半变系数模型约束PLS估计的渐近正态性

变系数模型已获得了广泛的应用,半变系数模型是变系数模型的有效推广,本文给出半变系数模型在线性约束条件下的PLS估计,并证明了常系数和函数系数估计的渐近正态性.     

Component desorption effect on the material catalyticity in high-temperature multicomponent gases

The distinctive features of the formation of the catalyticity of materials with respect to atom recombination on the material surface are investigated for mixtures of different high-temperature gases under conditions of hypersonic atmospheric flight or bench setups. It is shown that in general the catalyticity constants (heterogenous recombination probabilities) of individual components determined experimentally in dissociated flows of “pure” gases are improperly used for calculating the heat fluxes to material surfaces in multicomponent gas flows, owing to differences in the occupation of the surface by atoms in pure gases and mixtures. This effect must be taken into account in interpreting the experimental data which so far have been the only source of information on material catalyticity in gas mixtures. Otherwise, the results of calculations of the heat transfer to hypersonic flight vehicles could turn out to be invalid. Examples of the possible effect of ignoring this factor on the calculated heat fluxes are presented.     

论通信动力系统运维效益的量化方法

为了实现通信动力系统运维管理部门的量化考核与绩效改进,文章提出了基于成本与网络风险损失的动力运维效益量化方法,直接计算单位成本的有效电度,并提供网络风险损失系数取值的建议。     

基于分布参数模型的CO_2蒸发器结构参数研究

在设计工况下,建立了用于跨临界二氧化碳热泵热水器的套管式蒸发器的稳态分布参数模型,对其结构参数进行了敏感性分析,指出了它们的合理变化范围:管内套1根管时,内管外径应至少大于11.00mm,低于13.00mm,外管内径应在20.00mm以上,23.00mm以下;管内套多根管时,以管内套3根管的性能为最优。优化设计结果对开发二氧化碳蒸发器产品具有一定的指导意义。     

Vibrational spectroscopic investigation of poly(p‐phenylene sulfide)

Poly(p‐phenylene sulfide) (PPS) is an important polymer of engineering interest particularly useful in the electronics and automotive industries. Normal mode analysis including phonon dispersion has been performed to understand completely the vibrational spectra of this polymer. Various characteristic features of the dispersion curves have been reported. Crossing/Repulsion between various pairs of modes at certain phase values have been explained as arising due to internal symmetry in the energy momentum space. The heat capacity is calculated as a function of temperature via density‐of‐states in the range 220–360 K. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 2353–2367, 2009     

Photoinitiating monomers based on di‐ and triacryloylated hydroxylamine derivatives

The purpose of our study was to design a new class of acrylate‐based monomers with an UV‐cleavable heteroatom bond, offering the possibility to initiate radical polymerization upon irradiation with UV‐light. A method to derive the double bond conversion from the ATR‐IR spectra of the monomers and the cured polymers was employed, that enabled us to calculate the theoretical polymerization heats of the new monomers. Their photopolymerization properties were determined by Photo Differential Scanning Calorimetry. Surprisingly, some of these new compounds exhibited high photoinitiation activity, comparable to well‐established Type II photoinitiator systems like benzophenone/triethanolamine. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 392–403, 2009     

Analytic approach to the (an)harmonic crystal chains with self-consistent stochastic reservoirs

We consider the harmonic and anharmonic chains of oscillators with self-consistent stochastic reservoirs and derive an integral representation (à la Feynman-Kac) for the correlations, in particular, for the heat flow. For the harmonic chain, we give a new proof that its thermal conductivity is finite in the steady state. Based on this integral representation for the correlations and a perturbative analysis, the approach is quite general and can be extended to more intricate systems. __________ Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 156, No. 1, pp. 138–146, July, 2008.     

基于粗集理论的组合预测法在无形资产评估中的应用

针对如何评估企业无形资产的问题,运用基于粗集理论的组合预测方法,建立了企业无形资产评估的数量模型。该模型的特点是将组合预测方法中权系数的确定问题转化为粗集理论中的属性重要性评价问题,这样就在很大程度上克服了传统组合预测方法中权系数确定主观性太大的缺陷,而使得权系数的确定更具客观性。最后,结合实例阐述了基于粗集理论的组合预测方法在企业无形资产评估中的应用,进一步说明了该方法的可行性和有效性。     

光子晶体平面波导与脊波导高效耦合技术的研究

利用一维变周期谐振腔阵列和非线性缓变边界，可以实现光波从脊波导到光子晶体平面波导 （PCW）的高效耦合.基于平面波展开法（PWE）和时域有限差分法（FDTD），深入分析和讨 论了普通脊波导、2D-PCW结构和本征模以及工作模式、缓变边界形状等对耦合效率的影响， 从而得出光波从脊波导到2D-PCW、再返回脊波导的统一图景.指出考虑模式转换和采用缓变 边界条件可以极大提高PCW与脊波导间的耦合效率.对PC-PW边界采用线性和非线性缓变结构 进行了仿真，讨论了边界缓变程度对耦合效率的影响.结果表明，采用模式耦合和PC-PW余弦 缓变边界时的耦合效率在较宽的带宽内超过了95%. 关键词： 光子晶体波导 脊波导 PWE FDTD 耦合边界     

Thermodynamics of electrolyte solutions: Activity and osmotic coefficients of aqueous NaCl in the NaCl-MgCl2-H2O system at different temperatures by the EMF method

The activity and osmotic coefficients of aqueous NaCI in the NaCl-MgCl₂-H₂O system at 25, 35 and 45°C and total ionic strengths of 0.5, 1, 2 and 3 were obtained by an EMF method using a sodium ion-selective electrode and an Ag/AgCl electrode. The Harned coefficients and Pitzer binary and ternary interaction coefficients were also determined.