TGA-DTA,infrared and x-ray powder diffraction studies on strontium nitroprusside and its hydrates

Dehydration data for the tetra-, di- and monohydrate of strontium nitroprusside and the vibrational behaviour of the water molecules in normal and deuterated samples agree with crystal data previously reported (for the di- and tetrahydrate as single crystals) and in this paper (monohydrate as a powder). Four distinct types of water molecules are present in the three hydrates with one type (oxygen bonded to Sr²⁺) in common. Other types are a non hydrogen-bonded molecule (dihydrate), a molecule bonded by a single hydrogen atom to the nitrogen atom of a cyanide group and a set of two molecules similarly bonded to the oxygen atom of the previous type (tetrahydrate). The spatial orientation of the NO groups of the nitroprusside ions in the tetrahydrate is confirmed by the observed dichroism of the corresponding stretching band.     

Photochemical transformations-iv: Oxyfunctionalization of some saturated hydrocarbons with hydroxyl radicals (1)

It is shown that hydroxylation of saturated hydrocarbons by hydrogen peroxide occurs under the influence of light. This reaction has been investigated on acyclic, monocyclic and bicyclic hydrocarbons. These reactions were also studied using performic acid as the source of hydroxyl radicals and results compared with those obtained with peracetic acid. As expected, the preferred attack was on tertiary centres, followed by secondary and then primary.     

Squeeze film flow of ideal elastic liquids

An exact solution is presented for the squeeze film flow of an Oldroyd B. fluid. The solution demonstrates that the flow kinematics is similar to the Newtonian (or Maxwellian) one. Theoretical predictions for constant velocity squeezing are compared to experimental observation for well characterized non-shear thinning elastic fluids. It is shown both theoretically and experimentally that the effect of elasticity in a constant velocity squeeze film flow is to always reduce the load relative to the inelastic (Newtonian) prediction and that this load reduction falls between the upper and lower asymptote prediction by the exact solution for the Oldroyd B fluid. The upper load asymptote is given by the Stefan solution for the viscosity of the polymer solution and the lower asymptote is given by the Stefan solution for the viscosity of the solvent. Experimental observations agree with the theoretical prediction for the Oldroyd B fluid at low shear rates where it is shown that the steady and dynamic flow properties of the test fluids used in the experimental program are well represented by the Oldroyd B constitutive equation. With the exception of the work of Lee et al. [6] for constant load squeezing of a Maxwell fluid, this work represents one of the few cases where experimental observation of large effects due to elasticity are indeed predicted with a constitutive equation which actually describes the steady and dynamic shear properties of the fluids used in the experimental program.     

A critical re-appraisal of the jet-thrust technique for normal stresses,with particular reference to axial velocity and stress rearrangement at the exit plane

It is shown that the thrust, T, exerted by a jet on the tube from which it flows, and the corresponding die-swell ratio, D, are closely related and dependent on the axial velocity and stress profiles at the exit plane. Velocity-profile data, calculated by Tanner using a finite element method, have been used to demonstrate that for a Newtonian liquid the reduction in measured thrust from the expected value arises from a re-arranged, non-parabolic axial velocity profile and the related re-arranged non-zero axial stress profile at the exit plane. The axial stress re-arrangement is the major effect.Using the correction-curve thus derived to determine the normal stresses, ν₁ + $\text{1}\text{2}$ν₂ aqueous and non-aqueous polymer solutions gives values that are higher than the “correct” results by a significant, substantial amount. The difference is not due to neglect of the second normal stress difference, ν₂, nor to the neglect of the wall pressure at the exit plane, which is shown experimentally to be very small. It is suggested that the difference, which is a function only of the shear stress (or rate of shear) at the wall, may arise from a difference in the stress profile associated with the velocity re-arrangement at the exit between Newtonian liquids and elasticoviscous liquids for which the extensional viscosity may be high.     

