The Thermodynamics of Insertion Electrochemical Electrodes—A Team Play of Electrons and Ions across Two Separate Interfaces

Insertion electrochemical electrodes exhibit simultaneous electron and ion transfer, with the two transfers proceeding across different interfaces. Herein the thermodynamics of the overall electrochemical electrode reaction is discussed with respect to the thermodynamics of these two charge‐transfer equilibria. This Minireview includes insertion electrochemical systems where the redox centers are in a solid phase and the ions are transferred between that phase and a solution, and also systems where the redox centers are in a liquid phase that is immiscible with another liquid phase and ions are transferred between the two liquid phases. The Minireview is intended to spark similar studies on battery materials to improve their performance.     

Ionization dynamics of dense matter generated by intense ultrashort X‐ray pulses

We investigate a pump‐probe X‐ray Thomson scattering (XRTS) experiment that might be carried out at a free electron laser facility to study warm‐to‐hot states of dense matter. Ultrashort and intense X‐ray pulses with different energies (1,560–1,830 eV) heat a 1 µm thick Al target isochorically and create homogeneous and uncompressed warm‐to‐hot states of dense matter. A second pulse with variable delay probes this heated state via XRTS. The X‐ray laser–target interaction is modelled within radiation‐hydrodynamic simulations applying the HELIOS‐CR code. The HELIOS‐CR results qualitatively agree with Monte‐Carlo simulations, where the laser pulse absorption is simulated based on a uniform random sequence of events. The electron feature in the simultaneously observed X‐ray scattering spectrum is a function of the degree of ionization and the target temperature. Therefore, the temporal evolution of the plasmon peak measures the ionization dynamics on ultra‐short time scales. The XRTS spectrum is calculated based on the Chihara formula utilizing the Born‐Mermin approximation for the free electron dynamic structure factor. The proposed experiment will reveal important details of the ionization dynamics on ultra‐short time scales as well as of the relaxation on ps time scales.     

Effects of non‐extensive electrons on the sheath of dusty plasmas with variable dust charge

In this study, a detailed investigation of the problem of sheath is presented using the fluid model in a magnetized three‐component dusty plasma system comprising positive ions, dust grains with variable charge and q‐non‐extensive electrons (i.e., the electrons evolve far away from their Maxwellian thermodynamic equilibrium [q = 1]). The effects of q‐non‐extensivity parameter on the plasma sheath parameters are studied numerically. A significant change is observed in the quantities characterizing the sheath with the presence of the super‐extensive electrons (q < 1) and sub‐extensive electrons (q > 1). In addition, based on the orbital motion limited theory, by taking various forces acting on the dust particle into consideration, the dynamics of the dust located within the sheath, that is, the dust grain charging inside the sheath, is examined under different values of q. It is found that the q‐non‐extensivity has affected significantly the dynamics and the charging process of the dust grains in the sheath.     

Solitary Potential in a Space Plasma Containing Dynamical Heavy Ions and Bi-Kappa Distributed Electrons of Two Distinct Temperatures

The heavy ion-acoustic solitary waves(HIASWs) in a magnetized, collisionless, space plasma system(containing dynamical heavy ions and bi-kappa distributed electrons of two distinct temperatures) have been theoretically investigated. The Korteweg-de Vries(K-dV), modified K-dV(MK-dV), and higher-order MK-dV(HMK-dV) equations are derived by employing the reductive perturbation method. The basic features of HIASWs(viz. speed, polarity,amplitude, width, etc.) are found to be significantly modified by the effects of number density and temperature of different plasma species, and external magnetic field(obliqueness). The K-dV and HM-Kd V equations give rise to both compressive and rarefactive solitary structures, whereas the MK-dV equation supports only the compressive solitary structures. The implication of our results in some space and laboratory plasma situations are briefly discussed.     

Orbital angular momentum of channeling radiation from relativistic electrons in thin Si crystal

We propose to use channeling radiation (CR) from relativistic electrons as a source of high energy twisted photons in the MeV range. We calculate numerically the orbital angular momentum (OAM) of radiation produced by electrons with the energies $155÷2500$ MeV for the axial and planar channeling in the thin Si crystal. We obtain that the average OAM of CR in this case is approximately $1÷6?$ per photon with the photon energies about $1÷2$ MeV.     

