FRP加固梁的FRP-混凝土界面脱胶分析

为了研究纤维增强聚合物(fiber reinforced polymer, FRP) 加固梁的FRP-混凝土界面脱胶破坏过程,本文将混凝土梁和FRP 板均视为线弹性的欧拉-伯努利梁(Euler-Bernoulli beams), 且两者通过粘结层胶结在一起. 对于FRP-混凝土结构,有两种形式的脱胶破坏：板端脱胶破坏和跨中裂缝导致的脱胶破坏.对于FRP-混凝土梁,利用合理的粘结模型按第2 种脱胶失效形式,详细讨论了FRP-混凝土界面的脱胶过程,得到了不同阶段的胶结滑移、界面剪应力和FRP 轴向力的解析解. 实验研究验证了理论分析的结果,参数研究进一步探讨了胶结长度和粘结层厚度对于FRP-混凝土界面脱胶行为的影响.     

基于纤芯失配多模干涉的光纤折射率传感器

基于多模干涉效应的单模-多模-单模(SMS)结构光纤折射率传感器通常需要进行包层腐蚀来提高灵敏度,而且易受环境温度影响。为克服SMS结构的这些不足,提出了一种新型的基于纤芯失配多模干涉的光纤折射率传感器,由单模光纤-色散补偿光纤-单模光纤(SMF-DCF-SMF)级联光纤布拉格光栅(FBG)构成,长度不超过100mm。对其灵敏度、线性范围和温度特性等进行了测试,实验结果显示在测量折射率为1.33～1.39的折射率液时,特征波长与折射率呈线性关系,灵敏度为232.8nm,级联的FBG具有良好的温度校准功能。     

具有有源闭合腔的光纤光栅传感系统地址查询技术

基于熔融拉锥技术研制的3 dB宽带耦合器的光纤环形镜的工作原理,提出了一种新型的具有有源闭合腔装置的光纤光栅传感系统。在用作闭合共振腔端镜的环形镜中写入十个波分复用光纤光栅传感元,利用共振腔中接入的法布里-珀罗滤波器,通过控制电压对传感光栅的波长扫描,实现对传感地址的查询。用非平衡的迈克耳孙扫描干涉仪将传感光栅的波长漂移信息变为相移信息,实现传感信号的解调。系统传感灵敏度的实验值为1.5835°/10-6ε,与理论值(1.6662°/10-6ε)基本吻合。     

Carbonized cotton fibers via a facile method for highly sensitive solid‐phase microextraction of polycyclic aromatic hydrocarbons

Cotton fiber is an environmentally friendly and natural material with a certain extraction capacity, while its enrichment ability is poor. In order to improve the extraction efficiency of cotton fibers, it was carbonized to form a layer of amorphous carbon as the sorbent by a simple carbonization method. Carbonized cotton fibers were filled into a polyetheretherketone tube for in‐tube solid‐phase microextraction. The carbonization time was investigated to obtain high extraction efficiency. Coupled to high‐performance liquid chromatography, the extraction tube was evaluated with polycyclic aromatic hydrocarbons, estrogens and phthalates, and it exhibited best extraction efficiency for polycyclic aromatic hydrocarbons. Under the optimum conditions, an online analysis method for several polycyclic aromatic hydrocarbons was established with large linear ranges (0.016–0.20 μg/L), low limits of detection (0.005–0.020 μg/L), and high enrichment factors (948–2874). Analysis method was successfully applied to the detection of targets in the real samples and shown satisfactory durability and chemical stability. Moreover, the relative recoveries ranged from 82 to 119.2%, which demonstrated the applicability of carbonized cotton fibers in sample preparation. Compared with other reported methods, the proposed method provided shorter extraction time, higher enrichment factors, comparable limits of detection, and recoveries.     

Hollow fiber liquid phase microextraction as a preconcentration and clean-up step after pressurized hot water extraction for the determination of non-steroidal anti-inflammatory drugs in sewage sludge

