancer cell lines, A549 and H460, are presented.     

捕捉环加成反应中的有机亚铜中间体构筑氮杂环化合物研究进展

铜(I)盐催化的环加成反应,如叠氮-炔[3+2]环加成(Cu AAC)、不饱和化合物与异氰基化合物的[3+2]环加成、硝酮-炔的环加成(Kinugasa反应)是构建多类氮杂环的高效合成方法,被广泛应用于有机合成的各个领域.近年来,针对几类环加成反应中产生的有机亚铜中间体的多样性转化吸引了国内外很多课题组的注意,基于对这些环加成反应中有机亚铜中间体的捕捉,多类串联及多组分反应得以发展,从而成功实现了一系列多取代杂环或稠环结构的高效构建.本综述总结了这一领域的研究进展,按照所经历的有机亚铜中间体的类型进行分类,包括:(1)Cu AAC反应中产生的三氮唑亚铜中间体;(2)炔烃与异氰化合物[3+2]环加成反应中产生的2H-吡咯基亚铜中间体;(3) Kinugasa反应中产生的烯醇亚铜中间体.期望此综述能够有助于研究者了解有机亚铜中间体捕捉策略的发展、应用现状及不足之处,进一步推动铜催化转化的发展.     

光催化剂活性位点调控及其光还原CO2制C2 产物研究进展

工业发展与人类活动导致大气中CO₂浓度逐年升高, 引发一系列生态环境问题. 将CO₂光催化转化为高附加值化学物质不仅有利于缓解环境压力,也可以带来额外经济价值. 然而, 由于多电子利用效率低和C―C偶联动力学缓慢, 光还原CO₂制多碳产品面临产率低和选择性差等挑战. 光催化剂活性位点调控能够有效解决上述问题. 我们综述了近几年用于光还原CO₂催化剂表面活性位点设计的研究进展, 主要包括缺陷位点、 金属位点以及掺杂位点等, 从活性位点的角度为光还原CO₂催化剂设计提供新视角, 并对开发高效光催化剂具有启发意义.     

Kinetics and Mechanism of the Photo-oxidation of Thiophene by O2 Adsorbed on Molecular Sieves

Photochemical oxidation of thiophene in n-octane/water extraction system using O2 as oxidant was studied. The reaction mechanism ofthiophene oxidation was proposed. Results obtained here can be used as the reference for the oxidative desulfurization of gasoline because thiophene is one of the main components containing sulfur in fluid catalytic cracking gasoline. Thiophene dissolved in n-octane was photodecomposed and removed into the water phase at ambient temperature and atmospheric pressure. A 500 W high-pressure mercury lamp （main wave length 365 nm, 0.22 kW/m） was used as light source for irradiation, and air was introduced by a gas pump to supply O2. Thiophene can be photo-oxidized to sulfone, oxalic acid, SO4^2-, and CO2. The desulfurization yield of thiophene in n-octane is 58.9% under photo-irradiation for 5 h under the conditions of air flow at 150 mL/min and V（water）：V（n-octane）=1：1. It can be improved to 92.3% by adding 0.15 g zeoliteartificial into 100 mL reaction system, which is the adsorbent for O2 and thiophene. And under such conditions, the photo-oxidation kinetics of thiophene with O2/zeoliteartificial is first-order with an apparent rate constant of 0.5047 h^-1 and a half-time of 1.37 h. The sulfur content can be depressed from 800 μL/L to less than 62 μL/L.