MEMS开关封装结构热形变对芯片性能的影响

模拟了处在一定功率密度或不同温度下封装结构贴片的形变引起的X波段MEMS开关芯片的形变,从而导致的开关芯片性能的变化。用Coventor软件模拟出在开关衬底为200μm,贴片处功率密度为300pW/μm2时,开关芯片的形变量为0.142μm;开关衬底为300μm,温度为373K时,开关芯片的形变量为0.791μm。进一步用HFSS模拟出开关的插入损耗在中心频率10GHz处由封装前的0.042dB和0.022dB变化为封装后的0.078dB和0.024dB。     

硅基竖直耦合三环谐振波分复用器的特性

对1×N信道硅基竖直耦合三环谐振波分复用器的传输特性进行了分析,给出了光学传递函数的公式.在中心波长1550.918nm、波长间隔1.6nm的情况下,对其振幅耦合比率、波谱响应、分光光谱、插入损耗、信道间的串扰进行了数值模拟.计算结果表明,该器件具有以下良好性能:若取小环与信道间的振幅耦合比率为0.27,小环与大环间的振幅耦合比率为0.06,该器件具有箱形波谱响应,输出光谱中的次峰值已被抑制到-25dB,谐振峰平坦且陡峭,3dB带宽约为0.28nm,每条输出信道的插入损耗及串扰较小,插入损耗小于0.71dB,串扰可降至-53dB以下.     

Zur Reaktion eines Bis(amino)germylens mit Germaniumaziden: Abfangreaktionen von instabilen Germa-Iminen

Reaction of a Cyclic Bis(amino)germylene with Germaniumazides: Trapping-Reactions of Unstable Germa-Imines . The cyclic bis(amino)germylene 1 reacts with different germaniumazides of the type Me₂Si(NtBu)₂Ge(R)N₃ (R = Me ( 2 ), tBu ( 3 ), N(SiMe₃)₂ ( 4 ), R = N₃ ( 5 )). With the exception of 4 all azides lose dinitrogen when treated with 1 and the Ge^II center coordinates the α-nitrogen of the azide group. It seems to be reasonable to assume a transient germaimine (nitride) which is trapped by further reaction with the azide molecules 2 and 5 or by reaction with the solvent pyridine ( 3 ). In the case of 2 the germatetrazole [Me₂Si(NtBu)₂]GeN₄[Ge(NtBu)₂SiMe₂]₂ ( 6 ) is formed, the tetrazole nitrogens being exclusively substituted by germanium atoms (point symmetry of the molecule C_s(m)). When 1 is treated with 5 a tris(germa)amine [Me₂Si(NtBu)₂Ge(N₃)]₃N ( 8 ) is formed, which has an azide group attached to each Ge-atom. X-ray analysis reveals that the nine nitrogen atoms of the azide groups are coplanar with the trigonal planar Ge₃N moiety (crystallographic symmetry: 3/m). The reaction of 1 with 3 is very surprising: the pyridine in the product Me₂Si(NtBu)₂Ge(C₅H₄N)? N(H)Ge(tBu)(NtBu)₂SiMe₂ ( 7 ) is bonded via an α-carbon atom while the remaining hydrogen has added to the nitride-nitrogen. 6 crystallizes in the monoclinic system space group C2/m, a = 24.306(9), b = 10.933(6), c = 19.420(9) Å, β = 91.81(2)° and Z = 4. 7 crystallizes in the hexagonal system space group P6₃/m with a = b = 16.73(1), c = 11.006(8) Å, γ = 120° and Z = 2, and 8 crystallizes in the monoclinic system space group P2₁/n, a = 11.341(6), b = 26.086(9), c = 13.244(7) Å, β = 98. I2(2)° mit Z = 4.     

B-Splines with Arbitrary Connection Matrices

We consider a space of Chebyshev splines whose left and right derivatives satisfy linear constraints that are given by arbitrary nonsingular connection matrices. We show that for almost all knot sequences such spline spaces have basis functions whose support is equal to the support of the ordinary B-splines with the same knots. Consequently, there are knot insertion and evaluation algorithms analogous to de Boors algorithm for ordinary splines.     

Electrochemical impedance study of lithium-ion insertion into rice husk carbon

Electrochemical impedance spectroscopy (EIS) was employed to study electrochemical behaviors during Li-ion insertion into rice husk carbon. The impedance spectra consist of two depressed semicircles in the high and middle range frequency and an incline line at low frequency. The impedance spectra, obtained in the potential range 2.0 to 0.005 V were analyzed with an equivalent circuit model. Kinetic parameters such as the charge-transfer resistance and surface film resistance were evaluated and discussed. Paper presented at the International Conference on Solid State Science and Technology 2006, Kuala Terengganu, Malaysia, September 4–6, 2006.     

哈密尔顿性和部分平方图的独立集

设G是一个图,G的部分平方图G*满足V(G*)=V(G),E(G*)=E(G)∪{uv:uv■E(G),且J(u,v)≠■},这里J(u,v)={w∈N(u)∩N(v):N(w)■N[u]∪N[v]}.利用插点方法,证明了如下结果:设G是k-连通图(k2),b是整数,0min {k,(2b-1+k)/2}(n(Y)-1),则G是哈密尔顿图.同时给出图是1-哈密尔顿的和哈密尔顿连通的相关结果.     

Intramolecular C-H insertion using NHC-di-rhodium(II) complexes: the influence of axial coordination

In this work we show that the intramolecular C-H insertion of diazo-acetamides catalysed by di-rhodium(II) complexes can be highly influenced by the axial ligand on the di-rhodium(II) complex. Axially monocoordinated NHC-Rh₂(OAc)₄ complexes have a distinct reactivity from the parent Rh₂(OAc)₄ complex affording the cyclisation products in different rates and selectivities. Surprisingly, a new reaction mode emerged when using these complexes which led to a decarbonylation pathway.     

Mechanistic Insights into the Substrate‐Controlled Stereochemistry of Glycals in One‐Pot Rhodium‐Catalyzed Aziridination and Aziridine Ring Opening

We carried out a principle study on the reaction mechanism of rhodium‐catalyzed intramolecular aziridination and aziridine ring opening at a sugar template. A sulfamate ester group was introduced at different positions of glycal to act as a nitrene source and, moreover, to allow the study of the relative reactivity of the nitrene transfer from different sites of the glycal molecule. The structural optimization of each intermediate along the reaction pathway was extensively done by using BPW91 functional. The crucial step in the reaction is the Rh‐catalyzed nitrene transfer to the double bond of the glycal. We found that the reaction could proceed in a stepwise manner, whereby the N atom initially induced a single‐bond formation with C1 on the triplet surface or in a single step through intersystem crossing (ISC) of the triplet excited state of the rhodium–nitrene transition state to the singlet ground state of the aziridine complexes. The relative reactivity for the conversion of the nitrene species to the aziridine obtained from the computed potential energy surface (PES) agrees well with the reaction time gained from experimental observation. The aziridine ring opening is a spontaneous process because the energy barrier for the formation of the transition state is very small and disappears in the solution calculations. The regio‐ and stereoselectivity of the reaction product is controlled by the electronic property of the anomeric carbon as well as the facial preference for the nitrene insertion, and the nucleophilic addition.