An experimental study of nonrheometric flows of viscoelastic fluids: II. Flow in a liquid jet exiting from a vertical tube

A laser anemometer has been used to study the region of accelerating shear flow near the exit of a vertical tube. It is in this region that the transition between steady laminar shear flow in the upstream tube and elongational flow in the downstream liquid jet takes place.Downstream velocity profiles were measured for solutions of 0.9% polyacrylamide in 85% glycerol/water and 0.9% polyacrylamide in water. Reynolds numbers (based on wall conditions in the fully developed upstream flow) ranged from 45 to 310 and Froude numbers from 0.294 to 4.11. Tubes, having sharpedged and rounded exit corners, with diameters of 1.25 cm and 1.90 cm were usedUpstream velocity profiles were measured for a solution of 0.9% polyacrylamide in water. Reynolds numbers ranged from 16 to 670. Only tubes having sharp-edged exit corners were used.It was found that the transition region did not extend upstream into the tube but was confined to the downstream jet. The transition took place over a distance of about 3–5 tube diameters depending upon the value of the Froude number. The axial distance downstream from the tube exit plane at which the velocity profile first became flat increased with increasing Froude number. The magnitude of the jet velocity at this point decreased with increasing Froude number.The condition of the tube exit corner was found to influence the flow in the transition region. Downstream velocity profiles obtained using tubes having rounded exit corners initially develop more slowly than, but soon catch up with and eventually overtake, the corresponding profiles obtained using tubes with sharp-edged exit corners.Downstream velocity profiles obtained for the 0.9% polyacrylamide in 85% glycerol/water solution were found to develop smoothly. The transition from steady shear flow in the tube to elongational flow in the jet took place through the combined processes of acceleration of the outer layers of the jet due to radial transfer of momentum with adjacent inner layers, the process spreading steadily inwards with increasing axial distance from the tube exit plane, and acceleration of the whole due to gravity. However, the velocity profiles obtained for the 0.9% polyacrylamide in water solution did not always develop so smoothly. At a Reynolds number of 310 and Froude number of 2.06 the radial momentum transfer process was restricted to a narrow outer region of the jet until a downstream axial distance of about 2 tube diameters was reached. Thereafter, the transition to a flat profile took place smoothly.     

Fast electron energy loss spectrum of an amorphous tungsten trioxide film

The forward scattering energy loss spectrum of 300 KeV electrons transmitted through thin films of WO₃ has been measured in the energy range of 0.8–225 eV with an energy loss resolution of 0.1 eV. Energy losses due to excitation of color centers, inter band transitions and core elestrons in WO₃ have been identified. Measurement of the elastic electron difraction pattern revealed the amorphous nature of the film with structural differences depending upon the preparative methods.     

具有内悬臂的环板在两种不同荷载共同作用下的塑性极限分析

针对承受两种不同荷载的具有内悬臂环板的塑性极限分析问题，应用奇异函数给出一种分析方法。文中给出一些算例，由此显示出本文方法的简单方便性。     

Homoisopavinanes—a highly probable class of phenethylisoquinoline alkaloids

Homoisopavinanes have been prepared by acid-catalysed cyclisation of the appropriately substituted aminoacetaldehyde dimethylacetal derivatives. The characteristic mass spectral fragmentation patterns of these homoisopavinanes is described.     

Crystal structure and habit of fine metal particles formed by gas-evaporation technique; bcc metals (V,Fe, Cr,Mo and W)

Fine particles of several kinds of bcc metals were prepared by evaporation in an argon atmosphere. They were collected at various growth zones in the smokes and their structures and habits were studied by electron microscopy. Vanadium and iron particles grown in all zones have the ordinary bcc structure. However, chromium and molybdenum particles grown in the inner part of the smokes have the bcc structure, and those in the outer part have the A-15 type structure. Habits of particles with the bcc structure can be generally described in terms of rhombic dodecahedra truncated by six (100) faces with various degrees of truncation from 0 to 100%. The truncated rhombic dodecahedron is a common habit to the bcc metals, though the degree of truncation is dependent on the metal. For vanadium it varies from zone to zone systematically. Molybdenum particles of rounded cube and {211} icositetrahedron are found to have the A-15 type structure in addition to the well known {211} icositetrahedron and rhombic dodecahedron found in chromium.     

Long-term stability of glass electrodes in aqueous media

The stability of the potential of glass electrodes has been studied. The potential changes only slightly during the hydration of freshly etched electrodes. With glass electrodes previously used in alkaline solutions, structural transformations within the gel-layer give rise to large potential drifts in neutral or acidic test solutions. In alkaline solutions all glass electrodes are attacked, especially the low-temperature type, and the potential changes with time. Drying hydrated electrodes affects the stability only slightly. Alternating transfers between acidic and basic solutions decrease the stability. Recommendations for precise measurements with glass electrodes are given.