基于作用距离的红外成像系统光学参数确定

作用距离是决定红外成像系统性能的重要指标,可直接影响红外成像光学系统的参数确定.基于作用距离的参数确定方法建立了探测器与作用距离、空间分辨率之间的关系,对光学系统的参数确定和性能评价具有重要作用.结合实例确定了红外成像系统光学的主要参数,采用非制冷凝视型长波红外探测器(工作波段为8mμ～12μm),在.特定的作用距离下,利用该方法确定的红外光学系统通光口径为90mm,F数值为1.     

10.6μm线性声光调制器研究

本文讨论的１０．６μｍ线性声光调制器，采用Ｇｅ单晶作为声光介质，工作中心频率为８０ＭＨｚ，３ｄｂ带宽为７ＭＨｚ。在驱动射频源输出功率８Ｗ的条件下，得到器件衍射效率峰值达３６％，该器件已作为激光束强度调制器件应用于视频／红外动态图象转换装置中。     

Non-Invasive Detection of Anti-Inflammatory Bioactivity and Key Chemical Indicators of the Commercial Lanqin Oral Solution by Near Infrared Spectroscopy

Quality control methods of current traditional Chinese medicine (TCM) preparation is time-consuming and difficult to assess in terms of overall efficiency of the drug. A non-destructive rapid near-infrared spectroscopy detection system for key chemical components and biological activity of Lanqin oral solution (LOS), one of the best-selling TCM formulations, was established for comprehensive quality evaluation. Near infrared spectral scanning was carried out on 101 batches of commercial LOS under the penetrated vial state and traditional state. RAW 264.7 cells were cultured to detect the anti-inflammatory ability of LOS, and the reference concentrations of epigoitrin, geniposide, and baicalin were obtained by HPLC. The quantitative models were optimized by three kinds of variable selection methods. The correlation coefficients of prediction value of the models were greater than 0.94. The system also passed the external validation. The performance of the non-invasive models was similar to the traditional models. The established non-destructive system can be applied to the rapid quality inspection of LOS to avoid unqualified drugs from entering the market and ensure drug effectiveness. The biological activity index of LOS was introduced and predicted by NIRs for the first time, which provides a new idea about the quality control of TCM formulations.     

Adoption of Common Schemes for Single and Sequential Extractions of Trace Metal in Soils and Sediments

Abstract

The various methods for determining the mode of occurrence of trace metals in sediments and soils have a long history which dates back to the determinations of the availability of metals for plant nutrition performed earlier. Various methods have been developed in the 70′s and 80′s dealing with both single and sequential extraction schemes. Although some schemes received wide acceptance, none of them developed into a commonly accepted procedure. As a result, the information obtained was site-specific and the interpretation of the results scientist-specific. The workshop on single and sequential extraction in sediments and soils held at Sitges     

基于局域网的频谱仪信号参数录取方法研究

立足实际装备,对电波监测类装备的监测原理进行了深入研究。提出了通过局域网连接频谱仪并设置参数、录取频谱仪实时显示数据参数的方法。通过设计软件实现频谱仪数据录取系统。达到丰富电波监测的测量手段、提高测量仪器的自动化水平的目的。对今后监测系统的功能实现、扩展、虚拟仪器设计都具有一定的指导作用。同时,对电波监测类装备的研制及改进也有一定的借鉴意义,可提高测量仪器的自动化水平。     

基于无线传感网的现代水产养殖监控系统设计

针对传统水产养殖存在的弊端,文章设计了一款基于无线传感网、移动互联及云计算等技术的养殖水体环境因子智能化监控系统,可以实现对水体关键环境因子的快速检测、及时反馈和自动调节,对于发展高效、生态、安全的现代水产养殖业具有重要的推动作用。     

Real-Time Monitoring of the Mechanical Properties of a Soy Protein and Rubber Polymer during its Production Using Transient Infrared Spectroscopy

Soy protein–based polymers offer promising performance properties, but their characteristics are sensitively dependent on production conditions, so on-line monitoring could help provide the needed control during production. Mid-infrared spectroscopy combined with partial least squares offer the needed analysis, but the opacity of many materials in the mid-infrared range limits its conventional application. Transient infrared spectroscopy is a method of acquiring mid-infrared spectra from moving streams in real time that avoids the opacity problem. We apply transient infrared spectroscopy to a polymer of soy protein and polyisoprene-graft-maleic anhydride–modified natural rubber during its compounding extrusion to measure tensile strength and Young's modulus.     

Formation of “Quasi” Contact or Solvent‐separated Ion Pairs in the Local Environment of Probe Molecules Dissolved in Ionic Liquids

The change from “quasi” contact to “quasi” solvent‐separated ion‐pair configuration in the local environment of a probe molecule in ionic liquids depends on the varying interaction strength of the chosen anions. The ion speciation in these Coulomb fluids could be shown by combining infrared spectroscopy, density functional theory calculations, and natural bond orbital analysis using a low‐self‐clustering probe molecule.     

On‐Line Monitoring of Chemical Reactions by using Bench‐Top Nuclear Magnetic Resonance Spectroscopy

Real‐time nuclear magnetic resonance (NMR) spectroscopy measurements carried out with a bench‐top system installed next to the reactor inside the fume hood of the chemistry laboratory are presented. To test the system for on‐line monitoring, a transfer hydrogenation reaction was studied by continuously pumping the reaction mixture from the reactor to the magnet and back in a closed loop. In addition to improving the time resolution provided by standard sampling methods, the use of such a flow setup eliminates the need for sample preparation. Owing to the progress in terms of field homogeneity and sensitivity now available with compact NMR spectrometers, small molecules dissolved at concentrations on the order of 1 mmol L^?1 can be characterized in single‐scan measurements with 1 Hz resolution. Owing to the reduced field strength of compact low‐field systems compared to that of conventional high‐field magnets, the overlap in the spectrum of different NMR signals is a typical situation. The data processing required to obtain concentrations in the presence of signal overlap are discussed in detail, methods such as plain integration and line‐fitting approaches are compared, and the accuracy of each method is determined. The kinetic rates measured for different catalytic concentrations show good agreement with those obtained with gas chromatography as a reference analytical method. Finally, as the measurements are performed under continuous flow conditions, the experimental setup and the flow parameters are optimized to maximize time resolution and signal‐to‐noise ratio.