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41.
The orientational relaxation of optically induced anisotropy in rarefied gases and at a damped rotation has been investigated. It has been found that the anisotropy relaxation in rarefied gases is described by a reduced kinetic equation depending only on free rotation integrals. The behavior of the integral anisotropy of luminescence for free symmetric and asymmetric top molecules has been elucidated. The law of luminescence depolarization has been obtained for asymmetric top molecules in the Gordon J-diffusion model. It represents the sum of two Stern–Volmer-type dependences, whose relative contribution is determined by the orientation of the dipole moments of transitions with absorption and emission of light in the molecular coordinate system and by the principal moments of inertia of the molecular top. It has been established that in the limit of a strongly damped rotation, kinetic equations of the general form reduce to equations of rotational diffusion. A number of modified diffusion equations correctly describing the contribution of inertial effects to the orientational relaxation of anisotropy have been obtained. 相似文献
42.
Evgenia Adamopoulou Konstantinos Demestichas Panagiotis Demestichas Michael Theologou 《International Journal of Communication Systems》2008,21(3):311-330
Cognitive radio systems dynamically reconfigure the algorithms and parameters they use, in order to adapt to the changing environment conditions. However, reaching proper reconfiguration decisions presupposes a way of knowing, with high enough assurance, the capabilities of the alternate configurations, especially in terms of achievable transmission capacity and coverage. The present paper addresses this problem, firstly, by specifying a complete process for extracting estimations of the capabilities of candidate configurations, in terms of transmission capacity and coverage, and, secondly, by enhancing these estimations with the employment of a machine learning technique. The technique is based on the use of Bayesian Networks, in conjunction with an effective learning and adaptation strategy, and aims at extracting and exploiting knowledge and experience, in order to reach robust (i.e. stable and reliable) estimations of the configurations' capabilities. Comprehensive results of the proposed method are presented, in order to validate its functionality. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
43.
研究了 2 0 0 0年 MCM— B题 ,将问题推广到有三层干扰的复杂情况 ,给出并严格证明了 ( k,1,1)问题的最优解 相似文献
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Michael C. W. Chan Dr. 《化学:亚洲杂志》2008,3(1):18-27
The notion of weak attractive ligand–polymer interactions is introduced, and its potential application, importance, and conceptual links with “cooperative” ligand–substrate interactions are discussed. Synthetic models of weak attractive ligand–polymer interactions are described, in which intramolecular weak C? H???F? C interactions (the existence of which remains contentious) have been detected by NMR spectroscopy and neutron and X‐ray diffraction experiments. These C? H???F? C interactions carry important implications for the design of catalysts for olefin polymerization, because they provide support for the practical feasibility of ortho‐F???Hβ ligand–polymer contacts proposed for living Group 4 fluorinated phenoxyimine catalysts. The notion of weak attractive noncovalent interactions between an “active” ligand and the growing polymer chain is a novel concept in polyolefin catalysis. 相似文献
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介绍了电磁辐射的分类和非无线电辐射造成的各种危害,指出了可能产生电磁辐射的设备,给出了几种特殊情况的辐射值,并结合国际标准和国家标准,分析了电磁干扰的管理现状,最后提出了减少非无线电设备电磁辐的几种方法。 相似文献
49.
Pure gas sorption and transport properties of polyesters based on bisphenol-A and both pure isophthalic and pure terephthalic acid chloride were obtained for He, N2, O2, CH4, and CO2 at 35°C. The polymers were synthesized in our laboratory and amorphous films were prepared with a specialized solvent casting procedure. The polymer containing m-phenylene groups shows higher permselectivity for most of the gas pairs. The ideal selectivity of O2/N2 was increased by 33% when p-phenylene units were replaced by m-phenylene ones. On the other hand, the polyester containing only p-phenylene groups, shows higher permeability to all the gases studied. The polymer based on pure terephthalic acid chloride has a 75% higher oxygen permeability and a 1.1-fold higher carbon dioxide permeability than the isophthalic acid derivative. The polyester containing meta-phenylene units has lower Tg, higher permselectivity, lower permeability, lower fractional free volume (FFV), and lower d-spacing. The values of FFV, and lower d-spacing. The values of FFV and d-spacing were only slightly different between the two isomers. Moreover, for the sub-Tgγ transition the maximum in tan δ occured at essentially the same temperature (?55°C). The polymer with a higher concentration of p-phenylene units shows somewhat larger area under the γ-peak, indicating slightly more sub-Tg motion. The Distribution of FFV is considered to be the determining factor for the differences in transport properties observed. © 1993 John Wiley & Sons, Inc. 相似文献
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