Glass transitions and mixed phases in block SBS

Differential scanning calorimetry (DSC) does not allow for easy determination of the glass‐transition temperature (T_g) of the polystyrene (PS) block in styrene–butadiene–styrene (SBS) block copolymers. Modulated DSC (MDSC), which deconvolutes the standard DSC signal into reversing and nonreversing signals, was used to determine the (T_g) of both the polybutadiene (PB) and PS blocks in SBS. The T_g of the PB block was sharp, at ?92 °C, but that for the PS blocks was extremely broad, from ?60 to 125 °C with a maximum at 68 °C because of blending with PB. PS blocks were found only to exist in a mixed PS–PB phase. This concurred with the results from dynamic mechanical analysis. Annealing did not allow for a segregation of the PS blocks into a pure phase, but allowed for the segregation of the mixed phase into two mixed phases, one that was PB‐rich and the other that was PS‐rich. It is concluded that three phases coexist in SBS: PB, PB‐rich, and PS‐rich phases. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 276–279, 2005     

Optical properties of polarization-dependent geometric phase elements with partially polarized light

The behavior of geometric phase elements illuminated with partially polarized monochromatic beams is investigated both theoretically and experimentally. The element discussed in this paper is composed of wave plates with π-retardation and a space-variant orientation angle. We found that a beam emerging from such an element comprises two polarization orders; right-and left-handed circularly polarized states with conjugate geometric phase modification. This phase equals twice the orientation angle of the space-variant wave plate comprising the element. Apart from the two polarization orders, the emerging beam coherence polarization matrix includes a “vectorial interference matrix” which contains information concerning the correlation between the two orthogonal, circularly polarized portions of the incident beam. In this paper we measure this correlation by a simple interference experiment. In addition, we found that the equivalent mutual intensity of the emerging beam is modulated according to the geometric phase induced by the element. Other interesting phenomena concerning propagation will be discussed theoretically and demonstrated experimentally. The experiment made use of a spherical geometric phase element that was realized by use of a space-variant subwavelength grating illuminated with CO₂ laser radiation of 10.6 μm wavelength.     

Discontinuous travelling wave solutions for certain hyperbolic systems

In an earlier paper on a malignant cell invasion model (Marchantet al., SIAM J. Appl. Math, 60, 2000) we introduced a novelform of discontinuous travelling wave solution. These solutionscould be studied easily by combining behaviour within a phaseplane with the Rankine–Hugoniot shock conditions, whichdescribe properties (such as the ratio of the jump discontinuitiesto the speed of propagation) that solutions may possess. Theseresults were new for several reasons. The shock conditions relateto hyperbolic equations (which the model is) but were appliedin a travelling wave ordinary differential equation phase planeusing techniques that usually apply to parabolic reaction–diffusionsystems. In addition the solutions possess singular behaviournear several points in the phase plane but in spite of thisthere exists a robust and stable family of physically interestingsolutions. In this paper we discuss two previously studied models, oneof detonation theory and one of angiogenesis. We show that eachof these models also possesses a family of discontinuous travellingwave solutions which was not previously discovered. Of particularinterest is the solution which has a blunt interface at thefront of the invading profile. In all three models it is thissolution that is seen to stably evolve from physically relevantinitial data, and for physically relevant parameter values. This work confirms the robustness of these novel travellingwave solutions and their applicability to a wider range of mathematicalmodelling situations.     

新型微波-毫米波幅相测试系统及扩展应用

介绍了一种新型微波 毫米波幅相测试系统及其在相关测试领域中的典型应用。与传统微波幅相测试系统相比 ,该系统具有原理新颖、结构简单、扩展频段容易和使用方便等优点。本系统目前广泛应用于紧缩场电气性能检测、天线测量和RCS测量等领域中 ,频率范围为 1～ 110GHz。本测试系统已经申请国家专利 ,并通过相关部门鉴定。     

介质极化的瞬时相位与振幅

求解电子运动的二阶微分方程，在旋转波近似下，介质在外场突然变化时产生的瞬态感应极化与外场同频，但相位总是落后，最大落后为π/2；振幅大小与初态有关，随时间按指数规律衰减，衰减快慢由介质的阻尼系数决定。     

Local Existence and Continuation Criterion for Solutions of the Spherically Symmetric Einstein-Vlasov-Maxwell System

Using the iterative scheme we prove the local existence and uniqueness of solutions of the spherically symmetric Einstein-Vlasov-Maxwell system with small initial data. We prove a continuation criterion to global in-time solutions.     

On Covariant Phase Space and the Variational Bicomplex

The notion of a phase space in classical mechanics is well known. The extension of this concept to field theory however, is a challenging endeavor, and over the years numerous proposals for such a generalization have appeared in the literature. In this paper We review a Hamiltonian formulation of Lagrangian field theory based on an extension to infinite dimensions of J.-M. Souriau's symplectic approach to mechanics. Following G. Zuckerman, we state our results in terms of the modern geometric theory of differential equations and the variational bicomplex. As an elementary example, we construct a phase space for the Monge–Ampere equation.     

蓝光相变光盘的多层膜结构设计

为了使光盘获得优良的记录／读出性能并能够长期稳定地使用，必须优化设计相变光盘的多层膜结构。采用自行设计的模拟分析相变光盘读出过程设计软件，从光学角度出发模拟计算了蓝光(405nm)相变光盘的膜层结构，研究了多层膜系的反射率和反射率对比度等光学参量与各层膜厚度和槽深的关系。研究得出的最佳多层膜结构为：下介电层／记录层／上介电层／反射层的厚度对于台记录为100nm／10nm／25nm，／60nm，而对于槽记录则为140nm／15nm／30nm，／60nm，槽深为50nm。模拟计算结果对于将来高密度蓝光相变光盘的制备具有一定的指导意义。     

时间分辨红外发射光谱法对自由基反应的研究

在过去的 15年中 ,傅立叶变换红外发射光谱法广泛应用于研究气相自由基反应 .Sloan首先研究了O(1D)的反应 ,随后Leone和Hancock研究了O(3 P)的反应 .此后 ,孔繁敖和朱起鹤等研究了小自由基 ,包括CH、CH2 、CH3 、C2 H3 、C2 H5、C2 H、C3 H3 和C3 H5与O2 、NO、N2 O、NO2 等分子的反应。在红外光谱中观察到各个反应的初生产物和初步反应通道 ,和从头算的理论研究结合起来 ,这些反应的机理已基本弄清 .     

Analysis of Two-Dimensional Optical Fields Using an Additional Shift

A solution to the phase problem in optics is considered within the context of registration and analysis of two-dimensional stationary optical fields transformed by the object under study or fields forming an image. To obtain information on amplitude and phase distributions of the light field analyzed, a method of registration of two intensity distributions is used. The first distribution corresponds directly to the amplitude distribution. The other is formed for the sum of the initial field and the field shifted along a certain direction. The intensity distributions obtained allow one to calculate the two-dimensional structure of the field under study. It is noteworthy that the method requires no iteration procedures in solving the problem. This leads to speeding up of the processing and analysis of the information. Two variants of optical schemes for the analysis of light fields are considered. The first one corresponds to registration of the image of the analyzed plane and the second to registration of the spectrum of the spatial frequencies.