A method for the quantitative determination of non-steroidal anti-inflammatory drugs (NSAIDs) in sewage sludge was developed and validated. The target compounds were extracted using pressurized hot water extraction (PHWE) and then purified and preconcentrated by three-phase hollow fiber liquid phase microextraction (HF-LPME) followed by LC–ESI-MS analysis. The PHWE was optimized with regard to the pH of solvent as well as other operational parameters. The optimum conditions were 0.01 M NaOH as the extraction solvent, temperature of 120 °C, pressure of 100 bar, static time 5 min, 5 cycles, flush volume 90% and purge time 60 s. Spike recoveries for sludge samples spiked at 200 ng g⁻¹ were in the range of 101–109% but for the native drugs in non-spiked sludge samples, recoveries were 38.9%, 59.8%, 90.3% and 47.8% for ketoprofen, naproxen, diclofenac and ibuprofen, respectively. Donor phase pH, ionic strength and extraction time were optimized for HF-LPME after PHWE. The optimum conditions were 2 h extraction at pH 1.5 without salt addition. Enrichment factors in the range of 947–1213 times were achieved (extraction recoveries were 23.6–30.3%) for HF-LPME after PHWE. The matrix effect on the ionization of drugs in LC–ESI-MS was also investigated. The results show that there is a smaller matrix effect (−8.9% to +14.6%) in comparison with other published values obtained using solid phase extraction (SPE) for clean-up after pressurized liquid extraction (PLE). Method detection limits (MDLs) and method quantification limits (MQLs) for different drugs were in the range of 0.4–3.7 ng g⁻¹ and 1.5–12.2 ng g⁻¹ in dried sludge samples, respectively. The characteristics of the proposed method were compared with those of other published works. The considerably lower ion suppression/enhancement and minimum use of organic solvents (a few microliters of di-n-hexyl ether) in the sample preparation step are two highlighted advantages of the proposed method in comparison with previously published works. The method was applied to determine NSAIDs in sewage sludge from Källby wastewater treatment plant (Lund, Sweden) in April, June, August and October 2010. The highest concentration level was recorded for ibuprofen in the April sewage sludge sample (588 ng g⁻¹) and all of the selected NSAIDs were detected in all the samples analyzed.     

The dynamic mechanical behavior of random-in-plane short fiber-reinforced epoxy resin composites

In the present paper, the dynamic mechanical properties of random-in-plane short fiber-reinforced epoxy resin composites were studied by using a rheometrics solids analyzer. The three-point bend testing of the four composites (glass fiber/913 epoxy resin, glass fiber/924 epoxy resin, carbon fiber/913 epoxy resin and carbon fiber/924 epoxy resin) was carried out over temperatures from −100°C to 200°C at a frequency of 10 Hz and strain 0.05%. The composites based on 924 epoxy resin, which has been designed specially for high temperature applications, have less energy loss than the 913 epoxy resinbased composites. For the same resin, the carbon fiber-reinforced composites have less energy loss than the glass fiber-reinforced composites. All the composites have less energy loss than their corresponding matrices; the greater the fiber content, the lower the energy loss. The beta transition of 913 epoxy resin has been shifted to a higher temperature after being reinforced. It was shifted from −50°C to −30°C after being reinforced with glass fiber and made a diffuse shoulder-like peak commencing at −30°C after being reinforced with carbon fiber. The 924 epoxy resin has undergone the same change in beta transition as the 913 resin, though to a smaller extent. The phenomenon suggested that interactions between the macromolecules of the epoxy resins and the molecules along the fiber's surface.     

医用体内光纤温度传感器探头神经网络设计

利用误差反向传播算法(BP)和径向基函数(RBF)神经网络法，分别对医用体内光纤温度传感器探头进行设计，训练神经网络的数据通过实验和插值得到。该方法具有准确、可靠和知识辅助设计的特点。结果证明，此方法可以节省设计成本，缩短设计周期，有很高的实用价值。     

8字形主被动锁模掺Er3+光纤激光器

在理论上分析了利用非线性光学环形镜作为等效可饱和吸收体压缩脉冲进行锁模的物理机制。利用8字形主被动混合锁模的结构在调制频率2．498749GHz下，在1．543μm处获得了12ps的锁模脉冲输出，对应谱宽0．22nm，时间脉宽积0．33。在抽运功率50mW情况下，输出脉冲平均功率3．715mW。在调制频率2．499344GHz、2．499114GHz和2．498999GHz时分别并获得了2～4阶幅度较为均衡的有理数谐波锁模脉冲序列。     

抑制光纤通信系统偏振模色散的措施

偏振模色散(PMD)已成为长距离、高速率光纤通信系统的主要障碍。从光纤的制造工艺、光器件的选择、信号传输三个方面全面分析讨论了偏振模色散的抑制方法,并对这些方法的可行性进行了分析。     

油-气-水三相流超声传感器持气率测量

为探索油-气-水三相流持气率测量难题,该文开展了脉冲透射式超声传感器持气率测量动态实验研究。首先,利用超声传感器与光纤传感器组合,测取了油-气-水三相流中段塞流、混状流、泡状流的响应信号;其次,提取了超声脉冲信号的最大值序列来反映不同流型时超声传感器响应特性,同时,借助双头光纤传感器与相关测速法,计算得到了流体中气泡弦长序列;最后,结合流型与泡径信息,利用超声传感器测量了不同流型下持气率,并分析了不同流型持气率预测的误差来源,为其他油-气-水三相流持气率测量传感器设计提供了借鉴。