全文获取类型
收费全文 | 2714篇 |
免费 | 432篇 |
国内免费 | 204篇 |
专业分类
化学 | 219篇 |
晶体学 | 3篇 |
力学 | 430篇 |
综合类 | 37篇 |
数学 | 880篇 |
物理学 | 820篇 |
无线电 | 961篇 |
出版年
2024年 | 10篇 |
2023年 | 40篇 |
2022年 | 60篇 |
2021年 | 54篇 |
2020年 | 68篇 |
2019年 | 73篇 |
2018年 | 78篇 |
2017年 | 93篇 |
2016年 | 127篇 |
2015年 | 98篇 |
2014年 | 154篇 |
2013年 | 214篇 |
2012年 | 176篇 |
2011年 | 183篇 |
2010年 | 152篇 |
2009年 | 131篇 |
2008年 | 210篇 |
2007年 | 189篇 |
2006年 | 142篇 |
2005年 | 140篇 |
2004年 | 147篇 |
2003年 | 119篇 |
2002年 | 107篇 |
2001年 | 96篇 |
2000年 | 84篇 |
1999年 | 72篇 |
1998年 | 42篇 |
1997年 | 41篇 |
1996年 | 58篇 |
1995年 | 30篇 |
1994年 | 28篇 |
1993年 | 21篇 |
1992年 | 20篇 |
1991年 | 11篇 |
1990年 | 6篇 |
1989年 | 14篇 |
1988年 | 8篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1972年 | 2篇 |
1959年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有3350条查询结果,搜索用时 15 毫秒
51.
Yi Sun Kuanxin Zhang Run Chai Yueda Wang Xianhong Rui Kang Wang Huaxia Deng Hongfa Xiang 《Advanced functional materials》2023,33(36):2303020
Considered the promising anode material for next-generation high-energy lithium-ion batteries, SiOx has been slow to commercialize due to its low initial Coulombic efficiency (ICE) and unstable solid electrolyte interface (SEI) layer, which leads to reduced full-cell energy density, short cycling lives, and poor rate performance. Herein, a novel strategy is proposed to in situ construct an artificial hybrid SEI layer consisting of LiF and Li3Sb on a prelithiated SiOx anode via spontaneous chemical reaction with SbF3. In addition to the increasing ICE (94.5%), the preformed artificial SEI layer with long-term cycle stability and enhanced Li+ transport capability enables a remarkable improvement in capacity retention and rate capability for modified SiOx. Furthermore, the full cell using Li(Ni0.8Co0.1Mn0.1)O2 and a pre-treated anode exhibits high ICE (86.0%) and capacity retention (86.6%) after 100 cycles at 0.5 C. This study provides a fresh insight into how to obtain stable interface on a prelithiated SiOx anode for high energy and long lifespan lithium-ion batteries. 相似文献
52.
为了提高位置敏感探测器(PSD)的位置检测范围,解决光斑在探测器光敏面脱靶时无法准确定位光斑的问题,提出一种光斑脱靶误差补偿方法,分析了脱靶前后PSD检测光斑能量重心变化规律,建立了PSD光强信号与位置检测误差间的函数关系。实验结果表明:当PSD光敏面尺寸为12mm×12mm时,对于半径为5mm的高斯光斑,通过所提出的光斑补偿方案补偿后PSD的X轴检测范围提高了66.7%,位置检测平均相对误差不超过5%,该方法对提高PSD位置检测性能具有重要的意义。 相似文献
53.
梳理基于等待门限判决的脉冲位置键控系统相关文献资料,发现文献给出的误比特率(BER)理论公式不能准确描述系统误比特率,尤其是在低信噪比情况下一些理论公式计算的误比特率已经高于0.5,超过了通信系统误比特率上限,不符合通信理论。分析了各文献资料误比特率理论公式推导过程中的问题所在,推导得到了一个新的误比特率理论公式。进行了数值仿真,结果表明,新的误比特率理论公式与仿真吻合良好,能够准确描述系统误比特率,并且在低噪比下计算的误比特率不高于0.5,符合通信理论。在新的误比特率理论公式基础上,分析了基于等待门限判决的脉冲位置键控系统能量效率,并与二进制相移键控(BPSK)系统进行了比较,表明基于等待门限判决的脉冲位置键控系统是一种具有较高能量效率的系统,在一定条件下甚至优于BPSK系统。 相似文献
54.
55.
