α，α‘—二氧代烯酮环二硫代缩酮类化合物的特征红外光谱（Ⅲ）

研究了5种α，α‘-二氧代烯酮环二硫代缩酮类化合物的碳基、碳碳双键、碳硫等一些特征红外光谱，尤其着重研究了共轭体系下的各种特征谱带随化学结构而变化的规律。     

Organometallic mediated radical polymerization of vinyl acetate with Fe(acac)2

The radical polymerization of vinyl acetate (VAc) is moderated by iron(II) acetylacetonate (Fe(acac)₂) by the organometallic route (OMRP), as well as by degenerative transfer polymerization (DTP) when in the presence of excess radicals, through the formation of thermally labile organometallic Fe^III dormant species. The poly(vinyl acetate) (PVAc)‐Fe^III(acac)₂ dormant species has been isolated in the form of an oligomer and characterized by ¹H NMR, EPR, and IR methods, and then used as a single‐component initiator for the OMRP of VAc. The degree of polymerization of this isolated oligomeric species demonstrates the limited ability of Fe(acac)₂, relative to the Co(acac)₂ congener, to rapidly trap the growing PVAc radical chain. Control under OMRP conditions is improved by the presence of Lewis bases, especially PMe₂Ph. On the other hand, iron(II) phthalocyanine inhibits the radical polymerization of VAc completely. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 3494–3504     

A study on melt grafting of maleic anhydride onto low‐density polyethylene and its blend with polyamide 6

Graft copolymerization of low‐density polyethylene (LDPE) with a maleic anhydride (MAH) was performed using intermeshing corotating twin‐screw extruder in the presence of benzoyl peroxide (BPO). The LDPE/polyamide 6 (PA6) and LDPE‐g‐MAH/PA6 blends were prepared in a corotating twin‐screw extruder. The melt viscosity of the grafted LDPE was measured by a capillary rheometer. The grafted copolymer was characterized by Fourier transform infrared spectroscopy (FTIR) and scanning electron microcopy (SEM). The influence of the variation in temperature, BPO and MAH concentration, and temperature on the grafting degree and on the melt viscosity was studied. The grafting degree increased appreciably up to about 0.45 phr and then decreased continuously with an increasing BPO concentration. According to the FTIR analysis, it was found that the amount of grafted MAH on the LDPE chains was ～5.1%. Thermal analysis showed that melting temperature of the graft copolymers decreases with increasing grafting degree. In addition to this, loss modulus (E″) of the copolymers first increased little with increasing grafting and then obviously decreased with increasing grafting degree. Furthermore, the results revealed that the tensile strength of the blends increased linearly with increasing PA6 content. The results of SEM and mechanical test showed that the blends have good interfacial adhesion and good stability of the phase structure, which is reflected in the mechanical properties. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 267–275, 2010     

Investigation of nitrogen‐rich energetic polymers based on alkylbridged bis‐(1‐methyl‐tetrazolylhydrazines)

Nitrogen‐rich energetic polymers were synthesized by the polyaddition reaction of 1,2‐bis(5‐monomethylhydrazinyl‐1H‐tetrazolyl)ethane ( 1a ), 1‐methyl‐1,2‐bis(5‐monomethylhydrazinyl‐1H‐tetrazolyl)ethane ( 1b ), and 1,4‐bis(5‐mono‐methylhydrazinyl‐1H‐tetrazolyl)butane ( 1c ) with hexamethylene diisocyanate. The experiments showed that neither a polymerization from solution or bulk was possible. Therefore, a new method for the polymerization of tetrazolyl hydrazines had to be developed. The formed polymers were characterized by vibrational spectroscopy (IR) and elemental analysis. The energetic properties were investigated by bomb calorimetric measurements along with calculations using the EXPLO5 software. The thermal stability was investigated by DSC measurements. The properties render the polymers into promising compounds regarding an application as energetic binder. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 122–127, 2010     

Effect of in situ annealing on highly-mismatched In0.75Ga0.25As on InP grown using molecular beam epitaxy

We demonstrate that the electrical quality of junctions fabricated in lattice-mismatched In_0.75Ga_0.25As on InP grown by molecular beam epitaxy can be improved with the addition of in situ anneals in the buffer layer that separates the substrate from the In_0.75Ga_0.25As device layers. Near infrared photodetectors fabricated using this material had dark current densities of approximately 2.5 mA/cm² at a reverse bias of 1 V, which is more than one order of magnitude smaller than commercially available photodetectors grown using vapor phase epitaxy. Transmission electron microscopy revealed that dislocations due to the lattice mismatch between the substrate and the epitaxial layer are confined primarily to the buffer layer for all samples studied. No significant differences in x-ray diffraction spectra or dislocation distribution were observed on samples with and without in situ annealing. Atomic force microscopy indicated that all samples had a crosshatch pattern, and that the average surface roughness of the sample that contained in situ anneals is a factor of three greater than the sample without in situ anneals.     

GaN1-xPx三元合金的红外谱

对GaN1-xPx三元合金进行了红外谱的测试和拟合. 分析结果表明在GaN1-xPx三元合金中存在两个彼此竞争的机制制约着载流子浓度的变化. 一个是来自等电子陷阱的影响，它将减少三元合金中载流子的浓度；另一个来自缺陷的影响，它将增加三元合金中载流子的浓度. 对合金介电函数的倒数的虚部进行了计算，其结果显示，随着合金中P组分比的增加，纵向光学声子-等离激元（LPP）耦合模式向高频方向移动，同时LPP模式线宽逐渐增宽，说明随着合金中P组分比的增加，LPP模式的耦合作用增加，阻尼增强.     

Cr：Mg2SiO4晶体红外光致发光谱的研究

报道了在室温和液氮温度下分别用1064nm和532nm激光诱导的Cr:Mg_2SiO_4晶体的红外光致发光谱,并详细分析光谱的结构和特点.在假设Cr:Mg_2SiO_4晶体中同时存在(CrO_6)~(9-)和(CrO_4)~(4-)两种络离子的基础上讨论了红外光致发光的产生机理,理论计算证明假设是合理的.     

用于红外探测的新型冷却器—脉冲管制冷机

脉冲管制冷技术近年来的突破性进展,使其可在相当多的领域得到应用。本文通过分析和比较,结合作者等人近几年来的研究结果,给出脉冲管制冷机应用于红外探测器件冷却的可行性。