光子与相对论麦克斯韦分布电子散射截面的蒙特卡罗计算方法

高温全电离等离子体的辐射输运问题中,光子与电子的Compton散射与逆Compton散射是其中重要的特性,光子与相对论麦克斯韦电子散射的描述及截面的计算非常复杂且费时.本文提出了一种用于模拟计算光子与相对论麦克斯韦速度分布电子散射截面的蒙特卡罗计算方法.给出了各步骤的具体实现办法,推导了对应的计算公式,研究了相对论电子速率抽样方法,编写了光子与相对论电子散射的微观截面的蒙特卡罗计算程序.开展了高温全电离等离子体中,不同能量光子与不同温度电子散射的微观散射截面计算和分析.模拟计算结果显示,在电子温度低于25 keV情况下,本文方法与多重数值积分方法的计算结果非常接近;但随着电子温度继续升高,二者差异逐渐增大并较明显,经分析,可能是本文方法目前的电子速率抽样偏差所致,希望将来能够找到更好的相对论电子速率抽样方法以克服此缺陷.     

Linear Analyses of Langmuir and EM Waves in Relativistic Hot Plasmas

The linear Langmuir and electromagnetic (EM) waves in relativistic hot plasmas are discussed, and the dispersion relations are obtained based on the covariant Maxwell's and fluid equations. When kBT/mc²>1, the effective mass of electrons will be increased obviously. As the results, many other influences are induced, such as the decrease of the plasmas frequency and the critical frequency, the reduction of the electron sound velocity and the electrons' oscillation velocity, and so on. Numerical results show that these influences can affect the dispersion relations of Langmuir and EM waves seriously even in linear regime.     

Shannon entropies and Fisher information of K-shell electrons of neutral atoms

We represent the two K-shell electrons of neutral atoms by Hylleraas-type wave function which fulfils the exact behavior at the electron–electron and electron-nucleus coalescence points and, derive a simple method to construct expressions for single-particle position- and momentum-space charge densities, $\rho (\mathit{r})$ and $\gamma (\mathit{p})$ respectively. We make use of the results for $\rho (\mathit{r})$ and $\gamma (\mathit{p})$ to critically examine the effect of correlation on bare (uncorrelated) values of Shannon information entropies (S) and of Fisher information (F) for the K-shell electrons of atoms from helium to neon. Due to inter-electronic repulsion the values of the uncorrelated Shannon position-space entropies are augmented while those of the momentum-space entropies are reduced. The corresponding Fisher information are found to exhibit opposite behavior in respect of this. Attempts are made to provide some plausible explanation for the observed response of S and F to electronic correlation.     

A mechanism for hot-spot generation in a reactive two-dimensional sheared viscous layer

A two-dimensional model for the non-uniform melting of a thin sheared viscous layer is developed. An asymptotic solution is presented for both a non-reactive and a reactive material. It is shown that the melt front is linearly stable to small perturbations in the non-reactive case, but becomes linearly unstable upon introduction of an Arrhenius source term to model the chemical reaction. Results demonstrate that non-uniform melting acts as a mechanism to generate hot spots that are found to be sufficient to reduce the time to ignition when compared with the corresponding one-dimensional model of melting.     

NMOS管热载流子衰退效应评价模型及寿命预测方法研究

热载流子是器件可靠性研究的热点之一.特别对于亚微米器件,热载流子失效是器件失效的一个最主要方面.通过对这种失效机理及其失效模型的研究,为设计和工艺提供帮助,从而有效降低由热载流子引起的电路失效,提高电路可靠性.本文主要针对几种典型工艺的栅氧厚度(例如:Tox分别为150 (A)、200 (A)、250 (A))的NMOSFET进行加速应力实验,提取寿命模型的相关参数,估算这些器件在正常工作条件下的寿命值,对亚微米工艺器件寿命进行快速评价.