用从头算研究了d空穴位置不同对Ni—CO成键机制的影响。结果表明,Ni—CO键中σ/π接受作用的相对强弱,取决于Ni—CO簇所处的能态。σ空间电子云较π空间电子云弥散,因而Ni—CO簇的稳定性与σ空间电子云的排斥密切相关。随着Ni4pσ轨道上电子占据数的增加,Ni—CO稳定性减弱。比较了分子簇Ni—CO与NiCO分子及CO/Ni化学吸附体系之间的性质。 相似文献
56.
Matrix element of the Gallilean invariant nonrelativistic reduction of the pseudoscalar-pseudovector interaction has been
calculated for free pion absorption by a single nucleon inside the nucleus of16O. The Hartree-Fock wavefunctions obtained with the unitary-model-operator approach starting with the hard-core nucleon-nucleon
interaction have been used for the π-capturing nucleon in the initial state. The initial pion distortion in the presence of
nuclear field of the absorbing nucleus prior to its absorption together with the Coulomb interaction with the finite nuclear
size has been taken into account. The distortion of the emitted proton in the field of the residual nucleus has also been
considered. The differential cross-sections have been obtained and calculated results are compared with the previous experimental
and theoretical work. 相似文献
57.
Ronova I. A. Eylshina L. B. Vasilyuk A. N. Rusanov A. L. Bulycheva E. G. 《Russian Chemical Bulletin》2002,51(5):820-824
The dependence of the glass transition and initial decomposition temperatures of polyperyleneimide and polynaphthylimide on the conformational rigidity was studied by the Monte Carlo, Kuhn segment, and quantum chemical AM1 methods. The corresponding linear plots can be used for estimation of the glass transition and initial decomposition temperatures when experimental determination is difficult. 相似文献
58.
归一化互相关测度在光照改变时比采用绝对差之和测度(SAD)要稳定,但是归一化互相关测度的缺陷在于它的计算量非常大。为此,提出了一种结合自适应连续多级分区和初始阈值估计的基于归一化互相关(NCC)的快速模板匹配算法。根据模板图像中不同模块的梯度值,将模板图像进行逐级分区,通过分区顺序将互相关之和分为不同的层,得到各层互相关的上界,运用柯西-施不等式得到上界间的关系,形成自适应连续多级分区淘汰方法。同时,为了加快匹配速度,利用初始阈值估计产生一个较大的边界阈值,以淘汰初始搜索时的大量非匹配点,减少搜索点数目。实验结果表明:所提出的算法具有较好的鲁棒性,且算法的执行速度优于传统算法。 相似文献
59.
Yusuke Yoshimura Ryuichiro Hibi Akiho Nakata Moeka Togashi Shoujiro Ogawa Takayuki Ishige Mamoru Satoh Fumio Nomura Tatsuya Higashi 《Biomedical chromatography : BMC》2019,33(7)
A liquid chromatography/electrospray ionization–tandem mass spectrometry‐based method was developed for the identification of the conjugation positions of the monoglucuronides of 25‐hydroxyvitamin D3 [25(OH)D3] and 24,25‐dihydroxyvitamin D3 [24,25(OH)2D3] in human urine. The method employed derivatization with 4‐(4‐dimethylaminophenyl)‐1,2,4‐triazoline‐3,5‐dione to convert the glucuronides into fragmentable derivatives, which provided useful product ions for identifying the conjugation positions during the MS/MS. The derivatization also enhanced the assay sensitivity and specificity for urine sample analysis. The positional isomeric monoglucuronides, 25(OH)D3‐3‐ and ‐25‐glucuronides, or 24,25(OH)2D3‐3‐, ‐24‐ and ‐25‐glucuronides, were completely separated from each other under the optimized LC conditions. Using this method, the conjugation positions were successfully determined to be the C3 and C24 positions for the glucuronidated 25(OH)D3 and 24,25(OH)2D3, respectively. The 3‐glucuronide was not present for 24,25(OH)2D3, unlike 25(OH)D3, thus we found that selective glucuronidation occurs at the C24‐hydroxy group for 24,25(OH)2D3. 相似文献
60.
P. Glaister 《International Journal of Mathematical Education in Science & Technology》2013,44(1):110-117
Three techniques for determining a straight line fit to data are compared. The methods are applied to a range of datasets containing one or more outliers, and to a specific example from the field of chemistry. For the method which is the most resistant to the presence of outliers, a Microsoft Excel spreadsheet, as well as two Matlab routines, are included which can be used to determine the slope and intercept estimates. 相似文献